Issue

Vol. 26 No. 15 (2014): Vol 26 Issue 15

Copyright (c) 2014 AJC

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

A Three-Dimensional Supramolecular Network Constructed from Ti(III) Doped Doubly Bridged Molecular Ribbons catena-bis(μ-pyrazine-2,3-dicarboxylato-N,O,O')-Titanium(III)0.15zinc(II)0.85 and Hydrated Proton via Hydrogen Bonding

https://doi.org/10.14233/ajchem.2014.16228
Xiao-Li Zhang
College of Materials Science and Engineering, China Jiliang University, Hangzhou 310018, P.R. China
Ying-Zhi Zhao
College of Materials Science and Engineering, China Jiliang University, Hangzhou 310018, P.R. China
Zhu Zhang
College of Materials Science and Engineering, China Jiliang University, Hangzhou 310018, P.R. China
Kang-Ying Shu
College of Materials Science and Engineering, China Jiliang University, Hangzhou 310018, P.R. China
Wen-Xiang Chai
College of Materials Science and Engineering, China Jiliang University, Hangzhou 310018, P.R. China ;State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P.R. China

Corresponding Author(s) : Wen-Xiang Chai

chaiwx@hotmail.com

Asian Journal of Chemistry, Vol. 26 No. 15 (2014): Vol 26 Issue 15

Abstract

In the title TiIII doped ZnII complex, Ti0.15Zn0.85(C6H2N2O4)2[(H3O)1.85.(H2O)0.15] (1), obtained during exploring new photochromic materials based on TiIII/IV ion, the coordination polyanion ribbons constructed by pyrazine-2,3-dicarboxylato (2,3-PZDC) ligands is balanced with the close-by hydronium cations. The asymmetric unit consists of a half metal center (composed of 15 % TiIII and 85 % ZnII) on the symmetry axis, a 2,3-PZDC ligand and one hydronium cation (2.91 H atoms disordered at three sites). The TiIII/ZnII ion is coordinated by four 2,3-PZDC ligands, giving a distorted Ti(Zn)N2O4 octahedral coordination geometry. The 2,3-PZDC ligand adopts a bridged 3-coordinated mode with one N and 2-carboxyl O atoms biting one metal center and the other 3-carboxyl O atom coordinating a adjacent metal. In addition, the connected mode of 2,3-PZDC ligand could append a p-p stacking interaction of two pyrazine within the doubly ribbons and especially append three strong hydrogen bonding interactions with hydronium cations. These hydrogen bonding interactions play a key role not only in the formation of the three-dimensional supramolecular network but also to the good thermal stability of the molecular structure. The optical absorption properties of powder samples of the title compound have also been studied and the colored profile of the sample also confirms the presence of the TiIII ion, just like a sapphire.

Keywords

TiIII doped ZnII complex Hydrogen bonding Supramolecular network Optical absorption
Zhang, X.-L., Zhao, Y.-Z., Zhang, Z., Shu, K.-Y., & Chai, W.-X. (2014). A Three-Dimensional Supramolecular Network Constructed from Ti(III) Doped Doubly Bridged Molecular Ribbons catena-bis(μ-pyrazine-2,3-dicarboxylato-N,O,O’)-Titanium(III)0.15zinc(II)0.85 and Hydrated Proton via Hydrogen Bonding. Asian Journal of Chemistry, 26(15), 4789–4793. https://doi.org/10.14233/ajchem.2014.16228
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. F.J. Duarte and L.W. Hillman, Dye Laser Principles, Academic, New York (1990).
  2. G. Simon, Mauve: How One Man Invented a Color that Changed the World, Faber and Faber (2000)..
  3. H. Zollinger, Color Chemistry: Synthesis, Properties and Applications of Organic Dyes and Pigments, Weinheim: Wiley-VCH, edn 3 (2003).
  4. K. Hunger, Industrial Dyes: Chemistry, Properties, Applications. Weinheim: Wiley-VCH (2003).
  5. M. Balter, Science, 325, 1329 (2009); doi:10.1126/science.325_1329a.
  6. N.S. Gill, F.B. Taylor, W.E. Hatfield, W.E. Parker, C.S. Fountain and F.L. Bunger, Inorg. Synth., 9, 136 (1967); doi:10.1002/9780470132401.ch37.
  7. A.E. Smith, H. Mizoguchi, K. Delaney, N.A. Spaldin, A.W. Sleight and M.A. Subramanian, J. Am. Chem. Soc., 131, 17084 (2009); doi:10.1021/ja9080666.
  8. H. Mizoguchi, A.W. Sleight and M.A. Subramanian, Inorg. Chem., 50, 10 (2011); doi:10.1021/ic102133z.
  9. T. He and J.N. Yao, Res. Chem. Intermed., 30, 459 (2004); doi:10.1163/1568567041280890.
  10. T. He and J.N. Yao, Prog. Mater. Sci., 51, 810 (2006); doi:10.1016/j.pmatsci.2005.12.001.
  11. J. Lin, W.X. Chai, L. Song, L.S. Qin and K.Y. Shu, Acta Crystallogr. C, 65, o621 (2009); doi:10.1107/S0108270109043339.
  12. Y.Y. Yang, W.X. Chai, L. Song and J. Lin, Acta Crystallogr. C, 67, m293 (2011); doi:10.1107/S0108270111030095.
  13. G.M. Sheldrick, Acta Crystallogr. A, 64, 112 (2008); doi:10.1107/S0108767307043930.
  14. M. Gryz, W. Starosta and J. Leciejewicz, J. Coord. Chem., 58, 931 (2005); doi:10.1080/00958970500055492.
  15. C.J. O'Connor, C.L. Klein, R.J. Majeste and L.M. Trefonas, Inorg. Chem., 21, 64 (1982); doi:10.1021/ic00131a012.
  16. P. Richard, D. Tranqui and E.F. Bertaut, Acta Crystallogr. B, 29, 1111 (1973); doi:10.1107/S056774087300395X.
  17. X. Wang, X.Y. Li, Q.W. Wang and G.B. Che, Acta Crystallogr. E, 64, m1078 (2008); doi:10.1107/S1600536808022824.
  18. J.M. Fang, M.X. Li, X. He, M. Shao, W. Pang and S.R. Zhu, J. Mol. Struct., 921, 137 (2009); doi:10.1016/j.molstruc.2008.12.054.
  19. H. Eshtiagh-Hosseini, H. Aghabozorg and M. Mirzaei, Acta Crystallogr. E, 66, m882 (2010); doi:10.1107/S1600536810025195.
  20. W.X. Chai, J. Lin, L. Song, L.S. Qin, H.S. Shi, J.Y. Guo and K.Y. Shu, Solid State Sci., 14, 1226 (2012); doi:10.1016/j.solidstatesciences.2012.06.002.
  21. W.X. Chai, L. Song, J. Lin, K.Y. Shu, L.S. Qin, H.S. Shi and J.Y. Guo, J. Inorg. Organomet. Polym., 22, 1263 (2012); doi:10.1007/s10904-012-9735-3.
  22. P. van der Sluis and A.L. Spek, Acta Crystallogr. A, 46, 194 (1990); doi:10.1107/S0108767389011189.
  23. W.X. Chai, L. Song, H.Y. Shen and K.Y. Shu, Phosphorus Sulfur Silicon Rel. Elem., 184, 3212 (2009); doi:10.1080/10426500902839400.
  24. W.X. Chai, L. Song, K.Y. Shu, H.S. Shi and L.S. Qin, J. Chem. Crystallogr., 40, 448 (2010); doi:10.1007/s10870-009-9676-z.
  25. J.J. He, W.X. Chai, L. Song, F. Niu and X.B. Fang, Acta Crystallogr. C, 68, m206 (2012); doi:10.1107/S0108270112028442.
Read More
Author biographies is not available.
Download
PDF
Statistic
Read Counter : 0 Download : 1