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Hydrothermal Synthesis and Crystal Structure of Co(II) Coordination Polymer
Corresponding Author(s) : Minghui Zhao
Asian Journal of Chemistry,
Vol. 26 No. 14 (2014): Vol 26 Issue 14
Abstract
A new coordination polymer [Co(BDC)(bimb)]n (1) with 1,3-benzene dicarboxylic acid (H2BDC) and 1,4-bis(1-imidazol-yl)-2,5-dimethyl benzene (bimb) has been has been prepared by hydrothermal synthesis and characterized by single-crystal X-ray diffraction and EA. Complex, [Co(BDC)(bimb)]n (1), is triclinic, space group P-1 with a = 8.792 (5), b = 10.076(5), c = 11.767 (5) Å, a = 85.577(5), b = 82.481 (5)°, g = 74.942(5), V = 997.0 (9) Å3, Z = 2, Mr = 461.33, Dc = 1.537 g/cm3 and F(000) = 474. The final refinement gave R = 0.0411 and wR = 0.0978 for 3634 reflections with I > 2s(I). X-ray diffraction analysis reveals that the complex 1 displays a two-dimensional structure with (4,4)-connected sql topology.
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- C. Janiak, Dalton Trans., 2781 (2003); doi:10.1039/b305705b.
- X. Lin, J.H. Jia, X.B. Zhao, K.M. Thomas, A.J. Blake, G.S. Walker, N.R. Champness, P. Hubberstey and M. Schroder, Angew. Chem. Int. Ed., 45, 7358 (2006); doi:10.1002/anie.200601991.
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- F. Guo, Inorg. Chim. Acta, 399, 79 (2013); doi:10.1016/j.ica.2013.01.003.
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- G.M. Sheldrick, SHELXTL NT, version 5.1; Program for Solution and Refinement of Crystal Structures, University of Göttingen, Germany (1997).
References
C. Janiak, Dalton Trans., 2781 (2003); doi:10.1039/b305705b.
X. Lin, J.H. Jia, X.B. Zhao, K.M. Thomas, A.J. Blake, G.S. Walker, N.R. Champness, P. Hubberstey and M. Schroder, Angew. Chem. Int. Ed., 45, 7358 (2006); doi:10.1002/anie.200601991.
M. Eddaoudi, J. Kim, N. Rosi, D. Vodak, J. Wachter, M. O’Keefe and O.M. Yaghi, Science, 295, 469 (2002); doi:10.1126/science.1067208.
B. Rather and M.J. Zaworotko, Chem. Commun., 830 (2003); doi:10.1039/b301219k.
F. Guo, Inorg. Chim. Acta, 399, 79 (2013); doi:10.1016/j.ica.2013.01.003.
G.L. Xu and F. Guo, Inorg. Chem. Commun., 27, 146 (2013); doi:10.1016/j.inoche.2012.10.025.
J. Li, J. Tao, R.B. Huang and L.S. Zheng, Inorg. Chem., 51, 5988 (2012); doi:10.1021/ic300487a.
A.G. Wong-Foy, A.J. Matzger and O.M. Yaghi, J. Am. Chem. Soc., 128, 3494 (2006); doi:10.1021/ja058213h.
C. Serre, F. Millange, C. Thouvenot, N. Gardant, F. Pellé and G. Férey, J. Mater. Chem., 14, 1540 (2004); doi:10.1039/b312425h.
F. Guo, X.L. Zhang, B.Y. Zhu and J.C. Qiu, J. Inorg. Organomet. Polym., 20, 38 (2010); doi:10.1007/s10904-009-9313-5.
SAINT Software Reference Manual; Bruker AXS: Madison, WI (1998).
G.M. Sheldrick, SHELXTL NT, version 5.1; Program for Solution and Refinement of Crystal Structures, University of Göttingen, Germany (1997).