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Chemical Composition of the Essential Oil and Petroleum Ether Extract from Korea Pine Needle Leaves of Cedrus deodara
Corresponding Author(s) : Ateeque Ahmad
Asian Journal of Chemistry,
Vol. 26 No. 10 (2014): Vol 26 Issue 10
Abstract
The composition of the pine needles leaves of Cedrus deodara essential oil and petroleum ether extract of Gwangjin-gu region of Seoul, Korea were obtained by hydrodistillation and extraction, respectively analyzed by gas chromatography-mass spectrometry (GC-MS). The essential oil yield was (0.20 %, w/w) of leaves. Thirty eight and forty components comprising 99.2 and 99.7 % of the total peak area were identified in the essential oil and petroleum ether extract, respectively. Essential oil major components were dominated by: a-pinene (2.9 %), a-myrcene (9.9 %), dl-limonene (3.9 %), trans-caryophyllene (4.2 %), a-humulene (3.4 %), linalyl propionate (10.9 %), d-cadinene (2.7 %), caryophyllene oxide (2.8 %), 1-dodecanol (2.9 %), a-cadinol (3.9 %), t-muurolol (4.4 %), dodecanoic acid (12.9 %). Petroleum ether extract major components were dominated by: butyl acetate (33.9 %), 4-allyloxy-2-methyl penta-en-2-ol (6.2 %), 2,2-dimethyl pentanal (2.4 %), a-pinene (2.9 %), 2-methyl-5-phenyl-5-pentanonenitrile (2.7 %), benzoic acid (2.7 %), ethyl ester of dodecanoic acid (6.1 %), butyl ester of 5-oxohexanethioic acid (2.5 %), caryophyllene oxide (6.8 %). The identity of components of essential oil and petroleum ether extract was confirmed on the basis of retention time, mass and supplemented library of NIST, USA. The essential oil and petroleum ether extract constituents are identified for the first time in Korean C. deodara pine needle leaves.
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References
M. Yatagai and T. Sato, Biochem. Syst. Ecol., 14, 469 (1986); doi:10.1016/0305-1978(86)90004-9.
P. Navarro, T.S. Nicolas, J.A. Gabaldon, M.T. Mercader-Ros, Á. Calín-Sánchez, Á.A. Carbonell-Barrachina and A.J. Pérez-López, J. Food Sci., 76, C319 (2011); doi:10.1111/j.1750-3841.2011.02176.x.
K.Y. Kim and H.J. Chung, J. Agric. Food Chem., 48, 1269 (2000); doi:10.1021/jf9900229.
U.K. Lim, J.J. Yoo and J.Y. Lee, In Health Care with Pine Needles: Jin Myoung Publishing: Seoul, South Korea, p. 52 (1993).
H.J. Song, Introductory Oriental Medicine at Home. In Dongeubogam, Kuk II Publishing: Seoul, South Korea, pp. 173-201 (1993).
J.D. Phillipson and L.A. Anderson, J. Ethnopharmacol., 25, 61 (1989); doi:10.1016/0378-8741(89)90045-7.
U.A. Shinde, A.S. Phadke, A.M. Nair, A.A. Mungantiwar, V.J. Dikshit and M.N. Saraf, J. Ethnopharmacol., 65, 21 (1999); doi:10.1016/S0378-8741(98)00150-0.
S.S. Bhatnagar, R.N. Chopra, B. Prasad, J.C. Ghosh, M.N. Saha and L.S. Ram, H. Santapall and B. N. Sastri, Cedrus deodara (Roxb.) Loud: The Wealth of India, Vol II. Council of Scientific and Industrial Research, New Delhi, p. 106 (1950).
A. Chaudhary, P. Sharma, G. Nadda, D.K. Tewari and B.J. Singh, J. Insect Sci., 11, Article 157 (2011).
K. Kar, V.N. Puri, G.K. Patnaik, R.N. Sur, B.N. Dhawan, D.K. Kulshrestha and R.P. Rastogi, J. Pharm. Sci., 64, 258 (1975); doi:10.1002/jps.2600640213.
A.K. Tiwari, P.V. Srinivas, S.P. Kumar and J.M. Rao, J. Agric. Food Chem., 49, 4642 (2001); doi:10.1021/jf010573a.
S.K. Singh, M. Shanmugavel, H. Kampasi, R. Singh, D. Mondhe, J. Rao, M. Adwankar, A. Saxena and G. Qazi, Planta Med., 73, 519 (2007); doi:10.1055/s-2007-967185.
T.C. Joseph and S. Dev, Tetrahedron Lett., 2, 216 (1961); doi:10.1016/S0040-4039(01)99234-2.
R. Shankaranarayanan, S. Krishnappa, S.C. Bisarya and S. Dev, Tetrahedron Lett., 14, 427 (1973); doi:10.1016/S0040-4039(01)95826-5.
P.K. Agrawal, S.K. Agarwal and R.P. Rastogi, Phytochemistry, 19, 1260 (1980); doi:10.1016/0031-9422(80)83107-4.
L. Boudarene, L. Rahim, A. Baaliouamer and B.Y. Meklati, J. Essent. Oil Res., 16, 531 (2004); doi:10.1080/10412905.2004.9698790.
W.A. Konig, D. Joulain, and D. H. Hochmuth, Terpenoids and Related Constituents of Essential Oil (2004); Online available at www.massfinder.com
D.H. Hoch, MassFinder 3.0 (2005); Online available at www.massfinder.com