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Modeling of Heavy Metals Adsorption by Inorganic Particles and Activated Sludge in Domestic Wastewater Treatment Plant
Corresponding Author(s) : Pengzhen Ke
Asian Journal of Chemistry,
Vol. 26 No. 14 (2014): Vol 26 Issue 14
Abstract
In order to verify whether a conventional wastewater treatment process can provide sufficient protective screen of heavy metals, a long-term regular monitoring of different stages of a wastewater treatment plant was conducted. Through a series of adsorption experiments using quartz sand, kaolin of known size distribution as inorganic adsorbents and laboratory-cultured activated sludge as organic adsorbent for adsorbing model of the Cu and Zn, it was found that the adsorption of heavy metals by the inorganic adsorbents well followed by the Langmuir isotherm with the saturation capacity proportional to the specific surface area of the solid particles, indicating a single-layer adsorption property. However for the activated sludge, its adsorption isotherm showed a property of multilayer adsorption and the adsorption capacity was one order higher than the inorganic particles. Models obtained from the adsorption experiment were practical and can provide an approach to predicting the contents of heavy metals in the wastewater treatment plant's effluent.
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- G.E. Üstün, J. Hazard. Mater., 172, 833 (2009); doi:10.1016/j.jhazmat.2009.07.073.
- R.B. Owen and N.S. Sandhu, Mar. Pollut. Bull., 40, 174 (2000); doi:10.1016/S0025-326X(99)00201-5.
- R. Zufiaurre, A. Olivar, P. Chamorro, A. Callizo and R. Zufiaurre, Analyst, 123, 255 (1998); doi:10.1039/a705168i.
- I. Alkorta, J. Hernández-Allica, J.M. Becerril, I. Amezaga, I. Albizu and C. Garbisu, Rev. Environ. Sci. Biotechnol., 3, 71 (2004); doi:10.1023/B:RESB.0000040059.70899.3d.
- Z. Al-Qodah, Desalination, 196, 164 (2006); doi:10.1016/j.desal.2005.12.012.
- M. García-Delgado, M.S. Rodríguez-Cruz, L.F. Lorenzo, M. Arienzo and M.J. Sánchez-Martín, Sci. Total Environ., 382, 82 (2007); doi:10.1016/j.scitotenv.2007.04.009.
- M. Inyang, B. Gao, Y. Yao, Y. Xue, A.R. Zimmerman, P. Pullammanappallil and X. Cao, Bioresour. Technol., 110, 50 (2012); doi:10.1016/j.biortech.2012.01.072.
- H.T.Q. Kieu, E. Müller and H. Horn, Water Res., 45, 3863 (2011); doi:10.1016/j.watres.2011.04.043.
- K.B. Chipasa, Waste Manage., 23, 135 (2003); doi:10.1016/S0956-053X(02)00065-X.
- J. Wang, Water Res., 37, 4835 (2002); doi:10.1016/j.watres.2003.08.021.
- G.P. Sheng, J. Xu, H.W. Luo, W.-W. Li, W.-H. Li, H.-Q. Yu, Z. Xie, S.-Q. Wei and F.-C. Hu, Water Res., 47, 607 (2013); doi:10.1016/j.watres.2012.10.037.
- G. Liu, D. Wang, J. Wang and C. Mendoza, Sci. Total Environ., 409, 2852 (2011); doi:10.1016/j.scitotenv.2011.03.022.
- E. Vaiopoulou and P. Gikas, Water Res., 46, 549 (2012); doi:10.1016/j.watres.2011.11.024.
- V. Ochoa-Herrera, G. León, Q. Banihani, J.A. Field and R. Sierra-Alvarez, Sci. Total Environ., 412-413, 380 (2011); doi:10.1016/j.scitotenv.2011.09.072.
- I. Langmuir, J. Am. Chem. Soc., 40, 1361 (1918); doi:10.1021/ja02242a004.
- J.A. Dean, Lange's Handbook of Chemistry, McGraw-Hill, edn 15 (1999).
References
G.E. Üstün, J. Hazard. Mater., 172, 833 (2009); doi:10.1016/j.jhazmat.2009.07.073.
R.B. Owen and N.S. Sandhu, Mar. Pollut. Bull., 40, 174 (2000); doi:10.1016/S0025-326X(99)00201-5.
R. Zufiaurre, A. Olivar, P. Chamorro, A. Callizo and R. Zufiaurre, Analyst, 123, 255 (1998); doi:10.1039/a705168i.
I. Alkorta, J. Hernández-Allica, J.M. Becerril, I. Amezaga, I. Albizu and C. Garbisu, Rev. Environ. Sci. Biotechnol., 3, 71 (2004); doi:10.1023/B:RESB.0000040059.70899.3d.
Z. Al-Qodah, Desalination, 196, 164 (2006); doi:10.1016/j.desal.2005.12.012.
M. García-Delgado, M.S. Rodríguez-Cruz, L.F. Lorenzo, M. Arienzo and M.J. Sánchez-Martín, Sci. Total Environ., 382, 82 (2007); doi:10.1016/j.scitotenv.2007.04.009.
M. Inyang, B. Gao, Y. Yao, Y. Xue, A.R. Zimmerman, P. Pullammanappallil and X. Cao, Bioresour. Technol., 110, 50 (2012); doi:10.1016/j.biortech.2012.01.072.
H.T.Q. Kieu, E. Müller and H. Horn, Water Res., 45, 3863 (2011); doi:10.1016/j.watres.2011.04.043.
K.B. Chipasa, Waste Manage., 23, 135 (2003); doi:10.1016/S0956-053X(02)00065-X.
J. Wang, Water Res., 37, 4835 (2002); doi:10.1016/j.watres.2003.08.021.
G.P. Sheng, J. Xu, H.W. Luo, W.-W. Li, W.-H. Li, H.-Q. Yu, Z. Xie, S.-Q. Wei and F.-C. Hu, Water Res., 47, 607 (2013); doi:10.1016/j.watres.2012.10.037.
G. Liu, D. Wang, J. Wang and C. Mendoza, Sci. Total Environ., 409, 2852 (2011); doi:10.1016/j.scitotenv.2011.03.022.
E. Vaiopoulou and P. Gikas, Water Res., 46, 549 (2012); doi:10.1016/j.watres.2011.11.024.
V. Ochoa-Herrera, G. León, Q. Banihani, J.A. Field and R. Sierra-Alvarez, Sci. Total Environ., 412-413, 380 (2011); doi:10.1016/j.scitotenv.2011.09.072.
I. Langmuir, J. Am. Chem. Soc., 40, 1361 (1918); doi:10.1021/ja02242a004.
J.A. Dean, Lange's Handbook of Chemistry, McGraw-Hill, edn 15 (1999).