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Hydrolysis Kinetics of Chloroacetic Acid with Sodium Hydroxide Under Strong Alkaline Conditions
Corresponding Author(s) : Xuan Qi
Asian Journal of Chemistry,
Vol. 26 No. 11 (2014): Vol 26 Issue 11
Abstract
The hydrolysis of chloroacetic acid and sodium hydroxide is carried out at 45-85 ºC by using equal mole of sodium chloroacetate and alkali. Using reasonable approximation, the hydrolysis reaction is proved to be a second-order reaction when the conversion is less than 95 % and the kinetic rate coefficients are determined. The activate energy is calculated 103 kJ mol-1.
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- A.B.M. Fakrul Alam and M.I.H. Mondal, J. Appl. Polym. Sci., 128, 1206 (2013); doi:10.1002/app.38446.
- D.C. Dash, R.K. Mohapatra, S. Ghosh and P. Naik, J. Indian Chem. Soc., 86, 121 (2009).
- I.O. Lebedyeva, M.V. Povstyanoy, A.B. Ryabitskii and V.M. Povstyanoy, J. Heterocycl. Chem., 47, 368 (2010); doi:10.1002/jhet.323.
- S.S. Vaghani, M. M. Patel, C. S. Satish, K. M. Patel and N. P. Jivani, Curr. Drug Deliv., 9, 628 (2012); doi:10.2174/156720112803529837.
- L.F. Berhenke and E.C. Britton, Ind. Eng. Chem., 38, 544 (1946); doi:10.1021/ie50437a027.
- S.C. Yu, M.L. Lu and R.N. Xu, Huadong Shifan Daxue Xuebao, 70 (1984) (in Chinese).
- J.Y. Xu and H. P. Wang, Anhui Hua Gong, 36 (1990) (in Chinese).
References
A.B.M. Fakrul Alam and M.I.H. Mondal, J. Appl. Polym. Sci., 128, 1206 (2013); doi:10.1002/app.38446.
D.C. Dash, R.K. Mohapatra, S. Ghosh and P. Naik, J. Indian Chem. Soc., 86, 121 (2009).
I.O. Lebedyeva, M.V. Povstyanoy, A.B. Ryabitskii and V.M. Povstyanoy, J. Heterocycl. Chem., 47, 368 (2010); doi:10.1002/jhet.323.
S.S. Vaghani, M. M. Patel, C. S. Satish, K. M. Patel and N. P. Jivani, Curr. Drug Deliv., 9, 628 (2012); doi:10.2174/156720112803529837.
L.F. Berhenke and E.C. Britton, Ind. Eng. Chem., 38, 544 (1946); doi:10.1021/ie50437a027.
S.C. Yu, M.L. Lu and R.N. Xu, Huadong Shifan Daxue Xuebao, 70 (1984) (in Chinese).
J.Y. Xu and H. P. Wang, Anhui Hua Gong, 36 (1990) (in Chinese).