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Vol. 26 No. 10 (2014): Vol 26 Issue 10

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Synthesis, Characterization and Antibacterial Activity of Organotin(IV) Complexes Derivatives of 2-Chloro-4-nitrobenzoic Acid

https://doi.org/10.14233/ajchem.2014.16066
Chen-Shang Choong
Department of Chemical Science, Faculty of Science, Universiti Tunku Abdul Rahman, Perak Campus, Jalan Universiti, Bandar Barat, 31900 Kampar, Perak, Malaysia
Yip-Foo Win
Department of Chemical Science, Faculty of Science, Universiti Tunku Abdul Rahman, Perak Campus, Jalan Universiti, Bandar Barat, 31900 Kampar, Perak, Malaysia
Sie-Tiong Ha
Department of Chemical Science, Faculty of Science, Universiti Tunku Abdul Rahman, Perak Campus, Jalan Universiti, Bandar Barat, 31900 Kampar, Perak, Malaysia
Emad Yousif
Department of Chemistry, College of Science, Al-Nahrain University, Baghdad, Iraq

Corresponding Author(s) : Yip-Foo Win

williamyfw@yahoo.com

Asian Journal of Chemistry, Vol. 26 No. 10 (2014): Vol 26 Issue 10

Abstract

Four organotin(IV) carboxylate complexes have been successfully synthesized and characterized quantitatively and qualitatively. Spectroscopic studies showed that the coordination took place via oxygen atoms from the carboxylate anions. With the exceptional case, spectroscopic studies indicated that one methanol molecule also take part in the coordination to tin(IV) atom moiety in complex 4 resulting the tin(IV) atom exhibited five coordination. From the preliminary in vitro antibacterial screening activity, triphenyltin(IV) (complex 4) showed some significant activity compared to diorganotin(IV) complexes (1-3).

Keywords

Organotin(IV) carboxylate 2-Chloro-4-nitrobenzoic acid
Choong, C.-S., Win, Y.-F., Ha, S.-T., & Yousif, E. (2014). Synthesis, Characterization and Antibacterial Activity of Organotin(IV) Complexes Derivatives of 2-Chloro-4-nitrobenzoic Acid. Asian Journal of Chemistry, 26(10), 2949–2953. https://doi.org/10.14233/ajchem.2014.16066
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