Copyright (c) 2022 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Separation of Gadolinium(III) from Samarium(III) using Emulsion Liquid Membrane Method and The Application of Experimental Design for its Selection Parameters
Corresponding Author(s) : A. Anggraeni
Asian Journal of Chemistry,
Vol. 34 No. 3 (2022): Vol 34 Issue 3, 2022
Abstract
This study aimed to study the parameters, which affect the separation of gadolinium(III) from samarium(III) and determine extraction efficiency (%E) and stripping efficiency (%S). Parameter selection was made to design experiment using two-level factorial based on response concentration of gadolinium(III) maximum and samarium(III) minimum. A simulation sample of a mixture of gadolinium(III) and samarium(III) was mixed with an emulsion prepared from a mixture of di-2-ethylhexyl phosphoric acid (D2EHPA) or tributylphosphate (TBP) ligands extractant, surfactant and the internal phase. Then the extraction and stripping results were analyzed using ICP-AES. The results for %E and %S separation of gadolinium(III) from samarium(III) were 72.48% and 48.46%, respectively.
Keywords
Download Citation
Endnote/Zotero/Mendeley (RIS)BibTeX
- H. Yuan, W. Hong, Y. Zhou, B. Pu, A. Gong, T. Xu, Q. Yang, F. Li, L. Qiu, W. Zhang and Y. Liu, J. Rare Earths, 36, 642 (2018); https://doi.org/10.1016/j.jre.2018.01.011
- P. Davoodi-Nasab, A. Rahbar-Kelishami, J. Safdari and H. Abolghasemi, J. Mol. Liq., 262, 97 (2018); https://doi.org/10.1016/j.molliq.2018.04.062
- KESDM, Kajian Potensi Mineral Ikutan pada Pertambangan Timah. Pusat Data dan Teknologi Informasi Energi dan Sumber Daya Mineral, Jakarta, Indonesia (2017).
- M. Anitha, D.N. Ambare, D.K. Singh, H. Singh and P.K. Mohapatra, Chem. Eng. Res. Des., 98, 89 (2015); https://doi.org/10.1016/j.cherd.2015.04.011
- V. Baliram, Geosci. Front., 10, 1285 (2019); https://doi.org/10.1016/j.gsf.2018.12.005
- A.C. García, M. Latifi, A. Amini and J. Chaouki, Metals, 10, 1524 (2020); https://doi.org/10.3390/met10111524
- Y. Hu, J. Florek, D. Larivière, F.-G. Fontaine and F. Kleitz, The Chem. Record, 18, 1261 (2018); https://doi.org/10.1002/tcr.201800012
- S. Suren, T. Wongsawa, U. Pancharoen, T. Prapasawat and A.W. Lothongkum, Chem. Eng. J., 191, 503 (2012); https://doi.org/10.1016/j.cej.2012.03.010
- T. Tasaki, T. Oshima and Y. Baba, Ind. Eng. Chem. Res., 46, 5715 (2007); https://doi.org/10.1021/ie061671u
- S. Budiman, H.H. Bahti, A. Mutalib and A. Anggraeni, J. Sains Kesehatan, 1, 510 (2018).
- M. Raji, H. Abolghasemi, J. Safdari and A. Kargari, Chemical Eng. Processing Process Intensif.., 120, 184 (2017); https://doi.org/10.1016/j.cep.2017.06.010
- A.P. Panovska, J. Acevska, G. Stefkov, K. Brezovska, R. Petkovska and A. Dimitrovska, J. Chromatogr. Sci., 54, 103 (2015); https://doi.org/10.1093/chromsci/bmv123
- T. Jiapeng, L. Yiting and Z. Li, Prep. Biochem. Biotechnol., 44, 90 (2014); https://doi.org/10.1080/10826068.2013.833111
- M.A. Hasan, R.F. Aglan and S.A. El-Reefy, J. Hazard. Mater., 166, 1076 (2009); https://doi.org/10.1016/j.jhazmat.2008.12.010
- M.G. Kassem, A.M.M. Ahmed, H.H. Abdel-Rahman and A.H. Moustafa, Energy Reports., 5, 221 (2019); https://doi.org/10.1016/j.egyr.2019.01.009
- T. Handini, B. Ehb and S. Sukmajaya, IPTEK Nuklir, 20, 49 (2017); https://doi.org/10.17146/gnd.2017.20.1.3072
- M. Mulder. Basic Principles of Membrane Technology, Springer: Dordrecht (1997).
- A. Anggraeni, B. Mutalib, P. Primadhini and H.H. Bahti, Chim. Nat. Acta, 3, 80 (2015); https://doi.org/10.24198/cna.v3.n2.9197
- J.C. Miller and J.N. Miller, Statistic and Chemometrics for Analytical Chemistry, In: Handbook of Pharmaceutical Analysis by HPLC, Purdue Pharma: New York (2005).
References
H. Yuan, W. Hong, Y. Zhou, B. Pu, A. Gong, T. Xu, Q. Yang, F. Li, L. Qiu, W. Zhang and Y. Liu, J. Rare Earths, 36, 642 (2018); https://doi.org/10.1016/j.jre.2018.01.011
P. Davoodi-Nasab, A. Rahbar-Kelishami, J. Safdari and H. Abolghasemi, J. Mol. Liq., 262, 97 (2018); https://doi.org/10.1016/j.molliq.2018.04.062
KESDM, Kajian Potensi Mineral Ikutan pada Pertambangan Timah. Pusat Data dan Teknologi Informasi Energi dan Sumber Daya Mineral, Jakarta, Indonesia (2017).
M. Anitha, D.N. Ambare, D.K. Singh, H. Singh and P.K. Mohapatra, Chem. Eng. Res. Des., 98, 89 (2015); https://doi.org/10.1016/j.cherd.2015.04.011
V. Baliram, Geosci. Front., 10, 1285 (2019); https://doi.org/10.1016/j.gsf.2018.12.005
A.C. García, M. Latifi, A. Amini and J. Chaouki, Metals, 10, 1524 (2020); https://doi.org/10.3390/met10111524
Y. Hu, J. Florek, D. Larivière, F.-G. Fontaine and F. Kleitz, The Chem. Record, 18, 1261 (2018); https://doi.org/10.1002/tcr.201800012
S. Suren, T. Wongsawa, U. Pancharoen, T. Prapasawat and A.W. Lothongkum, Chem. Eng. J., 191, 503 (2012); https://doi.org/10.1016/j.cej.2012.03.010
T. Tasaki, T. Oshima and Y. Baba, Ind. Eng. Chem. Res., 46, 5715 (2007); https://doi.org/10.1021/ie061671u
S. Budiman, H.H. Bahti, A. Mutalib and A. Anggraeni, J. Sains Kesehatan, 1, 510 (2018).
M. Raji, H. Abolghasemi, J. Safdari and A. Kargari, Chemical Eng. Processing Process Intensif.., 120, 184 (2017); https://doi.org/10.1016/j.cep.2017.06.010
A.P. Panovska, J. Acevska, G. Stefkov, K. Brezovska, R. Petkovska and A. Dimitrovska, J. Chromatogr. Sci., 54, 103 (2015); https://doi.org/10.1093/chromsci/bmv123
T. Jiapeng, L. Yiting and Z. Li, Prep. Biochem. Biotechnol., 44, 90 (2014); https://doi.org/10.1080/10826068.2013.833111
M.A. Hasan, R.F. Aglan and S.A. El-Reefy, J. Hazard. Mater., 166, 1076 (2009); https://doi.org/10.1016/j.jhazmat.2008.12.010
M.G. Kassem, A.M.M. Ahmed, H.H. Abdel-Rahman and A.H. Moustafa, Energy Reports., 5, 221 (2019); https://doi.org/10.1016/j.egyr.2019.01.009
T. Handini, B. Ehb and S. Sukmajaya, IPTEK Nuklir, 20, 49 (2017); https://doi.org/10.17146/gnd.2017.20.1.3072
M. Mulder. Basic Principles of Membrane Technology, Springer: Dordrecht (1997).
A. Anggraeni, B. Mutalib, P. Primadhini and H.H. Bahti, Chim. Nat. Acta, 3, 80 (2015); https://doi.org/10.24198/cna.v3.n2.9197
J.C. Miller and J.N. Miller, Statistic and Chemometrics for Analytical Chemistry, In: Handbook of Pharmaceutical Analysis by HPLC, Purdue Pharma: New York (2005).