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Synthesis and Crystal Structural of 1,10-Phenanthroline Lead(II) Complex
Corresponding Author(s) : Dong Xie
Asian Journal of Chemistry,
Vol. 26 No. 14 (2014): Vol 26 Issue 14
Abstract
A novel lead(II) complex [Pb(phen)2(NO3)]·NO3 has been synthesized, with 1,10-phenanthroline (phen) and nitrate (NO3–) as ligands and characterized by IR spectra and single-crystal X-ray diffraction measurements. The crystal is monoclinic, space group P2(1)/n with unit cell parameters: a =16.6321(18)Å, b = 7.7550(8)Å, c = 18.0809(19)Å, a = 90º, b = 98.2880(10)º, g = 90º, V = 2307.8(4) Å3, Z = 4, Mr = 691.62, Dc = 1.991 Mg/cm3, μ = 7.366 mm-1, F(000) = 1328, T = 298(2) K, R = 0.0795, wR = 0.1980 for 4068 reflections with I > 2s(I). In the molecular structure unit, lead(II) cation is coordinated by six donor atoms.
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- W.T. Deng, J.C. Liu and J. Cao, J. Coord. Chem., 66, 3782 (2013).
- M. Sahin, N. Koçak, D. Erdenay and U. Arslan, Spectrochim. Acta A, 103, 400 (2013).
- N.M. El-Metwaly and M.S. Refat, Spectrochim. Acta A, 81, 519 (2011).
- B.K. Singh, A. Prakash, H.K. Rajour, N. Bhojak and D. Adhikari, Spectrochim. Acta A, 76, 376 (2010).
- F.M. Raquel, E.G. David and B. Andres, Inorg. Chem., 48, 24 (2009).
- H. Khanmohammadi, R. Arabahmadi, M.H. Abnosi and H.R. Khavasi, Polyhedron, 26, 4963 (2007).
- G.M.L. Sheldrick, SHELXS-97 and SHELXL-97, University of Gottingen, Germany (1997)
References
W.T. Deng, J.C. Liu and J. Cao, J. Coord. Chem., 66, 3782 (2013).
M. Sahin, N. Koçak, D. Erdenay and U. Arslan, Spectrochim. Acta A, 103, 400 (2013).
N.M. El-Metwaly and M.S. Refat, Spectrochim. Acta A, 81, 519 (2011).
B.K. Singh, A. Prakash, H.K. Rajour, N. Bhojak and D. Adhikari, Spectrochim. Acta A, 76, 376 (2010).
F.M. Raquel, E.G. David and B. Andres, Inorg. Chem., 48, 24 (2009).
H. Khanmohammadi, R. Arabahmadi, M.H. Abnosi and H.R. Khavasi, Polyhedron, 26, 4963 (2007).
G.M.L. Sheldrick, SHELXS-97 and SHELXL-97, University of Gottingen, Germany (1997)