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Effects of Continuous Volume Extensional flow on Low Density Polyethylene/Calcium Carbonate Nanocomposites
Corresponding Author(s) : Jin Ping Qu
Asian Journal of Chemistry,
Vol. 26 No. 9 (2014): Vol 26 Issue 9
Abstract
In this paper, low density polyethylene (LDPE)/calcium carbonate (CaCO3) nanocomposites were prepared both by Battenfeld screw extruder and vane extruder which is a kind of innovative equipment for polymer processing. Effects of the two processing equipment on the morphology, the thermal behaviour and the mechanical properties of the composites were investigated by scanning electron microscopy, differential scanning calorimetry (DSC), wide-angle X-ray diffraction and mechanical testing. SEM examinations showed that the nanocomposites extruded in the vane extruder had a smaller particle diameter and better effects on the distribution and dispersion mixing, compared with those extruded by the screw extruder. Correspondingly, it exhibited a higher degree of crystallinity, which was determined by DSC. Both the tensile and flexural properties of LDPE/CaCO3 nanocomposites extruded by the vane extruder are much higher than that extruded by the screw extruder.
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- Y. Gao, L. Liu and Z. Zhang, Acta Mechan. Solida Sinica., 22, 555 (2009); doi:10.1016/S0894-9166(09)60386-4.
- Y. Xiang, Z. Hou, R. Su, K. Wang and Q. Fu, Polym. Adv. Technol., 21, 48 (2010); doi:10.1002/pat.1355.
- H.-Z. He and J.-X. Fu, Modern Plastics Process. Appl., 20, 1 (2008).
- G. Wang, China Plastic Chengdu: Sichuan Univ., 10, 23 (2003).
- F.N. Fritsch and R.E. Carlson, SIAM J. Numer. Anal., 17, 238 (1980); doi:10.1137/0717021.
- J.G. Ryu, H. Kim and J.W. Lee, Polym. Eng. Sci., 44, 1198 (2004); doi:10.1002/pen.20114.
- E.C. Lee, D.F. Mielewski and R.J. Baird, Polym. Eng. Sci., 44, 1773 (2004); doi:10.1002/pen.20179.
- M. Arellano, I. Manas-Zloczower and D.L. Feke, Polym. Compos., 16, 489 (1995); doi:10.1002/pc.750160607.
- M. Tokihisa, K. Yakemoto, T. Sakai, L.A. Utracki, M. Sepehr, J. Li and Y. Simard, Polym. Eng. Sci., 46, 1040 (2006); doi:10.1002/pen.20542.
- H.C. Kim, A. Pendse and J.R. Collier, J. Rheol., 38, 831 (1994); doi:10.1122/1.550595.
- J.P. Qu, China Patent 200810026054.X, (2008).
- J.P. Qu, Eng. Sci., 10, 20 (2012).
References
Y. Gao, L. Liu and Z. Zhang, Acta Mechan. Solida Sinica., 22, 555 (2009); doi:10.1016/S0894-9166(09)60386-4.
Y. Xiang, Z. Hou, R. Su, K. Wang and Q. Fu, Polym. Adv. Technol., 21, 48 (2010); doi:10.1002/pat.1355.
H.-Z. He and J.-X. Fu, Modern Plastics Process. Appl., 20, 1 (2008).
G. Wang, China Plastic Chengdu: Sichuan Univ., 10, 23 (2003).
F.N. Fritsch and R.E. Carlson, SIAM J. Numer. Anal., 17, 238 (1980); doi:10.1137/0717021.
J.G. Ryu, H. Kim and J.W. Lee, Polym. Eng. Sci., 44, 1198 (2004); doi:10.1002/pen.20114.
E.C. Lee, D.F. Mielewski and R.J. Baird, Polym. Eng. Sci., 44, 1773 (2004); doi:10.1002/pen.20179.
M. Arellano, I. Manas-Zloczower and D.L. Feke, Polym. Compos., 16, 489 (1995); doi:10.1002/pc.750160607.
M. Tokihisa, K. Yakemoto, T. Sakai, L.A. Utracki, M. Sepehr, J. Li and Y. Simard, Polym. Eng. Sci., 46, 1040 (2006); doi:10.1002/pen.20542.
H.C. Kim, A. Pendse and J.R. Collier, J. Rheol., 38, 831 (1994); doi:10.1122/1.550595.
J.P. Qu, China Patent 200810026054.X, (2008).
J.P. Qu, Eng. Sci., 10, 20 (2012).