Catalytic Properties for Decomposition of sec-Butyl Alcohol Over ZnO@SiO2 Nanocomposites Sol-Gel Catalysts

Xiaomei Zhu; Ru Li; Ngoc Long Nguyen; Bing Sun

doi:10.14233/ajchem.2014.16429

Issue

Vol. 26 No. 15 (2014): Vol 26 Issue 15

Issue Published : July 16, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Catalytic Properties for Decomposition of sec-Butyl Alcohol Over ZnO@SiO2 Nanocomposites Sol-Gel Catalysts

https://doi.org/10.14233/ajchem.2014.16429

Xiaomei Zhu

College of Environment Science and Engineering, Dalian Maritime University, Dalian, P.R. China

Ru Li

College of Environment Science and Engineering, Dalian Maritime University, Dalian, P.R. China

Ngoc Long Nguyen

College of Environment Science and Engineering, Dalian Maritime University, Dalian, P.R. China

Bing Sun

College of Environment Science and Engineering, Dalian Maritime University, Dalian, P.R. China

Corresponding Author(s) : Bing Sun

zxmhc7879@126.com

Asian Journal of Chemistry, Vol. 26 No. 15 (2014): Vol 26 Issue 15
Article Published : July 19, 2014

Abstract

ZnO/SiO₂ catalysts of two different zinc oxide contents were prepared by the sol-gel technique and calcined at 653 and 953 K. ZnO/SiO₂ catalyst with 9 % zinc oxide content was prepared by impregnation method as compare. The samples prepared were then used as catalyst in the decomposition of sec-butyl alcohol. They were found to give the opposite selectivity for dehydrogenation or dehydration on the catalysts prepared via the different methods. Characterization of the catalysts by TEM, BET and XPS confirmed that the difference of selectivity for dehydrogenation or dehydration was no obvious relation with the crystal, size, surface area, pore volume and reaction temperature. Further studies indicate that the reason of the different surface properties is caused by different interactions between zinc oxide and the silica matrix.

Keywords

sec-Butyl alcohol ZnO@SiO2 Sol-gel Catalysts

Zhu, X., Li, R., Long Nguyen, N., & Sun, B. (2014). Catalytic Properties for Decomposition of sec-Butyl Alcohol Over ZnO@SiO2 Nanocomposites Sol-Gel Catalysts. Asian Journal of Chemistry, 26(15), 4879–4882. https://doi.org/10.14233/ajchem.2014.16429

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References

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References

J.H. Hong, Y.F. Wang, G. He and J.X. Wang, J. Non-Cryst. Solids, 356, 2778 (2010); doi:10.1016/j.jnoncrysol.2010.09.065.

R. Anedda, C. Cannas, A. Musinu, G. Pinna, G. Piccaluga and M. Casu, J. Nanopart. Res., 10, 107 (2008); doi:10.1007/s11051-007-9235-5.

Z. Yang, Z.Z. Ye, B.H. Zhao, X.L. Zong and P. Wang, J. Sol-Gel Sci. Technol., 54, 282 (2010); doi:10.1007/s10971-010-2191-z.

K.J. Chen, F.Y. Hung, S.J. Chang, S.J. Young and Z.S. Hu, Curr. Appl. Phys., 11, 1243 (2011); doi:10.1016/j.cap.2011.03.033.

S.M. Hossein Hejazi, F. Majidi, M. Pirhadi Tavandashti and M. Ranjbar, Mater. Sci. Semicond. Process., 13, 267 (2010); doi:10.1016/j.mssp.2010.12.004.

R. Longloilert, T. Chaisuwan, A. Luengnaruemitchai and S. Wongkasemjit, J. Sol-Gel Sci. Technol., 61, 133 (2012); doi:10.1007/s10971-011-2602-9.

S. Esposito, M. Turco, G. Bagnasco, C. Cammarano and P. Pernice, Appl. Catal. A, 403, 128 (2011); doi:10.1016/j.apcata.2011.06.024.

A. Kaddouri, N. Dupont, P. Gélin and A. Auroux, Catal. Commun., 15, 32 (2011); doi:10.1016/j.catcom.2011.08.008.

C.J. Brinker and G.W. Scherer, Sol-Gel Science, Academic Press, San Diego (1990).

K. Masuda, T. Sano, F. Mizukami and K. Kuno, Appl. Catal. A, 133, 59 (1995); doi:10.1016/0926-860X(95)00182-4.

N.E. Bogdanchikova, S. Fuentes, M. Avalos-Borja, M.H. Farias, A. Boronin and G. Diaz, Appl. Catal. B, 17, 221 (1998); doi:10.1016/S0926-3373(98)00010-1.

J. Yan, A.M. Buckley and M. Greenblatt, J. Non-Cryst. Solids, 180, 180 (1995); doi:10.1016/0022-3093(94)00476-5.

M.G. Ferreira da Silva and J.M. Fernandez Navarro, J. Non-Cryst. Solids, 100, 447 (1988); doi:10.1016/0022-3093(88)90062-2.

Y. Han, X.Y. Kang, T.D. Wang, Y. Han, M.D. Tao and M.J. Tu, Mater. Res. Bull., 32, 1165 (1997); doi:10.1016/S0025-5408(97)00091-3.

E.A. Meulenkamp, J. Phys. Chem. B, 102, 5566 (1998); doi:10.1021/jp980730h.

L. Khouchaf, M.H. Tuilier, M. Wark, J.J. Paillaud and M. Soulard, J. Phys. IV, 7, C2-267 (1997); doi:10.1051/jp4/1997194.

S. Lu, L. Zhang and X. Yao, Chin. Sci. Bull., 41, 1923 (1996).

C. Cannas, M. Casu, A. Lai, A. Musinu and G. Piccaluga, J. Mater. Chem., 9, 1765 (1999); doi:10.1039/a901001g.

T. López, R. Gomez, M.E. Llanos and E. López-Salinas, Mater. Lett., 38, 283 (1999); doi:10.1016/S0167-577X(98)00174-8.

G. Díaz, R. Pérez-Hernández, A. Gómez-Cortés, M. Benaissa, R. Mariscal and J.L.G. Fierro, J. Catal., 187, 1 (1999); doi:10.1006/jcat.1999.2578.

A.Y. Stakheev, E.S. Shpiro and J. Apijok, J. Phys. Chem., 97, 5668 (1993); doi:10.1021/j100123a034.

C.D. Wagner, D.A. Zatko and R.H. Raymond, Anal. Chem., 52, 1445 (1980); doi:10.1021/ac50059a017.

B.J. Aronson, C.F. Blanford and A. Stein, J. Phys. Chem. B, 104, 449 (2000); doi:10.1021/jp9920343.

F. Pepe, C. Angeletti and S. De Rossi, J. Catal., 118, 1 (1989); doi:10.1016/0021-9517(89)90295-9.

Issue

Vol. 26 No. 15 (2014): Vol 26 Issue 15

Catalytic Properties for Decomposition of sec-Butyl Alcohol Over ZnO@SiO2 Nanocomposites Sol-Gel Catalysts

Corresponding Author(s) : Bing Sun

Abstract

Keywords

Full Article

Download Citation

References

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