Issue

Vol. 34 No. 3 (2022): Vol 34 Issue 3, 2022

Copyright (c) 2022 AJC

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Investigation of Structural and Catalytic Performance of Nano Crystalline Yttria Dopped Zirconia

https://doi.org/10.14233/ajchem.2022.23511
Ramejabi Jahangir Sayyad
Department of Chemistry, Yashwantrao Mohite College of Arts Science and Commerce, Bharati Vidyapeeth (Deemed to be University), Pune-411038, India
Shobha A. Waghmode
Department of Chemistry, Abasaheb Garware College, (Affiliated to Savitribai Phule Pune University, Pune), Pune-411004, India
Sharda R. Gadale
Department of Chemistry, Yashwantrao Mohite College of Arts Science and Commerce, Bharati Vidyapeeth (Deemed to be University), Pune-411038, India

Corresponding Author(s) : Sharda R. Gadale

dagade@rediffmail.com

Asian Journal of Chemistry, Vol. 34 No. 3 (2022): Vol 34 Issue 3, 2022

Abstract

Nanocrystalline yttria doped zirconia (YZ) were prepared by sol-gel method and characterized by XRD, SEM, EDX, TGA and XPS techniques. The XRD results indicated the formation highly crystalline material with 2 to 4 nm in size. The tetragonal phase of the nanoparticles was confirmed by XRD analysis. Small amount of this catalysts was efficiently catalyzed acetylation of benzyl alcohol with acetic anhydride in short time under solvent free conditions. The 5 wt.% YZ gave best results at 120 ºC with 100% conversion of benzyl alcohol with 100% selectivity of the product. Different parameters were studied for optimization of acetylation, which proved the catalysts has excellent activity and can be used at large scale applications in industry.

Keywords

Mixed metal oxide Sol gel Acetylation reaction Yttria Zirconia Green chemistry
Jahangir Sayyad, R., A. Waghmode, S., & R. Gadale, S. (2022). Investigation of Structural and Catalytic Performance of Nano Crystalline Yttria Dopped Zirconia. Asian Journal of Chemistry, 34(3), 733–739. https://doi.org/10.14233/ajchem.2022.23511
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. K.L. Chandra, P. Saravanan, R.K. Singh and V.K. Singh, Tetrahedron, 58, 1369 (2002); https://doi.org/10.1016/S0040-4020(01)01229-7
  2. S.K. De, Tetrahedron Lett., 45, 2919 (2004); https://doi.org/10.1016/j.tetlet.2004.02.071
  3. E. Torregiani, G. Seu, A. Minassi and G. Appendino, Tetrahedron Lett., 46, 2193 (2005); https://doi.org/10.1016/j.tetlet.2005.02.042
  4. A.K. Chakraborti and R. Gulhane, Synlett, 627 (2004); https://doi.org/10.1055/s-2004-815442
  5. T.S. Reddy, M. Narasimhulu, N. Suryakiran, K.C. Mahesh, K. Ashalatha and Y. Venkateswarlu, Tetrahedron Lett., 47, 6825 (2006); https://doi.org/10.1016/j.tetlet.2006.07.059
  6. A. Kamal, M.N.A. Khan, K.S. Reddy, Y.V.V. Srikanth and T. Krishnaji, Tetrahedron Lett., 48, 3813 (2007); https://doi.org/10.1016/j.tetlet.2007.03.162
  7. R. Das and D. Chakraborty, Synthesis, 1621 (2011); https://doi.org/10.1055/s-0030-1259999
  8. F. Rajabi, Tetrahedron Lett., 50, 395 (2009); https://doi.org/10.1016/j.tetlet.2008.11.024
  9. G.A. Meshram and V.D. Patil, Synth. Commun., 39, 4384 (2009); https://doi.org/10.1080/00397910902906529
  10. S.A.R. Mulla, S.M. Inamdar, M.Y. Pathan and S.S. Chavan, Open J. Synth. Theory Appl., 1, 31 (2012); https://doi.org/10.4236/ojsta.2012.13006
  11. A.K. Chakraborti and Shivani, J. Org. Chem., 71, 5785 (2006); https://doi.org/10.1021/jo0605142
  12. S.T. Kadam and S.S. Kim, Synthesis, 267 (2008); https://doi.org/10.1055/s-2007-1000859
  13. I. López, J.L. Bravo, M. Caraballo, J.L. Barneto and G. Silvero, Tetrahedron Lett., 52, 3339 (2011); https://doi.org/10.1016/j.tetlet.2011.04.079
  14. F. Tamaddon, M.A. Amrollahi and L. Sharafat, Tetrahedron Lett., 46, 7841 (2005); https://doi.org/10.1016/j.tetlet.2005.09.005
  15. M. Hosseini Sarvari and H. Sharghi, Tetrahedron, 61, 10903 (2005); https://doi.org/10.1016/j.tet.2005.09.002
  16. J. Albadi, A. Alihosseinzadeh and M. Mardani, Chin. J. Catal., 36, 308 (2015); https://doi.org/10.1016/S1872-2067(14)60259-X
  17. M.A. Bhosale, D. Ummineni, T. Sasaki, D. Nishio-Hamane and B.M. Bhanage, Mol. Catal. A: Chem, 404-405, 8 (2015); https://doi.org/10.1016/j.molcata.2015.04.002
  18. H. Veisi, S. Taheri and S. Hemmati, Green Chem., 18, 6337 (2016); https://doi.org/10.1039/C6GC01975G
  19. H.J. Yoon, S.-M. Lee, J.-H. Kim, H.-J. Cho, J.-W. Choi, S.-H. Lee and Y.-S. Lee, Tetrahedron Lett., 49, 3165 (2008); https://doi.org/10.1016/j.tetlet.2008.03.005
  20. K. Niknam and D. Saberi, Appl. Catal. A Gen., 366, 220 (2009); https://doi.org/10.1016/j.apcata.2009.07.014
  21. L. Osiglio, G. Romanelli and M. Blanco, J. Mol. Catal. Chem., 316, 52 (2010); https://doi.org/10.1016/j.molcata.2009.09.021
  22. S. Farhadi and S. Panahandehjoo, Appl. Catal. A Gen., 382, 293 (2010); https://doi.org/10.1016/j.apcata.2010.05.005
  23. A. Zarei, A.R. Hajipour and L. Khazdooz, Synth. Commun., 41, 1772 (2011); https://doi.org/10.1080/00397911.2010.492197
  24. P. Kumar, R.K. Pande, M.S. Bodas, S.P. Dagade and M.K. Dongare, J. Mol. Catal. Chem., 181, 207 (2002); https://doi.org/10.1016/S1381-1169(01)00365-X
  25. A. Kumar, P. Kumar and A.S. Dhaliwal, Mater. Sci. Eng., 1033, 012052 (2021); https://doi.org/10.1088/1757-899X/1033/1/012052
  26. S. Esposito, Materials, 12, 668 (2019); https://doi.org/10.3390/ma12040668
  27. L. Sun, H. Guo, H. Peng, S. Gong and H. Xu, Progr. Nat. Sci.: Mater. Int., 23, 440 (2013); https://doi.org/10.1016/j.pnsc.2013.06.013
  28. B.M. Reddy, B. Chowdhury, I. Ganesh, E.P. Reddy, T.C. Rojas and A. Fernández, J. Phys. Chem. B, 102, 10176 (1998); https://doi.org/10.1021/jp9826165
  29. D.D. Sarma and C.N.R. Rao, J. Electr. Spectrosc. Rel. Phenom., 20, 25 (1980); https://doi.org/10.1016/0368-2048(80)85003-1
  30. A.E. Hughes and B.A. Sexton, J. Electron. Spectrosc., 50, 15 (1990); https://doi.org/10.1016/0368-2048(90)87080-8
  31. R. Kaufmann, H. Klewe-Nebenius, H. Moers, G. Pfennig, H. Jenett and H.J. Ache, Interface Anal., 11, 502 (1988); https://doi.org/10.1002/sia.740111003
  32. V.B. Gade, A.K. Rathi, S.B. Bhalekar, J. Tucek, O. Tomanec, R.S. Varma, R. Zboril, S.N. Shelke and M.B. Gawande, ACS Sustain. Chem.& Eng., 5, 3314 (2017); https://doi.org/10.1021/acssuschemeng.6b03167
  33. S. Farhadi and K. Jahanara, Chin. J. Catal., 35, 368 (2014); https://doi.org/10.1016/S1872 2067(12)60758-X
  34. N. Anbu, N. Nagarjun, J.M.V.K. Kalaiarasi, A. Dhakshinamoorthy and M. Jacob, Chemistry, 1, 69 (2019); https://doi.org/10.3390/chemistry1010006
Read More
Author biographies is not available.
Download
PDF
Statistic
Read Counter : 0 Download : 0