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Study of Intermolecular Interaction Between Polyacrylonitrile and Amphoteric Surfactant (Betaine) in Dimethylformamide Medium
Corresponding Author(s) : Said Abdul Nour
Asian Journal of Chemistry,
Vol. 26 No. 15 (2014): Vol 26 Issue 15
Abstract
Monomers of polyacrylonitrile were determined by the use of infrared spectroscopy. Viscosity and specific electrical conductivity of polyacrylonitrile were studied in N,N-dimethylformamide medium at different concentrations and temperatures. The critical micelle concentration of amphoteric surfactant (betaine) was determined in N,N-dimethylformamide medium. It was proved that viscosity and conductivity of polyacrylonitrile solutions containing betaine decrease at the field of critical micelle concentration. Crystalline structure of polyacrylonitrile in the solid phase in the presence of betaine was performed by X-ray diffraction and scanning electron microscope, found that betaine contributes in the development of polymer structure.
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- T. Lodge, Polymer Chemistry, Wood Head Publishing, London, p. 578 (2010).
- C.A. Lawrence, Fundamentals of Spun Yarn Technology, CRC press, New York, p. 191 (2003).
- Q. Liu, M. Xiong, M. Cao and Y. Chen, J. Appl. Polym. Sci., 110, 494 (2008); doi:10.1002/app.28669.
- D. Tong, J. Yao, H. Li and S. Han, J. Appl. Polym. Sci., 102, 3552 (2006); doi:10.1002/app.24812.
- J. Furukawa, Physical Chemistry of Polymer Rheology, Springer, Tokyo, p. 280 (2010).
- K. Kamide and T. Dobashi, Physical Chemistry of Polymer Solutions, Elsevier Science, p. 676 (2000).
- Q. Xu, L. Xu, W. Cao and S. Wu, Polym. Adv. Technol., 16, 642 (2005); doi:10.1002/pat.625.
- D.-G. Yu, G.R. Williams, L.-D. Gao, S.W.A. Bligh, J.-H. Yang and X. Wang, Colloids Surf., 396, 161 (2012); doi:10.1016/j.colsurfa.2011.12.063.
- K. Birdi, Surface and Colloid Chemistry, CRC press, New York, p. 244 (2010).
- S. Voyutsky, Colloid Chemistry, Mir Publisher, Moscow, p. 560 (1978).
- S. Abdul Nour, Ph.D. Thesis, Mendeleev University of Chemical Technology, Moscow (1990).
- J. Jang, J. Bae and E. Park, Adv. Funct. Mater., 16, 1400 (2006); doi:10.1002/adfm.200500598.
- J. Grant, H. Lee, R.C.W. Liu and C. Allen, Biomacromolecules, 9, 2146 (2008); doi:10.1021/bm800219m.
- H. Li, X.- Shen, G.- Gong and D. Wang, Carbohydr. Polym., 73, 191 (2008); doi:10.1016/j.carbpol.2007.11.022.
- A.R. Tehrani-Bagha, H. Bahrami, B. Movassagh, M. Arami, S.H. Amirshahi and F.M. Menger, Colloids Surf., 307, 121 (2007); doi:10.1016/j.colsurfa.2007.05.011.
- B. Falazy and N. Kutaish, Laboratory Experiments in Colloid Chemistry, Aleppo University Publication, Aleppo, p. 285 (1986).
- P. Tong and P. Dublin, Colloid-Polymer Interaction, ACS, Washington, p. 532 (1993).
- X.-H. Qin and S.-Y. Wang, Mater. Lett., 62, 1325 (2008); doi:10.1016/j.matlet.2007.08.047.
References
T. Lodge, Polymer Chemistry, Wood Head Publishing, London, p. 578 (2010).
C.A. Lawrence, Fundamentals of Spun Yarn Technology, CRC press, New York, p. 191 (2003).
Q. Liu, M. Xiong, M. Cao and Y. Chen, J. Appl. Polym. Sci., 110, 494 (2008); doi:10.1002/app.28669.
D. Tong, J. Yao, H. Li and S. Han, J. Appl. Polym. Sci., 102, 3552 (2006); doi:10.1002/app.24812.
J. Furukawa, Physical Chemistry of Polymer Rheology, Springer, Tokyo, p. 280 (2010).
K. Kamide and T. Dobashi, Physical Chemistry of Polymer Solutions, Elsevier Science, p. 676 (2000).
Q. Xu, L. Xu, W. Cao and S. Wu, Polym. Adv. Technol., 16, 642 (2005); doi:10.1002/pat.625.
D.-G. Yu, G.R. Williams, L.-D. Gao, S.W.A. Bligh, J.-H. Yang and X. Wang, Colloids Surf., 396, 161 (2012); doi:10.1016/j.colsurfa.2011.12.063.
K. Birdi, Surface and Colloid Chemistry, CRC press, New York, p. 244 (2010).
S. Voyutsky, Colloid Chemistry, Mir Publisher, Moscow, p. 560 (1978).
S. Abdul Nour, Ph.D. Thesis, Mendeleev University of Chemical Technology, Moscow (1990).
J. Jang, J. Bae and E. Park, Adv. Funct. Mater., 16, 1400 (2006); doi:10.1002/adfm.200500598.
J. Grant, H. Lee, R.C.W. Liu and C. Allen, Biomacromolecules, 9, 2146 (2008); doi:10.1021/bm800219m.
H. Li, X.- Shen, G.- Gong and D. Wang, Carbohydr. Polym., 73, 191 (2008); doi:10.1016/j.carbpol.2007.11.022.
A.R. Tehrani-Bagha, H. Bahrami, B. Movassagh, M. Arami, S.H. Amirshahi and F.M. Menger, Colloids Surf., 307, 121 (2007); doi:10.1016/j.colsurfa.2007.05.011.
B. Falazy and N. Kutaish, Laboratory Experiments in Colloid Chemistry, Aleppo University Publication, Aleppo, p. 285 (1986).
P. Tong and P. Dublin, Colloid-Polymer Interaction, ACS, Washington, p. 532 (1993).
X.-H. Qin and S.-Y. Wang, Mater. Lett., 62, 1325 (2008); doi:10.1016/j.matlet.2007.08.047.