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Vol. 26 No. 10 (2014): Vol 26 Issue 10

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Synthesis and Structural Characterizations of meso-Tetraphenyl Porphyrin

https://doi.org/10.14233/ajchem.2014.16659
Tianxiang Zhao
College of Chemical Engineering, Inner Mongolia University of Technology, Huhhot 010051, P.R. China
Jianbin Zhang
College of Chemical Engineering, Inner Mongolia University of Technology, Huhhot 010051, P.R. China ;Department of Applied Chemistry, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P.R. China
Xiaoxia Yang
College of Chemical Engineering, Inner Mongolia University of Technology, Huhhot 010051, P.R. China
Qiuxia Xu
College of Chemical Engineering, Inner Mongolia University of Technology, Huhhot 010051, P.R. China
Gongjia Lan
College of Chemical Engineering, Inner Mongolia University of Technology, Huhhot 010051, P.R. China

Corresponding Author(s) : Jianbin Zhang

tadzhang@pku.edu.cn

Asian Journal of Chemistry, Vol. 26 No. 10 (2014): Vol 26 Issue 10

Abstract

In this paper, tetraphenyl porphyrin (H2TPP) was synthesized by using pyrrole and benzaldehyde as raw materials under the catalysis of p-nitrobenzoic acid. The prepared tetraphenyl porphyrin was re-crystallized in a mixed system of methanol and methylene chloride (CH2Cl2) and the yield of tetraphenyl porphyrin is 34.2 %. Tetraphenyl porphyrin was characterized by using FTIR, UV-visible, 1H NMR and fluorescence spectrophotometer. The effects on the yield of tetraphenyl porphyrin at different volumes of dimethylbenzene as solvent were explored.

Keywords

Tetraphenylporphyrin Recrystallization Structural characterization
Zhao, T., Zhang, J., Yang, X., Xu, Q., & Lan, G. (2014). Synthesis and Structural Characterizations of meso-Tetraphenyl Porphyrin. Asian Journal of Chemistry, 26(10), 3050–3052. https://doi.org/10.14233/ajchem.2014.16659
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