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Vol. 26 No. 11 (2014): Vol 26 Issue 11

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Preparation and Properties of Novel Starch Derivatives Containing the Sulfonic Acid of the Group and Carboxymethyl

https://doi.org/10.14233/ajchem.2014.15869
Cheng-Li Ding
E-421 Chemicals Experiment Building, State Key Laboratory of Fine Chemicals, Dalian University of Technology, West Campus, 2# Linggong Road, Dalian 116024, P.R. China
Ben-Zhi Ju
E-421 Chemicals Experiment Building, State Key Laboratory of Fine Chemicals, Dalian University of Technology, West Campus, 2# Linggong Road, Dalian 116024, P.R. China
Shu-Fen Zhang
E-421 Chemicals Experiment Building, State Key Laboratory of Fine Chemicals, Dalian University of Technology, West Campus, 2# Linggong Road, Dalian 116024, P.R. China

Corresponding Author(s) : Ben-Zhi Ju

jubenzhi@dlut.edu.cn

Asian Journal of Chemistry, Vol. 26 No. 11 (2014): Vol 26 Issue 11

Abstract

In this study, novel anionic starch derivatives (2,4-bis(diiminobenzenesulfonic acid disodium salt)[1,3,5]triazine-6-yl)-carboxymethyl starch (BSTS-CMS) were prepared by the reaction of 2,4-bis(diiminobenzenesulfonic acid disodium salt)-6-chloro[1,3,5]triazine (BSTS) with carboxymethyl starch. The molecular weight of the samples with different degrees of substitution (DS) was analyzed by GPC and the structure was characterized by FT-IR. The thermal stability was investigated by non-isothermal thermogravimetry. The results showed that the BSTS-CMS had higher molecular weight (Mw × 106 = 3.12-3.56). The different degrees of substitution sample exhibited better temperature resistance properties compared with carboxymethyl starch. The viscosity of sample has the excellent stability towards pH 2-12. In addition, the thermogravimetric analysis of BSTS-CMS proved that it has good thermal stability compared with starch and carboxymethyl starch.

Keywords

Carboxymethyl starch Sulfonic acid group S-Triazine Thermal stability
Ding, C.-L., Ju, B.-Z., & Zhang, S.-F. (2014). Preparation and Properties of Novel Starch Derivatives Containing the Sulfonic Acid of the Group and Carboxymethyl. Asian Journal of Chemistry, 26(11), 3166–3170. https://doi.org/10.14233/ajchem.2014.15869
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