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Hydrothermal Synthesis and Crystal Structure of Novel Mn(II) Coordination Polymer Based on 4,4'-Bis(imidazolyl)biphenyl and Trimesic Acid
Corresponding Author(s) : Guanglong Zou
Asian Journal of Chemistry,
Vol. 26 No. 10 (2014): Vol 26 Issue 10
Abstract
In this paper, a new Mn(II) coordination polymer with 4,4'-bis(imidazolyl)biphenyl (bib) and trimesic acid (H3bct) has been has been prepared by hydrothermal synthesis and characterized by single-crystal X-ray diffraction, IR and EA. Complex, [Mn(Hbta)(bib)]n (1), is monoclinic, space group P21/c with a = 9.380 (5), b = 10.226 (5), c = 12.590 (5)Å, b = 86.079 (5)°, V = 1169.3 (10)Å3, Z = 2, Mr = 549.39, Dc =1.560 g/cm3 and F(000) = 562. The final refinement gave R = 0.0333 and wR = 0.0875 for 4708 reflections with I > 2s(I). X-ray diffraction analysis reveals that the complex 1 displays a two-dimensional layer structure.
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- P. Kanoo, G. Mostafa, R. Matsuda, S. Kitagawa and T. K. Maji, Chem. Commun., 47, 8106 (2011); doi:10.1039/c1cc11416f.
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- J. Li, J. Tao, R.B. Huang and L.S. Zheng, Inorg. Chem., 51, 5988 (2012); doi:10.1021/ic300487a.
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- M. Du, X.J. Zhao and Y. Wang, Dalton Trans., 2065 (2004); doi:10.1039/b403498h.
- W.W. Jia, J.H. Luo and M.L. Zhu, Cryst. Growth Des., 11, 2386 (2011); doi:10.1021/cg200142f.
- SAINT Software Reference Manual; Bruker AXS: Madison, WI (1998).
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References
P. Kanoo, G. Mostafa, R. Matsuda, S. Kitagawa and T. K. Maji, Chem. Commun., 47, 8106 (2011); doi:10.1039/c1cc11416f.
H. Yang, F. Wang, Y. Kang, T.H. Li and J. Zhang, Dalton Trans., 41, 2873 (2012); doi:10.1039/c2dt12261h.
J. Qin, C. Qin, C.-X. Wang, H. Li, L. Cui, T.-T. Li and X.-L. Wang, CrystEngComm, 12, 4071 (2010); doi:10.1039/c0ce00582g.
Z.Y. Du, H.B. Xu and J.G. Mao, Inorg. Chem., 45, 9780 (2006); doi:10.1021/ic0613255.
J. Li, J. Tao, R.B. Huang and L.S. Zheng, Inorg. Chem., 51, 5988 (2012); doi:10.1021/ic300487a.
J.E.W. Cull, F. Habib and I. Korobkov, M. Murugesu and J. Scott, Inorg. Chim. Acta, 370, 98 (2011); doi:10.1016/j.ica.2011.01.032.
S. Zheng, T. Wu, F. Zuo, C.T. Chou, P. Feng and X. Bu, J. Am. Chem. Soc., 134, 1934 (2012); doi:10.1021/ja209800x.
H.X. Zhang, F. Wang, H. Yang, Y.X. Tan, J. Zhang and X. Bu, J. Am. Chem. Soc., 133, 11884 (2011); doi:10.1021/ja2040927.
F. Guo, X.L. Zhang, B.Y. Zhu and J.C. Qiu, J. Inorg. Organomet. Polym., 20, 38 (2010); doi:10.1007/s10904-009-9313-5.
M. Du, X.J. Zhao and Y. Wang, Dalton Trans., 2065 (2004); doi:10.1039/b403498h.
W.W. Jia, J.H. Luo and M.L. Zhu, Cryst. Growth Des., 11, 2386 (2011); doi:10.1021/cg200142f.
SAINT Software Reference Manual; Bruker AXS: Madison, WI (1998).
G.M. Sheldrick, SHELXTL NT, version 5.1; Program for Solution and Refinement of Crystal Structures; University of Göttingen: Göttingen, Germany (1997).