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Vol. 26 No. 14 (2014): Vol 26 Issue 14

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Organic-Inorganic Hybrid Materials Based on Mesoporous Silica MCM-41 with b-Cyclodextrin and its Applications

https://doi.org/10.14233/ajchem.2014.16308
Sana M. Alahmadi
Department of Chemistry, Faculty of Science, University Malaya, Kuala Lumpur 50603, Malaysia; Department of Chemistry, Faculty of Science, Taibah University, Almadina Almonwara 30001, Saudi Arabia
Sharifah Mohamad
Department of Chemistry, Faculty of Science, University Malaya, Kuala Lumpur 50603, Malaysia
Mohd Jamil Maah
Department of Chemistry, Faculty of Science, University Malaya, Kuala Lumpur 50603, Malaysia

Corresponding Author(s) : Sana M. Alahmadi

so2002na@yahoo.com

Asian Journal of Chemistry, Vol. 26 No. 14 (2014): Vol 26 Issue 14

Abstract

This study explained the covalent attachment of b-cyclodextrin on MCM-41 through two different methods. In both methods, a diisocyanate was used as a linker. The modified mesoporous silicates characterized by Fourier transform infrared spectroscopy, thermal analysis and elemental analysis. The FTIR spectra and TGA analysis verified that the b-cyclodextrin was covalently attached to the mesoporous silica while the preservation of the MCM-41 channel system was checked by X-ray diffraction and nitrogen adsorption analysis. These materials were then used to evaluate the sorption properties of some organotin compounds (tributyltin, triphenyltin and dibutyltin). The results showed that mesoporous silica MCM-41 functionalized with b-cyclodextrins, using toluene di-iso-cyanate as a linker (MCM-TDI-b-CD), is a more highly effective sorbent for organotins especially for triphenyltin, compared to mesoporous silica MCM-41 functionalized with b-cyclodextrins using 3-chloropropyltriethoxysilane and toluene di-iso-cyanate as linkers (MCM-PTS-TDI-b-CD).

Keywords

MCM-41 β-Cyclodextrin Organotins
M. Alahmadi, S., Mohamad, S., & Jamil Maah, M. (2014). Organic-Inorganic Hybrid Materials Based on Mesoporous Silica MCM-41 with b-Cyclodextrin and its Applications. Asian Journal of Chemistry, 26(14), 4323–4329. https://doi.org/10.14233/ajchem.2014.16308
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References
  1. D.J. Pine and A. Imhof, Nature, 389, 948 (1997); doi:10.1038/40105.
  2. B.T. Holland, C.F. Blanford and A. Stein, Science, 281, 538 (1998); doi:10.1126/science.281.5376.538.
  3. D. Zhao, J. Feng, Q. Huo, N. Melosh, G.H. Fredrickson, B.F. Chmelka and G.D. Stucky, Science, 279, 548 (1998); doi:10.1126/science.279.5350.548.
  4. M.E. Davis, Nature, 364, 391 (1993); doi:10.1038/364391a0.
  5. J.E. Wijnhoven and W.L. Vos, Science, 281, 802 (1998); doi:10.1126/science.281.5378.802.
  6. C. Kresge, M. Leonowicz, W. Roth, J. Vartuli and J. Beck, Nature, 359, 710 (1992); doi:10.1038/359710a0.
  7. J.S. Beck, J.C. Vartuli, W.J. Roth, M.E. Leonowicz, C.T. Kresge, K.D. Schmitt, C.T.W. Chu, D.H. Olson and E.W. Sheppard, J. Am. Chem. Soc., 114, 10834 (1992); doi:10.1021/ja00053a020.
  8. K.J. van Bommel, A. Friggeri and S. Shinkai, Angew. Chem. Int. Ed., 42, 980 (2003); doi:10.1002/anie.200390284.
  9. X. Feng, G.E. Fryxell, L.Q. Wang, A.Y. Kim, J. Liu and K.M. Kemner, Science, 276, 923 (1997); doi:10.1126/science.276.5314.923.
  10. J. Liu, X. Feng, G.E. Fryxell, L.Q. Wang, A.Y. Kim and M. Gong, Adv. Mater., 10, 161 (1998); doi:10.1002/(SICI)1521-4095(199801)10:2<161::AID-ADMA161>3.0.CO;2-Q.
  11. G.E. Fryxell, J. Liu, T.A. Hauser, Z. Nie, K.F. Ferris, S. Mattigod, M. Gong and R.T. Hallen, Chem. Mater., 11, 2148 (1999); doi:10.1021/cm990104c.
  12. Y. Lin, G.E. Fryxell, H. Wu and M. Engelhard, Environ. Sci. Technol., 35, 3962 (2001); doi:10.1021/es010710k.
  13. B. Lebeau, C.E. Fowler, S.R. Hall and S. Mann, J. Mater. Chem., 9, 2279 (1999); doi:10.1039/a905155d.
  14. D.J. Macquarrie, Chem. Commun., 1961 (1996); doi:10.1039/cc9960001961.
  15. M.H. Lim, C.F. Blanford and A. Stein, Chem. Mater., 10, 467 (1998); doi:10.1021/cm970713p.
  16. L. Mercier and T.J. Pinnavaia, Chem. Mater., 12, 188 (2000); doi:10.1021/cm990532i.
  17. Y. Mori and T.J. Pinnavaia, Chem. Mater., 13, 2173 (2001); doi:10.1021/cm010048r.
  18. M. Kruk, T. Asefa, M. Jaroniec and G.A. Ozin, J. Am. Chem. Soc., 124, 6383 (2002); doi:10.1021/ja025573l.
  19. C. Liu, N. Naismith, L. Fu and J. Economy, Chem. Commun., 1920 (2003); doi:10.1039/b304057g.
  20. S. Alahmad, Oriental J. Chem., 28, 1 (2012); doi:10.13005/ojc/280101.
  21. J. Szejtli, Chem. Rev., 98, 1743 (1998); doi:10.1021/cr970022c.
  22. H. Hashimoto, J. Incl. Phenom. Macrocycl. Chem., 44, 57 (2002); doi:10.1023/A:1023036406829.
  23. M. Ma and D. Li, Chem. Mater., 11, 872 (1999); doi:10.1021/cm981090y.
  24. L. Janus, G. Crini, V. El-Rezzi, M. Morcellet, A. Cambiaghi, G. Torri, A. Naggi and C. Vecchi, React. Funct. Polym., 42, 173 (1999); doi:10.1016/S1381-5148(98)00066-2.
  25. W. Hill, V. Fallourd and D. Klockow, J. Phys. Chem. B, 103, 4707 (1999); doi:10.1021/jp990574u.
  26. R. Huq, L. Mercier and P.J. Kooyman, Chem. Mater., 13, 4512 (2001); doi:10.1021/cm010171i.
  27. C. Liu, J.B. Lambert and L. Fu, J. Org. Chem., 69, 2213 (2004); doi:10.1021/jo0352979.
  28. C. Park, K. Lee and C. Kim, Angew. Chem. Int. Ed., 48, 1275 (2009); doi:10.1002/anie.200803880.
  29. H. Kim, S. Kim, C. Park, H. Lee, H.J. Park and C. Kim, Adv. Mater., 22, 4280 (2010); doi:10.1002/adma.201001417.
  30. W. Guo, J. Wang, S.J. Lee, F. Dong, S.S. Park and C.S. Ha, Chem. Eur. J., 16, 8641 (2010); doi:10.1002/chem.201000980.
  31. Y.S. Chun, K. Ha, Y.-J. Lee, J.S. Lee, H.S. Kim, Y.S. Park and K.B. Yoon, Chem. Commun., 1846 (2002); doi:10.1039/b205046c.
  32. S.M. Alahmadi, Asian J. Chem., 23, 3787 (2011).
  33. G.-B. Jiang, J.-Y. Liu and Q.-F. Zhou, Environ. Sci. Technol., 38, 4349 (2004); doi:10.1021/es049787+.
  34. S.M. Alahmadi, S. Mohamad and M.J. Maah, Int. J. Mol. Sci., 13, 13726 (2012); doi:10.3390/ijms131013726.
  35. M. Yang, Y. Gao, J. He and M. Li, Express Polym. Lett., 1, 433 (2007); doi:10.3144/expresspolymlett.2007.61.
  36. P. Behra, É. Lecarme-Théobald, M. Bueno and J.-J. Ehrhardt, J. Colloid Interf. Sci., 263, 4 (2003); doi:10.1016/S0021-9797(03)00238-8.
  37. R.G. Arnold, J.A. Nelson and J.J. Verbanc, Chem. Rev., 57, 47 (1957); doi:10.1021/cr50013a002.
  38. V.L. Furer, E.I. Borisoglebskaya, V.V. Zverev and V.I. Kovalenko, Spectrochim. Acta A, 63, 207 (2006); doi:10.1016/j.saa.2005.05.006.
  39. V. Caps and S.C. Tsang, Appl. Catal. A, 248, 19 (2003); doi:10.1016/S0926-860X(03)00106-6.
  40. M.D. Alba, Z. Luan and J. Klinowski, J. Phys. Chem., 100, 2178 (1996); doi:10.1021/jp9515895.
  41. S. Shylesh and A.P. Singh, J. Catal., 228, 333 (2004); doi:10.1016/j.jcat.2004.08.037.
  42. A.P. Bhatt, K. Pathak, R.V. Jasra, R.I. Kureshy, N.-H. Khan and S.H.R. Abdi, J. Mol. Catal. Chem., 244, 110 (2006); doi:10.1016/j.molcata.2005.08.045.
  43. P. Oliveira, A. Machado, A. Ramos, I. Fonseca, F. Braz Fernandes, A. Botelho do Rego and J. Vital, Catal. Lett., 114, 192 (2007); doi:10.1007/s10562-007-9059-z.
  44. J. Sauer, F. Marlow and F. Schuth, Phys. Chem. Chem. Phys., 3, 5579 (2001); doi:10.1039/b108435f.
  45. R. Köhn and M. Fröba, Catal. Today, 68, 227 (2001); doi:10.1016/S0920-5861(01)00282-6.
  46. W. Hammond, E. Prouzet, S. Mahanti and T.J. Pinnavaia, Microporous Mesoporous Mater., 27, 19 (1999); doi:10.1016/S1387-1811(98)00222-4.
  47. O. Carmody, R. Frost, Y. Xi and S. Kokot, Surf. Sci., 601, 2066 (2007); doi:10.1016/j.susc.2007.03.004.
  48. J.C.P. Broekhoff, Mesopore Determination from Nitrogen Sorption Isotherms: Fundamentals, Scope, Limitations, pp. 663-684 (1979).
  49. H. Yang, G. Zhang, X. Hong and Y. Zhu, J. Mol. Catal. Chem., 210, 143 (2004); doi:10.1016/j.molcata.2003.09.009.
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