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Synthesis, Characterization and X-Ray Crystal Structure of Copper Complex with 18-Crown-6
Corresponding Author(s) : Imdad Hussain
Asian Journal of Chemistry,
Vol. 26 No. 13 (2014): Vol 26 Issue 13
Abstract
A 1:1 crystal of 18-crown-6 with copper has been obtained by stirring and refluxing equimolar quantities of methanolic solution of 18-crown-6 and Cu(NO3)2 overnight. Cu-18-crown-6 complex is a crystalline solid of blue colour. The complex crystallizes in the monoclinic space group P 2 1/n, with unit cell parameters a = 10.0228(7) Å, b = 12.9341(9) Å, c = 16.7351(12)Å, a = 90.00, b = 92.089(1), g = 90.00, Z = 4, V = 2168.0 (3) Å3. Copper metal does not fit into the cavity of 18-crown-6, because the cavity size of the 18-crown-6 is bigger than the size of the copper atom. So copper metal is coordinated by water molecule and that water molecules are further connected with 18-crown-6 through hydrogenbonding between water coordinated with copper metal and oxygen atoms of the crown ether. The complex was characterized by using single crystal X-ray spectroscopy, TGA, UV-spectroscopy, IR-spectroscopy and atomic absorption spectroscopy.
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- I. Batinic-Haberle and A.L. Crumbliss, Inorg. Chem., 34, 928 (1995); doi:10.1021/ic00108a026.
- H.M. Colquhoun, D.F. Lewis, J.F. Stoddart and D.J. Williams, J. Chem. Soc., Dalton Trans., 607 (1983); doi:10.1039/dt9830000607.
- H.M. Colquhoun, J.F. Stoddart and D.J. Williams, J. Chem. Soc. Chem. Commun., 851 (1981); doi:10.1039/c39810000851.
- H.M. Colquhoun, J.F. Stoddart, D.J. Williams, J.B. Wolstenholme and R. Zarzycki, Angew. Chem. Int. Ed. Engl., 20, 1051 (1981); doi:10.1002/anie.198110511.
- P.A. Cusack, B.N. Patel, P.J. Smith, D.W. Allen and I.W. Nowell, J. Chem. Soc., Dalton Trans., 1239 (1984); doi:10.1039/dt9840001239.
- I. Ando, M. Higashi, K. Ujimoto and H. Kurihara, Inorg. Chim. Acta, 282, 247 (1998); doi:10.1016/S0020-1693(98)00241-2.
- T.G. Chulkova, P.V. Gushchin, M. Haukka and V.Yu. Kukushkin, Inorg. Chem. Commun., 13, 580 (2010); doi:10.1016/j.inoche.2010.02.008.
- V.Yu. Kukushkin, D. Tudela and A.J.L. Pombeiro, Coord. Chem. Rev., 156, 333 (1996); doi:10.1016/0010-8545(95)01234-6.
- V.Yu. Kukushkin and A.J.L. Pombeiro, Coord. Chem. Rev., 181, 147 (1999); doi:10.1016/S0010-8545(98)00215-X.
- M.N. Kopylovich, V.Yu. Kukushkin, M. Haukka, K.V. Luzyanin and A.J.L. Pombeiro, J. Am. Chem. Soc., 126, 15040 (2004); doi:10.1021/ja046759i.
- K.V. Luzyanin, V.Yu. Kukushkin, M.L. Kuznetsov, D.A. Garnovskii, M. Haukka and A.J.L. Pombeiro, Inorg. Chem., 41, 2981 (2002); doi:10.1021/ic025554c.
- V.Yu. Kukushkin, T. Nishioka, D. Tudela, K. Isobe and I. Kinoshita, Inorg. Chem., 36, 6157 (1997); doi:10.1021/ic970501u.
- V.Yu. Kukushkin, D. Tudela, Y.A. Izotova, V.K. Belsky and A.I. Stash, Polyhedron, 17, 2455 (1998); doi:10.1016/S0277-5387(98)00041-2.
- Bruker, APEX2, GIS, SADABS and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA (2009).
- G.M. Sheldrick, Acta Crystallogr. A, 64, 112 (2008); doi:10.1107/S0108767307043930.
- L.J. Farrugia, J. Appl. Cryst., 32, 837 (1999); doi:10.1107/S0021889899006020.
- G.M. Sheldrick, SADABS-Bruker AXS Scaling and Absorption Correction, Bruker AXS Inc., Madison (2008).
- K. Brandenburg, Diamond-Crystal and Molecular Structure Visualization, v. 3.2g. Crystal Impact GbR, Bonn (2011).
- J.D. Dunitz, P. Seiler and R.P. Phizackerley, Acta Crystallogr. B, 30, 2739 (1974); doi:10.1107/S0567740874007916.
References
I. Batinic-Haberle and A.L. Crumbliss, Inorg. Chem., 34, 928 (1995); doi:10.1021/ic00108a026.
H.M. Colquhoun, D.F. Lewis, J.F. Stoddart and D.J. Williams, J. Chem. Soc., Dalton Trans., 607 (1983); doi:10.1039/dt9830000607.
H.M. Colquhoun, J.F. Stoddart and D.J. Williams, J. Chem. Soc. Chem. Commun., 851 (1981); doi:10.1039/c39810000851.
H.M. Colquhoun, J.F. Stoddart, D.J. Williams, J.B. Wolstenholme and R. Zarzycki, Angew. Chem. Int. Ed. Engl., 20, 1051 (1981); doi:10.1002/anie.198110511.
P.A. Cusack, B.N. Patel, P.J. Smith, D.W. Allen and I.W. Nowell, J. Chem. Soc., Dalton Trans., 1239 (1984); doi:10.1039/dt9840001239.
I. Ando, M. Higashi, K. Ujimoto and H. Kurihara, Inorg. Chim. Acta, 282, 247 (1998); doi:10.1016/S0020-1693(98)00241-2.
T.G. Chulkova, P.V. Gushchin, M. Haukka and V.Yu. Kukushkin, Inorg. Chem. Commun., 13, 580 (2010); doi:10.1016/j.inoche.2010.02.008.
V.Yu. Kukushkin, D. Tudela and A.J.L. Pombeiro, Coord. Chem. Rev., 156, 333 (1996); doi:10.1016/0010-8545(95)01234-6.
V.Yu. Kukushkin and A.J.L. Pombeiro, Coord. Chem. Rev., 181, 147 (1999); doi:10.1016/S0010-8545(98)00215-X.
M.N. Kopylovich, V.Yu. Kukushkin, M. Haukka, K.V. Luzyanin and A.J.L. Pombeiro, J. Am. Chem. Soc., 126, 15040 (2004); doi:10.1021/ja046759i.
K.V. Luzyanin, V.Yu. Kukushkin, M.L. Kuznetsov, D.A. Garnovskii, M. Haukka and A.J.L. Pombeiro, Inorg. Chem., 41, 2981 (2002); doi:10.1021/ic025554c.
V.Yu. Kukushkin, T. Nishioka, D. Tudela, K. Isobe and I. Kinoshita, Inorg. Chem., 36, 6157 (1997); doi:10.1021/ic970501u.
V.Yu. Kukushkin, D. Tudela, Y.A. Izotova, V.K. Belsky and A.I. Stash, Polyhedron, 17, 2455 (1998); doi:10.1016/S0277-5387(98)00041-2.
Bruker, APEX2, GIS, SADABS and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA (2009).
G.M. Sheldrick, Acta Crystallogr. A, 64, 112 (2008); doi:10.1107/S0108767307043930.
L.J. Farrugia, J. Appl. Cryst., 32, 837 (1999); doi:10.1107/S0021889899006020.
G.M. Sheldrick, SADABS-Bruker AXS Scaling and Absorption Correction, Bruker AXS Inc., Madison (2008).
K. Brandenburg, Diamond-Crystal and Molecular Structure Visualization, v. 3.2g. Crystal Impact GbR, Bonn (2011).
J.D. Dunitz, P. Seiler and R.P. Phizackerley, Acta Crystallogr. B, 30, 2739 (1974); doi:10.1107/S0567740874007916.