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Kinetics for Synthesis of 1-Octanethiol
Corresponding Author(s) : Guqqin Hu
Asian Journal of Chemistry,
Vol. 26 No. 10 (2014): Vol 26 Issue 10
Abstract
as the phase transfer catalyst was studied. The reaction kinetic model was established. Through the experimental verification, the reaction
kinetics can be described by first order reaction kinetics as:
The apparent activation energy of the reaction was 58.815 KJ mol-1. The calculated results using the kinetics parameters from the kinetic model agree well with the experimental data.
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- H.Y. Tang, Y.D. Zhang and Z.X. Wang, Speciality Petrochem., 27, 23 (2010).
- J.S. Zhang, J.X. Xiao, Z.Y. Liu, J.G. Qiu, Z.X. Liu and Z. Zhang, Organo-Fluorine Ind.., 1, 54 (2007).
- L. Ma, M.H. Zhang and L.J. Jiang, J. Sci. China Ser. B, 12, 1248 (1992).
- K. Schoumacker, M. Cattenot, C. Geantet, E. Puzenat, M. Lacroix and J.M. Herrmann, Catal. Commun., 11, 1116 (2010); doi:10.1016/j.catcom.2010.05.023.
- T.L. Cairns, A.W. Larchar and B.C. Mckusick, Org. Chem., 18, 748 (1953); doi:10.1021/jo01134a023.
- C.S. Marvel and C.D. Lewis, J. Polym. Sci.., 3, 354 (1948); doi:10.1002/pol.1948.120030308.
- Q. Zhou, Y. Ling and C. Yao, Chem. World, 2, 107 (2007).
- S. Matsunaga, R. Yokomori, D. Ino, T. Yamada, M. Kawai and T. Kobayshi, Electrochem. Commun., 9, 645 (2007); doi:10.1016/j.elecom.2006.10.047.
- M.L. Foresti, F. Loglio, M. Innocenti, S. Bellassai, F. Carlà, E. Lastraioli, G. Pezzatini, C. Bianchini and F. Vizza, Langmuir, 26, 1802 (2010); doi:10.1021/la902506m.
- L. Pan, K. Tahara, T. Masuko and Y. Hisaeda, Inorg. Chim. Acta, 368, 194 (2011); doi:10.1016/j.ica.2011.01.004.
- Z. Zhang and H. Li, Chem. Reagents, 31, 292 (2009).
- A. Marafi, E. Kam and A. Stanislaus, Fuel, 87, 2131 (2008); doi:10.1016/j.fuel.2007.11.013.
- W.C. Chan and Y.Z. Lai, Bioresour. Technol., 99, 4380 (2008); doi:10.1016/j.biortech.2007.08.033.
References
H.Y. Tang, Y.D. Zhang and Z.X. Wang, Speciality Petrochem., 27, 23 (2010).
J.S. Zhang, J.X. Xiao, Z.Y. Liu, J.G. Qiu, Z.X. Liu and Z. Zhang, Organo-Fluorine Ind.., 1, 54 (2007).
L. Ma, M.H. Zhang and L.J. Jiang, J. Sci. China Ser. B, 12, 1248 (1992).
K. Schoumacker, M. Cattenot, C. Geantet, E. Puzenat, M. Lacroix and J.M. Herrmann, Catal. Commun., 11, 1116 (2010); doi:10.1016/j.catcom.2010.05.023.
T.L. Cairns, A.W. Larchar and B.C. Mckusick, Org. Chem., 18, 748 (1953); doi:10.1021/jo01134a023.
C.S. Marvel and C.D. Lewis, J. Polym. Sci.., 3, 354 (1948); doi:10.1002/pol.1948.120030308.
Q. Zhou, Y. Ling and C. Yao, Chem. World, 2, 107 (2007).
S. Matsunaga, R. Yokomori, D. Ino, T. Yamada, M. Kawai and T. Kobayshi, Electrochem. Commun., 9, 645 (2007); doi:10.1016/j.elecom.2006.10.047.
M.L. Foresti, F. Loglio, M. Innocenti, S. Bellassai, F. Carlà, E. Lastraioli, G. Pezzatini, C. Bianchini and F. Vizza, Langmuir, 26, 1802 (2010); doi:10.1021/la902506m.
L. Pan, K. Tahara, T. Masuko and Y. Hisaeda, Inorg. Chim. Acta, 368, 194 (2011); doi:10.1016/j.ica.2011.01.004.
Z. Zhang and H. Li, Chem. Reagents, 31, 292 (2009).
A. Marafi, E. Kam and A. Stanislaus, Fuel, 87, 2131 (2008); doi:10.1016/j.fuel.2007.11.013.
W.C. Chan and Y.Z. Lai, Bioresour. Technol., 99, 4380 (2008); doi:10.1016/j.biortech.2007.08.033.