Copyright (c) 2014 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Chemical Isomerization of Glucose to Fructose Production: A Review
Corresponding Author(s) : Peng Bai
Asian Journal of Chemistry,
Vol. 26 No. 15 (2014): Vol 26 Issue 15
Abstract
Efficient chemical catalyst is becoming a research hotspot in isomerization of glucose to fructose, because the chemical catalyst rather than enzyme has a wider operating temperature range, a longer lifetime and a higher resistance to impurities. The most commonly used chemical catalysts for isomerization of glucose to fructose can be divided into five principal groups, such as homogeneous bases, heterogeneous bases, Lewis acids, aluminates and subcritical water. Thus, the focus of this review is mainly on isomerization of glucose to fructose by using chemical catalysts and mechanistic aspects of the isomerization reaction in order to gather maximum information in one manuscript for a better comprehension of the technological characteristics and specificities of fructose synthesis.
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References
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K. Parker, M. Salas and V.C. Nwosu, Biotechnol. Mol. Biol. Rev., 5, 71 (2010).
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J. Beenackers, B. Kuster and H. van der Baan, Appl. Catal., 16, 75 (1985); doi:10.1016/S0166-9834(00)84071-3.
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J.A. Rendleman Jr. and J.E. Hodge, Carbohydr. Res., 75, 83 (1979); doi:10.1016/S0008-6215(00)84629-7.
J.S. Kruger, V. Nikolakis and D.G. Vlachos, Curr. Opin. Chem. Eng., 1, 312 (2012); doi:10.1016/j.coche.2012.06.003.
E. Nikolla, Y. Román-Leshkov, M. Moliner and M.E. Davis, ACS Catal., 1, 408 (2011); doi:10.1021/cs2000544.
C.M. Lew, N. Rajabbeigi and M. Tsapatsis, Ind. Eng. Chem. Res., 51, 5364 (2012); doi:10.1021/ie2025536.
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F.B. Erich Haack and K. Kohler, US 3256270 (1966).
J.H.G. Leon Tumerman, US3850905 (1974).
A.J. Shaw III and G.T. Tsao, Carbohydr. Res., 60, 376 (1978); doi:10.1016/S0008-6215(78)80045-7.
C. Fabrice, FR2862973 (2003).
A.J. Shaw III and G.T. Tsao, Carbohydr. Res., 60, 327 (1978); doi:10.1016/S0008-6215(78)80039-1.
S. Despax, B. Estrine, N. Hoffmann, J. Le Bras, S. Marinkovic and J. Muzart, Catal. Commun., 39, 35 (2013); doi:10.1016/j.catcom.2013.05.004.
M. Watanabe, Y. Aizawa, T. Iida, T.M. Aida, C. Levy, K. Sue and H. Inomata, Carbohydr. Res., 340, 1925 (2005); doi:10.1016/j.carres.2005.06.017.
M. Watanabe, Y. Aizawa, T. Iida, R. Nishimura and H. Inomata, Appl. Catal. A, 295, 150 (2005); doi:10.1016/j.apcata.2005.08.007.
X. Qi, M. Watanabe, T.M. Aida and R.L. Smith Jr., Catal. Commun., 9, 2244 (2008); doi:10.1016/j.catcom.2008.04.025.
A. Chareonlimkun, V. Champreda, A. Shotipruk and N. Laosiripojana, Fuel, 89, 2873 (2010); doi:10.1016/j.fuel.2010.03.015.
Y. Yu and H. Wu, Ind. Eng. Chem. Res., 50, 10500 (2011); doi:10.1021/ie2011388.
N. Akiya and P.E. Savage, Chem. Rev., 102, 2725 (2002); doi:10.1021/cr000668w.
Y. Kanie, K. Akiyama and M. Iwamoto, Catal. Today, 178, 58 (2011); doi:10.1016/j.cattod.2011.07.031.