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Synthesis and Characterization of Carbon Fiber Functionalized with Poly(glycidyl methacrylate) via Catalytic Chain Transfer Polymerization
Corresponding Author(s) : Lei Xiong
Asian Journal of Chemistry,
Vol. 26 No. 11 (2014): Vol 26 Issue 11
Abstract
Catalytic chain transfer polymerization (CCTP) is an extremely efficient process to produce low-molecular weight polymers. In this paper, we reported a controllable synthesis of carbon fibers functionalized with poly(glycidyl methacrylate) (CF-PGMA) by using cobalt oxime boron fluoride (CoBF) as a chain transfer catalyst via catalytic chain transfer polymerization. In a typical run, the carbon fiber was first oxidized with a mixture of nitric acid and sulfuric acid (1:3) to introduce hydroxyl groups onto the carbon fiber surface. Subsequently, 3-(trimethoxysilyl)propylmethacrylate (KH570) was grafted onto the carbon fiber surface by chemical reaction of hydroxyl groups with the silane coupling agent. Finally, CF-PGMA was prepared by poly(glycidyl methacrylate) surface-grafted onto the carbon fiber via catalytic chain transfer polymerization and was characterized by FT-IR, TGA and XPS. The results show that the carbon fiber functionalized with poly(glycidyl methacrylate) was synthesized successfully and the content of grafted polymers was about 36.4 %.
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- S.J. Park, M.K. Seo and Y.S. Lee, Carbon, 41, 723 (2003); doi:10.1016/S0008-6223(02)00384-6.
- H. Ogawa and K. Saito, Carbon, 33, 783 (1995); doi:10.1016/0008-6223(95)00007-Z.
- Z.H. Wu, C.U. Pittman Jr. and S.D. Gardner, Carbon, 33, 597 (1995); doi:10.1016/0008-6223(95)00145-4.
- C. Marieta, E. Schulz, L. Irusta, N. Gabilondo, A. Tercjak and I. Mondragon, Compos. Sci. Technol., 65, 2189 (2005); doi:10.1016/j.compscitech.2005.05.008.
- S. Yumitori and Y. Nakanishi, Composites Part A, 27, 1059 (1996); doi:10.1016/1359-835X(96)00058-9.
- M. Toyoda, H. Katoh and M. Inagaki, Carbon, 39, 2231 (2001); doi:10.1016/S0008-6223(01)00209-3.
- C.U. Pittman Jr., W. Jiang, Z.R. Yue, S. Gardner, L. Wang, H. Toghiani and C.A. Leon, Carbon, 37, 1797 (1999); doi:10.1016/S0008-6223(99)00048-2.
- G.M. Wu, Mater. Chem. Phys., 85, 81 (2004); doi:10.1016/j.matchemphys.2003.12.004.
- Y.V. Basova, H. Hatori, Y. Yamada and K. Miyashita, Electrochem. Commun., 1, 540 (1999); doi:10.1016/S1388-2481(99)00112-5.
- E. Theodoridou, A.D. Jannakoudakis, P.D. Jannakoudakis, P. Andonoglou and J.O. Besenhard, Synth. Met., 87, 225 (1997); doi:10.1016/S0379-6779(97)80113-0.
- M.B. Ivanov, N.V. Gavrilov, T.A. Belyh, E.A. Ligacheva, L.V. Galijeva, A.E. Ligachev and V.V. Sohoreva, Surf. Coat. Technol., 201, 8326 (2007); doi:10.1016/j.surfcoat.2006.12.034.
- N. Dilsiz, N.K. Erinc, E. Bayramli and G. Akovali, Carbon, 33, 853 (1995); doi:10.1016/0008-6223(94)00181-X.
- L. Xiong, X.F. Li, H.B. Liang and S.M. Huang, Asian J. Chem, 25, 4032 (2013); doi:10.14233/ajchem.2013.13946.
- A. Bakac and J.H. Espenson, J. Am. Chem. Soc., 106, 5197 (1984); doi:10.1021/ja00330a027.
References
S.J. Park, M.K. Seo and Y.S. Lee, Carbon, 41, 723 (2003); doi:10.1016/S0008-6223(02)00384-6.
H. Ogawa and K. Saito, Carbon, 33, 783 (1995); doi:10.1016/0008-6223(95)00007-Z.
Z.H. Wu, C.U. Pittman Jr. and S.D. Gardner, Carbon, 33, 597 (1995); doi:10.1016/0008-6223(95)00145-4.
C. Marieta, E. Schulz, L. Irusta, N. Gabilondo, A. Tercjak and I. Mondragon, Compos. Sci. Technol., 65, 2189 (2005); doi:10.1016/j.compscitech.2005.05.008.
S. Yumitori and Y. Nakanishi, Composites Part A, 27, 1059 (1996); doi:10.1016/1359-835X(96)00058-9.
M. Toyoda, H. Katoh and M. Inagaki, Carbon, 39, 2231 (2001); doi:10.1016/S0008-6223(01)00209-3.
C.U. Pittman Jr., W. Jiang, Z.R. Yue, S. Gardner, L. Wang, H. Toghiani and C.A. Leon, Carbon, 37, 1797 (1999); doi:10.1016/S0008-6223(99)00048-2.
G.M. Wu, Mater. Chem. Phys., 85, 81 (2004); doi:10.1016/j.matchemphys.2003.12.004.
Y.V. Basova, H. Hatori, Y. Yamada and K. Miyashita, Electrochem. Commun., 1, 540 (1999); doi:10.1016/S1388-2481(99)00112-5.
E. Theodoridou, A.D. Jannakoudakis, P.D. Jannakoudakis, P. Andonoglou and J.O. Besenhard, Synth. Met., 87, 225 (1997); doi:10.1016/S0379-6779(97)80113-0.
M.B. Ivanov, N.V. Gavrilov, T.A. Belyh, E.A. Ligacheva, L.V. Galijeva, A.E. Ligachev and V.V. Sohoreva, Surf. Coat. Technol., 201, 8326 (2007); doi:10.1016/j.surfcoat.2006.12.034.
N. Dilsiz, N.K. Erinc, E. Bayramli and G. Akovali, Carbon, 33, 853 (1995); doi:10.1016/0008-6223(94)00181-X.
L. Xiong, X.F. Li, H.B. Liang and S.M. Huang, Asian J. Chem, 25, 4032 (2013); doi:10.14233/ajchem.2013.13946.
A. Bakac and J.H. Espenson, J. Am. Chem. Soc., 106, 5197 (1984); doi:10.1021/ja00330a027.