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Synthesis and Crystal Structure of New (3,5)-Connected Ni(II) Coordination Polymer
Corresponding Author(s) : Minghui Zhao
Asian Journal of Chemistry,
Vol. 26 No. 14 (2014): Vol 26 Issue 14
Abstract
In this paper, a new Ni(II) coordination polymer with 3,4-pyridine dicarboxylic acid(3, 4-PDB) and 1,4-bis (1-imidazol-yl)-2,5-dimethyl benzene (bimb) has been prepared by hydrothermal synthesis and characterized by single-crystal X-ray diffraction, IR and EA. Complex, [Ni(3, 4-PDB)(bimb)(H2O)]n (1), is monoclinic, space group P21/c with a = 10.254 (5), b = 14.219(5), c = 14.288 (5)Å, b = 100.816 (5)°, V = 2046.2(14)Å3, Z = 4, Mr = 480.12, Dc =1.559 g/cm3 and F(000) = 992. The final refinement gave R = 0.0285 and wR = 0.0800 for 4205 reflections with I > 2s(I). X-ray diffraction analysis reveals that the complex 1 displays a new three-dimensional structure with a (3,5)-connected topology.
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References
B.F. Hoskins and R.J. Robson, J. Am. Chem. Soc., 111, 5962 (1989); doi:10.1021/ja00197a079.
B.F. Hoskins and R.J. Robson, J. Am. Chem. Soc., 112, 1546 (1990); doi:10.1021/ja00160a038.
O.M. Yaghi, M. O’Keeffe, N.W. Ockwig, H.K. Chae, M. Eddaoudi and J. Kim, Nature, 423, 705 (2003); doi:10.1038/nature01650.
D.J. Tranchemontagne, J.L. Mendoza-Cortes, M. O’Keeffe and O.M. Yaghi, Chem. Soc. Rev., 38, 1257 (2009); doi:10.1039/b817735j.
J.J. Perry IV, J.A. Perman and M.J. Zaworotko, Chem. Soc. Rev., 38, 1400 (2009); doi:10.1039/b807086p.
J.J. Morris, B.C. Noll and K.W. Henderson, Chem. Commun., 5191 (2007); doi:10.1039/b711668c.
SAINT Software Reference Manual; Bruker AXS: Madison, WI (1998).
G.M. Sheldrick, SHELXTL NT, version 5.1; Program for Solution and Refinement of Crystal Structures, University of Göttingen, Germany (1997).