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Vol. 26 No. 10 (2014): Vol 26 Issue 10

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Thermodynamic Characterization on Surface of Iron Oxide Nanoparticles Prepared by Co-precipitation: An Inverse Gas Chromatography Application

https://doi.org/10.14233/ajchem.2014.16625
Seda Beyaz
Balikesir University, Department of Chemistry, 10145 Cagis Campus, Balikesir, Turkey
Ferdane Karaman
Yildiz Technical University, Department of Chemistry, 34220 Davutpasa Campus, Istanbul, Turkey

Corresponding Author(s) : Seda Beyaz

sedacan@balikesir.edu.tr; polymer22@hotmail.com

Asian Journal of Chemistry, Vol. 26 No. 10 (2014): Vol 26 Issue 10

Abstract

Surface thermodynamics of magnetic particles are crucial for many applications. In this study, a series of magnetic iron oxide nanoparticles were synthesized by co-precipitation at room temperature varying iron salts and base concentrations. The retention times of several organic solvents on these iron oxide nanoparticles were obtained in the temperature range from 323 to 363 K by inverse gas chromatography at infinite dilution. The dispersive component of surface free energy, gSD, thermodynamic parameters of adsorption (free energy, DGSP, enthalpy DHSP, entropy, DSSP) and the acid KA and base KD constants were calculated for iron oxide samples. It was found that gSD values fluctuated between 36 mJ/m2 and 20 mJ/m2 for all of the samples and temperatures. It was seen that the values of KD/KA were proportional with base concentration but inversely proportional with iron concentration. Hence it was arisen that the adsorption properties and acid-base contributions to the surface energy of iron oxide nanoparticles prepared by co-precipitation method altered considerably depending on the synthesis conditions. It can be said that the more effective surface modifications can be carried out adjusting synthesis conditions of iron oxide nanoparticles.

Keywords

Iron oxide nanoparticles Inverse gas chromatography Surface characterization Co-precipitation
Beyaz, S., & Karaman, F. (2014). Thermodynamic Characterization on Surface of Iron Oxide Nanoparticles Prepared by Co-precipitation: An Inverse Gas Chromatography Application. Asian Journal of Chemistry, 26(10), 3053–3060. https://doi.org/10.14233/ajchem.2014.16625
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