Effect High Temperature Annealing on Graphitization of Anthracite

Heng Ma; Yinxia Liu

doi:10.14233/ajchem.2014.16186A

Issue

Vol. 26 No. 9 (2014): Vol 26 Issue 9

Issue Published : April 28, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Effect High Temperature Annealing on Graphitization of Anthracite

https://doi.org/10.14233/ajchem.2014.16186A

Heng Ma

College of Safety Science and Engineering, Liaoning Technical University, Fuxin 123000, Liaoning Province, P.R. China ;Key Laboratory of Mine Thermodynamic Disasters and Control of Ministry of Education, Fuxin 123000, Liaoning Province, P.R. China

Yinxia Liu

Corresponding Author(s) : Heng Ma

maheng@163.com

Asian Journal of Chemistry, Vol. 26 No. 9 (2014): Vol 26 Issue 9
Article Published : April 30, 2014

Abstract

Effect of high temperature anneal on the graphitizability of an anthracite coal is explored. A thermal anneal of Taixi Coal Mine anthracite at 1400, 1600 and 1800 °C in argon was investigated. The sample was investigated by XRD, FTIR and SEM. The result shows that after low temperature anneal, the anthracite is amorphous state carbon, high temperature benefit to graphitization of the sample. The anthracite contains chemical functional groups of COOH and C-H, which decomposed at high temperature; after high temperature anneal, vitrinite and fusinite separated from the anthracite base. The shape of vitrinite is round particles and the fusinite is rod like.

Keywords

Anthracite High temperature annealing Graphitization

Ma, H., & Liu, Y. (2014). Effect High Temperature Annealing on Graphitization of Anthracite. Asian Journal of Chemistry, 26(9), 2729–2732. https://doi.org/10.14233/ajchem.2014.16186A

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References

R.M. Bustin, J.N. Rouzaud and J.V. Ross, Carbon, 33, 679 (1995); doi:10.1016/0008-6223(94)00155-S.
N. Cohaut, C. Blanche, D. Dumas, J.M. Guet and J.N. Rouzaud, Carbon, 38, 1391 (2000); doi:10.1016/S0008-6223(99)00274-2.
D. Gonzalez, M.A. Montes-Moran and A.B. Garcia, Energy Fuels, 19, 263 (2005); doi:10.1021/ef049893x.
E.L. Evans, J.L. Jenkins and J.M. Thomas, Carbon, 10, 637 (1972); doi:10.1016/0008-6223(72)90102-9.
J J.A. Johansen and H. Gran, In ECA for Improved Cathode Performance, in: E.W. Lee, Light Metals 1997 TMS Annual Meeting & Exhibition, Feb. 10-13, pp. 627-631 (1997).
D. Gonzalez, M.A. Montes-Moran and A.B. Garcia, Energy Fuels, 17, 1324 (2003); doi:10.1021/ef0300491.
A.D. Lueking, H.R. Gutierrez, D.A. Fonseca, D.L. Narayanan, D. Van Essendelft, P. Jain and C.E.B. Clifford, J. Am. Chem. Soc., 128, 7758 (2006); doi:10.1021/ja0604818.
A.D. Lueking, H.R. Gutierrez, P. Jain, D.T. Van Essandelft and C.E. Burgess-Clifford, Carbon, 45, 2297 (2007); doi:10.1016/j.carbon.2007.04.027.
D.L. Narayanan and A.D. Lueking, Carbon, 45, 805 (2007); doi:10.1016/j.carbon.2006.11.017.
B.J. Kim, Y.S. Lee and S.J. Park, Int. J. Hydrogen Energy, 33, 2254 (2008); doi:10.1016/j.ijhydene.2008.02.019.
S.J. Park, B.J. Kim, Y.S. Lee and M.S. Cho, Int. J. Hydrogen Energy, 33, 1706 (2008); doi:10.1016/j.ijhydene.2008.01.011.
C. Liu, Y. Chen, C.Z. Wu, S.T. Xu and H.M. Cheng, Carbon, 48, 452 (2010); doi:10.1016/j.carbon.2009.09.060.
B. Kuchta, L. Firlej, P. Pfeifer and C. Wexler, Carbon, 48, 223 (2010); doi:10.1016/j.carbon.2009.09.009.
M. Seiﬁ, D.K. Ross, D.J. Riley and I. Morrison, Carbon, 47, 3184 (2009); doi:10.1016/j.carbon.2009.07.030.
S.J. Yang, J.H. Cho, G.H. Oh, K.S. Nahm and C.R. Park, Carbon, 47, 1585 (2009); doi:10.1016/j.carbon.2009.02.010.
K.Y. Kang, B.I. Lee and J.S. Lee, Carbon, 47, 1171 (2009); doi:10.1016/j.carbon.2009.01.001.
J. Dong, X. Wang, H. Xu, Q. Zhao and J. Li, Int. J. Hydrogen Energy, 32, 4998 (2007); doi:10.1016/j.ijhydene.2007.08.009.
S.F. Santos and J. Huot, J. Alloys Comp., 472, 247 (2009); doi:10.1016/j.jallcom.2008.04.062.
G.L. Soloveichik, M. Andrus, Y. Gao, J.C. Zhao and S. Kniajanski, Int. J. Hydrogen Energy, 34, 2144 (2009); doi:10.1016/j.ijhydene.2008.12.053.

References

R.M. Bustin, J.N. Rouzaud and J.V. Ross, Carbon, 33, 679 (1995); doi:10.1016/0008-6223(94)00155-S.

N. Cohaut, C. Blanche, D. Dumas, J.M. Guet and J.N. Rouzaud, Carbon, 38, 1391 (2000); doi:10.1016/S0008-6223(99)00274-2.

D. Gonzalez, M.A. Montes-Moran and A.B. Garcia, Energy Fuels, 19, 263 (2005); doi:10.1021/ef049893x.

E.L. Evans, J.L. Jenkins and J.M. Thomas, Carbon, 10, 637 (1972); doi:10.1016/0008-6223(72)90102-9.

J J.A. Johansen and H. Gran, In ECA for Improved Cathode Performance, in: E.W. Lee, Light Metals 1997 TMS Annual Meeting & Exhibition, Feb. 10-13, pp. 627-631 (1997).

D. Gonzalez, M.A. Montes-Moran and A.B. Garcia, Energy Fuels, 17, 1324 (2003); doi:10.1021/ef0300491.

A.D. Lueking, H.R. Gutierrez, D.A. Fonseca, D.L. Narayanan, D. Van Essendelft, P. Jain and C.E.B. Clifford, J. Am. Chem. Soc., 128, 7758 (2006); doi:10.1021/ja0604818.

A.D. Lueking, H.R. Gutierrez, P. Jain, D.T. Van Essandelft and C.E. Burgess-Clifford, Carbon, 45, 2297 (2007); doi:10.1016/j.carbon.2007.04.027.

D.L. Narayanan and A.D. Lueking, Carbon, 45, 805 (2007); doi:10.1016/j.carbon.2006.11.017.

B.J. Kim, Y.S. Lee and S.J. Park, Int. J. Hydrogen Energy, 33, 2254 (2008); doi:10.1016/j.ijhydene.2008.02.019.

S.J. Park, B.J. Kim, Y.S. Lee and M.S. Cho, Int. J. Hydrogen Energy, 33, 1706 (2008); doi:10.1016/j.ijhydene.2008.01.011.

C. Liu, Y. Chen, C.Z. Wu, S.T. Xu and H.M. Cheng, Carbon, 48, 452 (2010); doi:10.1016/j.carbon.2009.09.060.

B. Kuchta, L. Firlej, P. Pfeifer and C. Wexler, Carbon, 48, 223 (2010); doi:10.1016/j.carbon.2009.09.009.

M. Seiﬁ, D.K. Ross, D.J. Riley and I. Morrison, Carbon, 47, 3184 (2009); doi:10.1016/j.carbon.2009.07.030.

S.J. Yang, J.H. Cho, G.H. Oh, K.S. Nahm and C.R. Park, Carbon, 47, 1585 (2009); doi:10.1016/j.carbon.2009.02.010.

K.Y. Kang, B.I. Lee and J.S. Lee, Carbon, 47, 1171 (2009); doi:10.1016/j.carbon.2009.01.001.

J. Dong, X. Wang, H. Xu, Q. Zhao and J. Li, Int. J. Hydrogen Energy, 32, 4998 (2007); doi:10.1016/j.ijhydene.2007.08.009.

S.F. Santos and J. Huot, J. Alloys Comp., 472, 247 (2009); doi:10.1016/j.jallcom.2008.04.062.

G.L. Soloveichik, M. Andrus, Y. Gao, J.C. Zhao and S. Kniajanski, Int. J. Hydrogen Energy, 34, 2144 (2009); doi:10.1016/j.ijhydene.2008.12.053.

Issue

Vol. 26 No. 9 (2014): Vol 26 Issue 9

Effect High Temperature Annealing on Graphitization of Anthracite

Corresponding Author(s) : Heng Ma

Abstract

Keywords

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