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Vol. 26 No. 14 (2014): Vol 26 Issue 14

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Preparation of Cationic Chitosan-g-Polyacrylamide and its Performance on Strengthening Paper and Antibacterial Activities

https://doi.org/10.14233/ajchem.2014.16079
Yong Lv
Key Laboratory of Eco-textiles, Ministry of Education, Jiangnan University, Wuxi 214122, P.R. China;School of Engineering and Information of Yiwu Industrial & Commercial College, Yiwu 322000, P.R. China
Ci Song
School of Engineering and Information of Yiwu Industrial & Commercial College, Yiwu 322000, P.R. China
Zhu Long
Key Laboratory of Eco-textiles, Ministry of Education, Jiangnan University, Wuxi 214122, P.R. China
Lei Dai
Key Laboratory of Eco-textiles, Ministry of Education, Jiangnan University, Wuxi 214122, P.R. China
Hong He
Key Laboratory of Eco-textiles, Ministry of Education, Jiangnan University, Wuxi 214122, P.R. China
Lina Yu
Key Laboratory of Eco-textiles, Ministry of Education, Jiangnan University, Wuxi 214122, P.R. China
Dan Zhang
Key Laboratory of Eco-textiles, Ministry of Education, Jiangnan University, Wuxi 214122, P.R. China

Corresponding Author(s) : Zhu Long

longzhu@jiangnan.edu.cn

Asian Journal of Chemistry, Vol. 26 No. 14 (2014): Vol 26 Issue 14

Abstract

A novel cationic polymer with long side chains (2,3-epoxypropyltrimethyl ammonium chloride (ETA) modified chitosan-graft-polyacrylamide, typically denoted as CTS-ETA-g-PAM) was prepared by grafting acrylamide onto the cationic modified chitosan. CTS-ETA-g-PAM samples were employed to modify the pulp fibers. The results indicated that: for the reaction of grafting polyacrylamide onto the cationic chitosan, the optimum initiator concentration, the degree of substitution (DS) of CTS-ETA (chitosan-2,3-epoxypropyltrimethyl ammonium chloride), reaction temperature and reaction time were 1.5 mmol/L, 0.369, 35 °C, 5 h, respectively. The CTS-ETA-g-PAM with higher percentage of grafting (PG) possessed more side chains, which could facilitate the formation of larger complexes among the CTS-ETA-g-PAM, microparticles and the fiber fines. The improved fiber wall strength would result in the improvement of the mechanical properties of the handsheets. As the percentage of grafting of CTS-ETA-g-PAM increased, no significant improvement was presented on antibacterial activities. However, the concentration of CTS-ETA-g-PAM had a strong influence on their antibacterial activities.

Keywords

Cationic chitosan Grafting reaction Mechanical properties Antibacterial activities
Lv, Y., Song, C., Long, Z., Dai, L., He, H., Yu, L., & Zhang, D. (2014). Preparation of Cationic Chitosan-g-Polyacrylamide and its Performance on Strengthening Paper and Antibacterial Activities. Asian Journal of Chemistry, 26(14), 4235–4242. https://doi.org/10.14233/ajchem.2014.16079
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