Zeta Potential as Criterion of Electrocoagulation Process Control in Acid Whey

Francisco Prieto Garcia; Judith Callejas Hernandez; Judith Prieto Mendez; Mar&iacute;a Aurora Mendez Marzo; Otilio Arturo Acevedo Sandoval

doi:10.14233/ajchem.2014.15770

Issue

Vol. 26 No. 9 (2014): Vol 26 Issue 9

Issue Published : April 28, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Zeta Potential as Criterion of Electrocoagulation Process Control in Acid Whey

https://doi.org/10.14233/ajchem.2014.15770

Francisco Prieto Garcia

Academic Area of Chemistry, Autonomous University of the State of Hidalgo. University City. Road Pachuca-Tulancingo Km 4.5, Pachuca, Hidalgo, Mexico

Judith Callejas Hernandez

Academic Area of Chemistry, Autonomous University of the State of Hidalgo. University City. Road Pachuca-Tulancingo Km 4.5, Pachuca, Hidalgo, Mexico

Judith Prieto Mendez

Institute of Agricultural Sciences, Autonomous University of the State of Hidalgo. University City. Road Pachuca-Tulancingo Km 4.5, Pachuca, Hidalgo, Mexico

María Aurora Mendez Marzo

Academic Area of Materials, Autonomous University of the State of Hidalgo. University City. Road Pachuca-Tulancingo Km 4.5, Pachuca, Hidalgo, Mexico

Otilio Arturo Acevedo Sandoval

Institute of Agricultural Sciences, Autonomous University of the State of Hidalgo. University City. Road Pachuca-Tulancingo Km 4.5, Pachuca, Hidalgo, Mexico

Corresponding Author(s) : Francisco Prieto Garcia

prietog@uaeh.edu.mx

Asian Journal of Chemistry, Vol. 26 No. 9 (2014): Vol 26 Issue 9
Article Published : April 29, 2014

Abstract

The electrocoagulation (EC) is a technique used for treatment of various waste waters. In this process, contaminants are removed suspended, emulsified or dissolved in the aqueous medium, inducing electric current through metal plates. The zeta potential (z) is an important parameter for electrostatic particles suspended in an aqueous medium as an index of evaluating the stability of colloidal dispersions with respect to the aggregation of particles. The aim of this work was to study the application of electrocoagulation process under conditions previously optimized for the treatment of organic load removal (COD), color and turbidity in a batch type electrochemical reactor. The results showed that it is possible to achieve optimum process performance while electrocoagulation sedimentation and reduction of the organic load present in the acid whey, carrying out measurements in the liquid phase zeta potential whey as an indicator of effectiveness electrocoagulated destabilization particles. The zeta potential positively correlated with pH and effective initial direct correlation with the color (measured as absorbance of purified liquid) and turbidity.

Keywords

Acid whey Zeta potential Turbidity Electrocogulation Correlation

Prieto Garcia, F., Callejas Hernandez, J., Prieto Mendez, J., Aurora Mendez Marzo, M., & Arturo Acevedo Sandoval, O. (2014). Zeta Potential as Criterion of Electrocoagulation Process Control in Acid Whey. Asian Journal of Chemistry, 26(9), 2629–2631. https://doi.org/10.14233/ajchem.2014.15770

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References

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E. Foegeding and P. Luck, in eds: B. Caballero, L. Trugo and P. Finglas, Whey Protein Products; In: Encyclopedia of Foods Sciences and Nutrition, Academic Press, New York, pp. 1957-1960 (2002).
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R.A. Parra, National School Agron. J. Medellin, 62, 4967 (2009).
WHO, Guidelines for Drinking Water: Incorporating First Addendum. Washington, DC: World Health Organization (2006).
E.L. Sharp, S.A. Parsons and B. Jefferson, Environ. Pollut., 140, 436 (2006); doi:10.1016/j.envpol.2005.08.001.
D. Cristancho, N.B. Morales, J.Z. Garavito and A. Chávez, Nueva Granada, 3, 125 (2010).
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A. Arango and L.F. Garces, Production & Cleaning, 4, 54 (2009).
J.Y. Kim and J.J. Sansalone, J. Hydrol., 356, 163 (2008); doi:10.1016/j.jhydrol.2008.04.006.
K. Furusawa and K. Uchiyama, Colloids Surf. A, 140, 217 (1998); doi:10.1016/S0927-7757(97)00280-X.
J. Ennis and J. Anderson, J. Colloid Interf. Sci., 185, 497 (1997); doi:10.1006/jcis.1996.4596.
P. Attard, D. Antelmi and I. Larson, Langmuir, 16, 1542 (2000); doi:10.1021/la990487t.
M. James, R.J. Hunter and R.W. O’Brien, Langmuir, 8, 420 (1992); doi:10.1021/la00038a017.
O. El-Gholabzouri, M.A. Cabrerizo and R. Hidalgo-Álvarez, Colloids Surf. A, 159, 449 (1999); doi:10.1016/S0927-7757(99)00280-0.
A. Sze, D. Erickson, L. Ren and D. Li, J. Colloid Interf. Sci., 261, 402 (2003); doi:10.1016/S0021-9797(03)00142-5.
R. Greenwood, Adv. Colloid Interf. Sci., 106, 55 (2003); doi:10.1016/S0001-8686(03)00105-2.
I. Clescer and L.S. Eaton, A Standard Methods for the Examination of Water and Wastewater, Washington: EPHAAWWA-WPCF, edn 18, pp. 3-115 (1992).
APHA, American Public Health Association, Standard Methods for the Examination of Water and Wastewater, American Water Work Association, Batilmore, edn 20 (1998).
NMX-AA-030-SCFI-2001, Norma Mexicana, Water Analysis-Determination of Total Phosphorus in Natural Water, Wastewater and Treated Wastewater-Test Method (2001).
Malvern Instrument, Inc., Zeta Potential, A Complete Course in Five Minutes, Ed Malvern Zeta-Meter Books Inst. Westborough, MA, USA (2004).
Hasch, Manual Water Analysis, Photometric Procedures, Hach Company (970) 2000, Loveland, Colorado, USA, edn 2 (Spanish).
Hasch, Portable Turbidimeter, Model 2100P, Instrument Manual, Ed Hach Company, Catalogue No. 46500-93.
R. Krishna Prasad and S.N. Srivastava, Chem. Eng. J., 146, 22 (2008); doi:10.1016/j.cej.2008.05.008.
C. Raghukumar and G. Rivonkar, Appl. Microbiol. Biotechnol., 55, 510 (2001); doi:10.1007/s002530000579.
D.J. Shaw, Introduction to Colloid and Surface Chemistry, Butterworths, London, p. 132 (1966).
A. Morfesis, A.M. Jacobson, R. Frollini, M. Helgeson, J. Billica and K.R. Gertig, Ind. Eng. Chem. Res., 48, 2305 (2009); doi:10.1021/ie800524x.
J.Y. Kim, J.L. Anderson, S. Garoff and P.J. Sides, Langmuir, 18, 5387 (2002); doi:10.1021/la025682d.

References

A. Abaigar, The Whey in Feeding the Pigs, Livestock ITG, pp. 13-17 (2009); ISSN-948-5656.

E. Foegeding and P. Luck, in eds: B. Caballero, L. Trugo and P. Finglas, Whey Protein Products; In: Encyclopedia of Foods Sciences and Nutrition, Academic Press, New York, pp. 1957-1960 (2002).

J.A. del Angel, J.M. Hernández, V.M. Jiménez and R. Musule, Treatment of Whey, Design by Implementing a Solar Evaporator (2009).

CODEX STAN 289-1995, CODEX Standard for whey powders, CODEX Alimentarius Standard, Argentina. Revision 2003. Amendment 2006, (2010).

R.A. Parra, National School Agron. J. Medellin, 62, 4967 (2009).

WHO, Guidelines for Drinking Water: Incorporating First Addendum. Washington, DC: World Health Organization (2006).

E.L. Sharp, S.A. Parsons and B. Jefferson, Environ. Pollut., 140, 436 (2006); doi:10.1016/j.envpol.2005.08.001.

D. Cristancho, N.B. Morales, J.Z. Garavito and A. Chávez, Nueva Granada, 3, 125 (2010).

J. Callejas Hernández, F. Prieto García, V.E. Reyes Cruz, Y. Marmolejo Santillán and M.A. Méndez Marzo, Revista Acta Univ., 22, 11 (2012).

A. Arango and L.F. Garces, Production & Cleaning, 4, 54 (2009).

J.Y. Kim and J.J. Sansalone, J. Hydrol., 356, 163 (2008); doi:10.1016/j.jhydrol.2008.04.006.

K. Furusawa and K. Uchiyama, Colloids Surf. A, 140, 217 (1998); doi:10.1016/S0927-7757(97)00280-X.

J. Ennis and J. Anderson, J. Colloid Interf. Sci., 185, 497 (1997); doi:10.1006/jcis.1996.4596.

P. Attard, D. Antelmi and I. Larson, Langmuir, 16, 1542 (2000); doi:10.1021/la990487t.

M. James, R.J. Hunter and R.W. O’Brien, Langmuir, 8, 420 (1992); doi:10.1021/la00038a017.

O. El-Gholabzouri, M.A. Cabrerizo and R. Hidalgo-Álvarez, Colloids Surf. A, 159, 449 (1999); doi:10.1016/S0927-7757(99)00280-0.

A. Sze, D. Erickson, L. Ren and D. Li, J. Colloid Interf. Sci., 261, 402 (2003); doi:10.1016/S0021-9797(03)00142-5.

R. Greenwood, Adv. Colloid Interf. Sci., 106, 55 (2003); doi:10.1016/S0001-8686(03)00105-2.

I. Clescer and L.S. Eaton, A Standard Methods for the Examination of Water and Wastewater, Washington: EPHAAWWA-WPCF, edn 18, pp. 3-115 (1992).

APHA, American Public Health Association, Standard Methods for the Examination of Water and Wastewater, American Water Work Association, Batilmore, edn 20 (1998).

NMX-AA-030-SCFI-2001, Norma Mexicana, Water Analysis-Determination of Total Phosphorus in Natural Water, Wastewater and Treated Wastewater-Test Method (2001).

Malvern Instrument, Inc., Zeta Potential, A Complete Course in Five Minutes, Ed Malvern Zeta-Meter Books Inst. Westborough, MA, USA (2004).

Hasch, Manual Water Analysis, Photometric Procedures, Hach Company (970) 2000, Loveland, Colorado, USA, edn 2 (Spanish).

Hasch, Portable Turbidimeter, Model 2100P, Instrument Manual, Ed Hach Company, Catalogue No. 46500-93.

R. Krishna Prasad and S.N. Srivastava, Chem. Eng. J., 146, 22 (2008); doi:10.1016/j.cej.2008.05.008.

C. Raghukumar and G. Rivonkar, Appl. Microbiol. Biotechnol., 55, 510 (2001); doi:10.1007/s002530000579.

D.J. Shaw, Introduction to Colloid and Surface Chemistry, Butterworths, London, p. 132 (1966).

A. Morfesis, A.M. Jacobson, R. Frollini, M. Helgeson, J. Billica and K.R. Gertig, Ind. Eng. Chem. Res., 48, 2305 (2009); doi:10.1021/ie800524x.

J.Y. Kim, J.L. Anderson, S. Garoff and P.J. Sides, Langmuir, 18, 5387 (2002); doi:10.1021/la025682d.

Issue

Vol. 26 No. 9 (2014): Vol 26 Issue 9

Zeta Potential as Criterion of Electrocoagulation Process Control in Acid Whey

Corresponding Author(s) : Francisco Prieto Garcia

Abstract

Keywords

Full Article

Download Citation

References

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