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Cyanide-Bridged Heterobimetallic Fe(III)-Mn(II) Complex: Synthesis, Crystal Structure and Magnetic Property
Corresponding Author(s) : Daopeng Zhang
Asian Journal of Chemistry,
Vol. 26 No. 13 (2014): Vol 26 Issue 13
Abstract
A cyanide-bridged heterobimetallic trinuclear Fe(III)-Mn(II) complex with the formula {[Fe(pcq)(CN)3]2[Mn(CH3OH)4]}(1) has been synthesized with mer-[PPh4][Fe(pcq)(CN)3] (pcq = 8-(pyridine-2-carboxamido)quinoline anion) as building block and [Mn(ClO4)]2·6H2O as assemble segment. Single X-ray diffraction reveals its neutral trinuclear Fe2Mn nature, in which the two cyanide-containing building blocks acting as a monodentate ligand are coordinated to the central Mn(II) ion. Investigation over its magnetic property shows the antiferromagnetic magnetic coupling between the cyanide-bridged neighboring Fe(III) and Mn(II) ions.
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- M. Verdaguer, A. Bleuzen, V. Marvaud, J. Vaissermann, M. Seuleiman, C. Desplanches, A. Scuiller, C. Train, R. Garde, G. Gelly, C. Lomenech, I. Rosenman, P. Veillet, C. Cartier dit Moulin and F. Villain, Coord. Chem. Rev., 190-192, 1023 (1999); doi:10.1016/S0010-8545(99)00156-3.
- D. Visinescu, O. Fabelo, C. Ruiz-Pérez, F. Lloret and M. Julve, CrystEngComm, 12, 2454 (2010); doi:10.1039/c002305a.
- S. Nastase, S.C. Maxim, M. Andruh, J. Cano, C. Ruiz-Pérez, J. Faus, F. Lloret and M. Julve, Dalton Trans., 40, 4898 (2011); doi:10.1039/c0dt01815e.
- W. Kosaka, K. Imoto, Y. Tsunobuchi and S.I. Ohkoshi, Inorg. Chem., 48, 4604 (2009); doi:10.1021/ic9001576.
- C.-G. Freiherr von Richthofen, A. Stammler, H. Bögge, M.W. DeGroot, J.R. Long and T. Glaser, Inorg. Chem., 48, 10165 (2009); doi:10.1021/ic901148q.
- M. Shatruk, C. Avendano and K.R. Dunbar, Prog. Inorg. Chem., 56, 155 (2009); doi:10.1002/9780470440124.ch3.
- Z.H. Ni, H.Z. Kou, L.F. Zhang, W.W. Ni, Y.B. Jiang, A.L. Cui, J. Ribas and O. Sato, Inorg. Chem., 44, 9631 (2005); doi:10.1021/ic051385v.
- J.I. Kim, H.S. Yoo, E.K. Koh, H.C. Kim and C.S. Hong, Inorg. Chem., 46, 8481 (2007); doi:10.1021/ic701361a.
- J.I. Kim, H.Y. Kwak, J.H. Yoon, D.W. Ryu, I.Y. Yoo, N. Yang, B.K. Cho, J.-G. Park, H. Lee and C.S. Hong, Inorg. Chem., 48, 2956 (2009); doi:10.1021/ic802033q.
- I.Y. Yoo, D. Won Ryu, J. Hee Yoon, A. Ram Sohn, K. Soo Lim, B. Ki Cho, E. Kwan Koh and C. Seop Hong, Dalton Trans., 41, 1776 (2012); doi:10.1039/c1dt11293g.
- T. Senapati, C. Pichon, R. Ababei, C. Mathonière and R. Clérac, Inorg. Chem., 51, 3796 (2012); doi:10.1021/ic2027708.
- A. Panja, P. Guionneau, I.-R. Jeon, S.M. Holmes, R. Clérac and C. Mathonière, Inorg. Chem., 51, 12350 (2012); doi:10.1021/ic301661x.
- G.M. Sheldrick, SHELXTL97, Program for the Refinement of Crystal Structure, University of Göttingen, Germany (1997).
- D. Zhang, H. Wang, Y. Chen, L. Zhang, L. Tian, Z.-H. Ni and J. Jiang, Dalton Trans., 9418 (2009); doi:10.1039/b909717a.
- D.P. Zhang, L.F. Zhang, X. Chen and Z.H. Ni, Transition Metal Chem., 36, 539 (2011); doi:10.1007/s11243-011-9500-4.
References
M. Verdaguer, A. Bleuzen, V. Marvaud, J. Vaissermann, M. Seuleiman, C. Desplanches, A. Scuiller, C. Train, R. Garde, G. Gelly, C. Lomenech, I. Rosenman, P. Veillet, C. Cartier dit Moulin and F. Villain, Coord. Chem. Rev., 190-192, 1023 (1999); doi:10.1016/S0010-8545(99)00156-3.
D. Visinescu, O. Fabelo, C. Ruiz-Pérez, F. Lloret and M. Julve, CrystEngComm, 12, 2454 (2010); doi:10.1039/c002305a.
S. Nastase, S.C. Maxim, M. Andruh, J. Cano, C. Ruiz-Pérez, J. Faus, F. Lloret and M. Julve, Dalton Trans., 40, 4898 (2011); doi:10.1039/c0dt01815e.
W. Kosaka, K. Imoto, Y. Tsunobuchi and S.I. Ohkoshi, Inorg. Chem., 48, 4604 (2009); doi:10.1021/ic9001576.
C.-G. Freiherr von Richthofen, A. Stammler, H. Bögge, M.W. DeGroot, J.R. Long and T. Glaser, Inorg. Chem., 48, 10165 (2009); doi:10.1021/ic901148q.
M. Shatruk, C. Avendano and K.R. Dunbar, Prog. Inorg. Chem., 56, 155 (2009); doi:10.1002/9780470440124.ch3.
Z.H. Ni, H.Z. Kou, L.F. Zhang, W.W. Ni, Y.B. Jiang, A.L. Cui, J. Ribas and O. Sato, Inorg. Chem., 44, 9631 (2005); doi:10.1021/ic051385v.
J.I. Kim, H.S. Yoo, E.K. Koh, H.C. Kim and C.S. Hong, Inorg. Chem., 46, 8481 (2007); doi:10.1021/ic701361a.
J.I. Kim, H.Y. Kwak, J.H. Yoon, D.W. Ryu, I.Y. Yoo, N. Yang, B.K. Cho, J.-G. Park, H. Lee and C.S. Hong, Inorg. Chem., 48, 2956 (2009); doi:10.1021/ic802033q.
I.Y. Yoo, D. Won Ryu, J. Hee Yoon, A. Ram Sohn, K. Soo Lim, B. Ki Cho, E. Kwan Koh and C. Seop Hong, Dalton Trans., 41, 1776 (2012); doi:10.1039/c1dt11293g.
T. Senapati, C. Pichon, R. Ababei, C. Mathonière and R. Clérac, Inorg. Chem., 51, 3796 (2012); doi:10.1021/ic2027708.
A. Panja, P. Guionneau, I.-R. Jeon, S.M. Holmes, R. Clérac and C. Mathonière, Inorg. Chem., 51, 12350 (2012); doi:10.1021/ic301661x.
G.M. Sheldrick, SHELXTL97, Program for the Refinement of Crystal Structure, University of Göttingen, Germany (1997).
D. Zhang, H. Wang, Y. Chen, L. Zhang, L. Tian, Z.-H. Ni and J. Jiang, Dalton Trans., 9418 (2009); doi:10.1039/b909717a.
D.P. Zhang, L.F. Zhang, X. Chen and Z.H. Ni, Transition Metal Chem., 36, 539 (2011); doi:10.1007/s11243-011-9500-4.