This work is licensed under a Creative Commons Attribution 4.0 International License.
Evaluation of Lime Juice as Potential Green Corrosion Inhibitor Using Gravimetric and Electrochemical Studies
Corresponding Author(s) : S.J. Hepziba Magie Jessima
Asian Journal of Chemistry,
Vol. 32 No. 8 (2020): Vol 32 Issue 8, 2020
Abstract
Lime, a vibrant fruit of citrus family is known for its antioxidant as well as anti-microbial properties. The constituents of lime juice include organic acids, polyphenols, soluble sugars, vitamins, minerals and amino acids. These details prompted to experiment lime juice as corrosion inhibitor for mild steel in 1 M HCl. The weight loss studies showed that the corrosion inhibition efficiency increased with increase in concentration of the lime juice as well as increase of temperature. The inhibition efficiency reached a maximum of 96% for an immersion period of 24 h. The best fit for the adsorption process obeyed Langmuir isotherm. The negative value of ΔGads showed the spontaneity of the corrosion inhibition process. The corrosion inhibition efficiency of the acidified lime juice was further validated by electrochemical studies namely AC impedance studies and potentiodynamic polarization studies. The surface morphology study was performed used optical profilometer.
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- M. Finsgar and J. Jackson, Corros. Sci., 86, 17 (2014); https://doi.org/10.1016/j.corsci.2014.04.044
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A.S. Yaro, A.A. Khadom and R.K. Wael, Alexandria Eng. J., 52, 129 (2013); https://doi.org/10.1016/j.aej.2012.11.001
A.S. Yaro, A.A. Khadom and H.F. Ibraheem, Anti-Corros. Methods Mater., 58, 116 (2011); https://doi.org/10.1108/00035591111130497
Z. Ahmad and F. Patel, Int. J. Corros., 2012, 982972 (2012);https://doi.org/10.1155/2012/982972
Y. Abboud, O. Tanane, A. El Bouari, R. Salghi, B. Hammouti, A. Chetouani and S. Jodeh, Corros. Eng. Sci. Technol., 51, 557 (2016);https://doi.org/10.1179/1743278215Y.0000000058
J.C. Da Rocha, J.A.C. Ponciano Gomes, E. D’Elia, A.P. Gil Cruz, L.M.C. Cabral and A.G. Torres, Int. J. Electrochem. Sci., 7, 11941 (2012).
X. Wang, Y. Wang, Q. Wang, Y. Wan, X. Huang and C. Jing, Int. J. Electrochem. Sci., 13, 5228 (2018); https://doi.org/10.20964/2018.06.36
K.H. Rashid and A.A. Khadom, J. Bio- Tribo-Corrosion, 6, 13 (2020); https://doi.org/10.1007/s40735-019-0312-y
H.D. Ada, S. Altanlar, F. Erdem and G. Bereket, Int. J. Indus. Chem., 7, 431 (2016); https://doi.org/10.1007/s40090-016-0077-9
H. Ashassi-sorkhabi, S. Mirzaee, T. Rostamikia and R. Bagheri, Int. J. Corros., 2015, 197587 (2015);https://doi.org/10.1155/2015/197587
K.M. Emran, N.M. Ahmed, B.A. Torjoman, A.A. Al-Ahmadi and S.N. Sheekh, J. Mater. Environ. Sci., 5, 1940 (2014).
V. Chinapongtitiwat, S. Jongaroontaprangsee, N. Chiewchan and S. Devahastin, J. Funct. Foods, 5, 1151 (2013); https://doi.org/10.1016/j.jff.2013.03.012
D. Soares, L.M.J. de Carvalho, E.M. Gomes Ribeiro and G.M. Dellamora-Ortiz, ed. B. Valdez, Food Industrial Process-Methods and Equipment, Chap. 16, InTech, Croatia (2012).
O.K. Buyukkurt, G. Guclu, H. Kelebek and S. Selli, J. Food Meas. Charact., 13, 3242 (2019); https://doi.org/10.1007/s11694-019-00246-w
M.S. Waghaye SY Kshirsagar RB and Sawate AR, Int. J. Chem. Stud., 7, 1098 (2019).
F. Khosravi, N. Rastakhiz, B. Iranmanesh and S.S.S. Jafari Olia, Int. J. Life Sci. (Kathmandu), 9, 41 (2015); https://doi.org/10.3126/ijls.v9i5.12690
N. Jamil, R. Jabeen, M. Khan, M. Riaz, T. Naeem, A. Khan, N. Us Sabah, S.A. Ghori, U. Jabeen, Z.A. Bazai, A. Mushtaq, S. Rizwan and S. Fahmid, Int. J. Basic Appl. Sci., 15, 1 (2015).
M.S. Tounsi, W.A. Wannes, I. Ouerghemmi, S. Jegham, Y.B. Njima, G. Hamdaoui, H. Zemni and B. Marzouk, J. Sci. Food Agric., 91, 142 (2011); https://doi.org/10.1002/jsfa.4164
E.I. Oikeh, E.S. Omoregie, F.E. Oviasogie and K. Oriakhi, Food Sci. Nutr., 4, 103 (2016); https://doi.org/10.1002/fsn3.268
M.H. Othman Ahmed, A.A. Al-Amiery, Y.K. Al-Majedy, A.A.H. Kadhum, A.B. Mohamad and T.S. Gaaz, Results Phys., 8, 728 (2018);https://doi.org/10.1016/j.rinp.2017.12.039
A.G. Santos, G.O. da Rocha and J.B. de Andrade, Sci. Rep., 9, 1 (2019); https://doi.org/10.1038/s41598-018-37186-2
S. Lahrour, A. Benmoussat, B. Bouras, A. Mansri, L. Tannouga and S. Marzorati, Appl. Sci., 9, 4684 (2019); https://doi.org/10.3390/app9214684
R. Karthikaiselvi and S. Subhashini, J. Assoc. Arab Univ. Basic Appl. Sci., 16, 74 (2014);https://doi.org/10.1016/j.jaubas.2013.06.002
R.T. Loto and O. Tobilola, J. King Saud Univ. -Eng. Sci., 30, 384 (2018);https://doi.org/10.1016/j.jksues.2016.10.001
K. Boumhara, F. Bentiss, M. Tabyaoui, J. Costa, J.M. Desjobert, A. Bellaouchou, A. Guenbour, B. Hammouti and S.S. Al-Deyab, Int. J. Electrochem. Sci., 9, 1187 (2014).
H.A. Emriadi, Yulistia and Velly, Der Pharma Chem., 10, 79 (2018).
U. Nazir, Z. Akhter, N.K. Janjua, M.A. Asghar, S. Kanwal, T.M. Butt, A. Sani, F. Liaqat, R. Hussain and F.U. Shah, RSC Adv., 10, 7585 (2020); https://doi.org/10.1039/C9RA10692H
H. Lgaz, S.K. Saha, A. Chaouiki, K.S. Bhat, R. Salghi, Shubhalaxmi, P. Banerjee, I.H. Ali, M.I. Khan and I.-M. Chung, Constr. Build. Mater., 233, 117320 (2020); https://doi.org/10.1016/j.conbuildmat.2019.117320
H. Lgaz, S. Masroor, M. Chafiq, M. Damej, A. Brahmia, R. Salghi, M. Benmessaoud, I.H. Ali, M.M. Alghamdi, A. Chaouiki and I.-M. Chung, Metals, 10, 357 (2020); https://doi.org/10.3390/met10030357
W. Li, Int. J. Electrochem. Sci., 15, 722 (2020); https://doi.org/10.20964/2020.01.63
S. Dahiya, P. Pahuja, H. Lgaz, I.-M. Chung and S. Lata, J. Adhes. Sci. Technol., 33, 1066 (2019);https://doi.org/10.1080/01694243.2019.1576353
M.H. Sliem, M. Afifi, A.B. Radwan, E.M. Fayyad, M.F. Shibl, F.E.T. Heakal and A.M. Abdullah, Sci. Rep., 9, 2319 (2019); https://doi.org/10.1038/s41598-018-37254-7