Synthesis, Crystal and Supramolecular Structure of {2,2'-[Ethylenedioxybis(nitrilomethylidyne)]dinaphthanolato}Cu(II)

Yu-Jie Zhang; Xin-Ying Zhang; Yu-Hua Yang; Meng-Meng Zhao; Gang Li; Xiu-Yan Dong

doi:10.14233/ajchem.2014.15793

Issue

Vol. 26 No. 9 (2014): Vol 26 Issue 9

Issue Published : April 28, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis, Crystal and Supramolecular Structure of {2,2'-[Ethylenedioxybis(nitrilomethylidyne)]dinaphthanolato}Cu(II)

https://doi.org/10.14233/ajchem.2014.15793

Yu-Jie Zhang

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

Xin-Ying Zhang

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

Yu-Hua Yang

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

Meng-Meng Zhao

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

Gang Li

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

Xiu-Yan Dong

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

Corresponding Author(s) : Gang Li

li_gang78@126.com

Asian Journal of Chemistry, Vol. 26 No. 9 (2014): Vol 26 Issue 9
Article Published : April 29, 2014

Abstract

A new Cu(II) complex has been synthesized by the reaction of a new Salamo-type ligand of 2,2'-[ethylenedioxybis(nitrilomethylidyne)] dinaphthanol (H₂L) with Cu(II) acetate monohydrate in acetone/methanol solution and characterized by X-ray diffraction methods. The X-ray crystallography of the Cu(II) complex shows it to be a mononuclear complex, in which the Cu(II) atom is in a distorted square-planar geometry and the center Cu(II) atom is tetra-coordinated lying in the N₂O₂ coordination sphere. The Cu(II) complex crystallizes in the triclinic system, space group P-1. The unit cell contains two crystallographically independent but chemically identical mononuclear Cu(II) complex (molecules A and B). And every complex molecule links four other molecules into an infinite 2D-layer supramolecular structure.

Keywords

Salamo-type ligand Cu(II) complex Synthesis Crystal structure

Zhang, Y.-J., Zhang, X.-Y., Yang, Y.-H., Zhao, M.-M., Li, G., & Dong, X.-Y. (2014). Synthesis, Crystal and Supramolecular Structure of {2,2’-[Ethylenedioxybis(nitrilomethylidyne)]dinaphthanolato}Cu(II). Asian Journal of Chemistry, 26(9), 2664–2666. https://doi.org/10.14233/ajchem.2014.15793

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References

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S. Akine, T. Taniguchi and T. Nabeshima, Angew. Chem. Int. Ed., 41, 4670 (2002); doi:10.1002/anie.200290011.

N.S. Venkataramanan, G. Kuppuraj and S. Rajagopal, Coord. Chem. Rev., 249, 1249 (2005); doi:10.1016/j.ccr.2005.01.023.

T. Katsuki, Coord. Chem. Rev., 140, 189 (1995); doi:10.1016/0010-8545(94)01124-T.

S. Di Bella and I. Fragala, Synth. Met., 115, 191 (2000); doi:10.1016/S0379-6779(00)00354-4.

J.P. Costes, F. Dahan and A. Dupuis, Inorg. Chem., 39, 165 (2000); doi:10.1021/ic990865h.

A. Bencini, C. Benelli, A. Caneschi, R.L. Carlin, A. Dei and D. Gatteschi, J. Am. Chem. Soc., 107, 8128 (1985); doi:10.1021/ja00312a054.

M. Sasaki, K. Manseki, H. Horiuchi, M. Kumagai, M. Sakamoto, H. Sakiyama, Y. Nishida, M. Sakai, Y. Sadaoka, M. Ohba and H. Okawa, J. Chem. Soc., Dalton Trans., 259 (2000); doi:10.1039/a907423f.

C. Edder, C. Piguet, J.C.G. Bünzli and G. Hopfgartner, Chem. Eur. J., 7, 3014 (2001); doi:10.1002/1521-3765(20010716)7:14<3014::AID-CHEM3014>3.0.CO;2-D.

J.C.G. Bünzli and C. Piguet, Chem. Rev., 102, 1897 (2002); doi:10.1021/cr010299j.

P.G. Lacroix, Eur. J. Inorg. Chem., 2001, 339 (2001); doi:10.1002/1099-0682(200102)2001:2<339::AID-EJIC339>3.0.CO;2-Z.

R. Atkins, G. Brewer, E. Kokot, G.M. Mockler and E. Sinn, Inorg. Chem., 24, 127 (1985); doi:10.1021/ic00196a003.

(a) W.K. Dong, Y.X. Sun, Y.P. Zhang, L. Li, X.N. He and X.L. Tang, Inorg. Chim. Acta, 362, 117 (2009); doi:10.1016/j.ica.2008.03.128.; (b) W.K. Dong, Y.X. Sun, C.Y. Zhao, X.Y. Dong and L. Xu, Polyhedron, 29, 2087 (2010); doi:10.1016/j.poly.2010.04.006.; (c) W.K. Dong, X.N. He, H.B. Yan, Z.W. Lv, X. Chen, C.Y. Zhao and X.L. Tang, Polyhedron, 28, 1419 (2009); doi:10.1016/j.poly.2009.03.017.; (d) W.K. Dong, J.G. Duan, Y.H. Guan, J.Y. Shi and C.Y. Zhao, Inorg. Chim. Acta, 362, 1129 (2009); doi:10.1016/j.ica.2008.05.028.; (e) W.K. Dong, L. Li, C.F. Li, L. Xu and J.G. Duan, Spectrochimica Acta, 71, 650 (2008); doi:10.1016/j.saa.2008.01.020.

S. Akine, Y. Morita, F. Utsuno and T. Nabeshima, Inorg. Chem., 48, 10670 (2009); doi:10.1021/ic901372k.

H.L. Wu, X.C. Huang, J.K. Yuan, F. Kou, F. Jia, B. Liu and Y. Bai, Z. Naturforsch, 66, 1049 (2011); doi:10.5560/ZNB.2011.66b1049.

H.L. Wu, J.K. Yuan, Y. Bai, F. Jia, B. Liu, F. Kou and J. Kong, Transition Met. Chem., 36, 819 (2011); doi:10.1007/s11243-011-9536-5.

H.L. Wu, F. Jia, F. Kou, B. Liu, J.K. Yuan and Y. Bai, Transition Met. Chem., 36, 847 (2011); doi:10.1007/s11243-011-9539-2.

Issue

Vol. 26 No. 9 (2014): Vol 26 Issue 9

Synthesis, Crystal and Supramolecular Structure of {2,2'-[Ethylenedioxybis(nitrilomethylidyne)]dinaphthanolato}Cu(II)

Corresponding Author(s) : Gang Li

Abstract

Keywords

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