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Synthesis and Crystal Structure of Nickel(II) Complex: [Ni(phen)2(N3)2]
Corresponding Author(s) : Wen-Jie Bi
Asian Journal of Chemistry,
Vol. 26 No. 13 (2014): Vol 26 Issue 13
Abstract
A novel nickel(II) complex [Ni(phen)2(N3)2] has been synthesized, with the 1,10-phenanthroline (phen) and the nitrine (N3-) as ligands and characterized by IR spectra and single-crystal X-ray diffraction measurements. The crystal is triclinic, space group P-1 with cell dimensions of a = 8.2079(7) Å, b = 11.0042(10) Å, c = 12.4317(11) Å, a = 82.259(2)º, b = 82.240(2)º, g = 72.5150(10)º, V = 1055.88(16) Å3, Z = 2, Mr = 503.18, Dc = 1.583 mg/cm3, μ = 0.957 mm-1, F(000) = 516, T = 298(2) K, R = 0.0372, wR = 0.0948 for 5278 reflections with I > 2(I). In the molecular structure unit, nickel(II) cation is coordinated by six donor atoms and has a slightly distorted octahedron configuration.
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References
C.M. Liu, Y.L. Hou, J. Zhang and S. Gao, Inorg. Chem., 41, 140 (2002); doi:10.1021/ic010735k.
L.K. Thompson, Coord. Chem. Rev., 233-234, 193 (2002); doi:10.1016/S0010-8545(02)00101-7.
Z.G. Gu, W. Liu, Q.F. Yang, X.-H. Zhou, J.-L. Zuo and X.-Z. You, Inorg. Chem., 46, 3236 (2007); doi:10.1021/ic062267q.
H. Miyasaka, S. Furukawa, S. Yanagida, K.-i. Sugiura and M. Yamashita, Inorg. Chim. Acta, 357, 1619 (2003); doi:10.1016/j.ica.2003.11.029.
X.C. Yao, L. Zhu, Y. Chen, J. Tian and Y. Wang, Food Chem., 139, 59 (2013); doi:10.1016/j.foodchem.2012.12.045.
K.C. Skyrianou, V. Psycharis, C.P. Raptopoulou, D.P. Kessissoglou and G. Psomas, J. Inorg. Biochem., 105, 63 (2011); doi:10.1016/j.jinorgbio.2010.09.007.
M.C. Rodrìguez-Argüelles, M.B. Ferrari, F. Bisceglie, C. Pelizzi, G. Pelosi, S. Pinelli and M. Sassi, J. Inorg. Biochem., 98, 313 (2004); doi:10.1016/j.jinorgbio.2003.10.006.
H.Z. Dong, W.B. Tao, J. Bi, V. Milway, Z. Xu, S. Zhang, X. Meng, W. Bi, J. Li and M. Li, Nanoscale Res. Lett., 6, 484 (2011); doi:10.1186/1556-276X-6-484.
H.S. Abbo, S.J.J. Titinchi, R. Prasad and S. Chand, J. Mol. Catal. A, 225, 225 (2005); doi:10.1016/j.molcata.2004.09.007.