Copyright (c) 2022 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Study of Anticorrosive Action and Synthesis of 2-(Phenoxymethyl)-5-p-tolyl-1,3,4-oxadiazole in 1 M Hydrochloric Acid Medium for Mild Steel
Corresponding Author(s) : Hariom Dahiya
Asian Journal of Chemistry,
Vol. 34 No. 3 (2022): Vol 34 Issue 3, 2022
Abstract
Oxadiazole derivative 2-(phenoxymethyl)-5-p-tolyl-1,3,4-oxadiazole (2POM5PTO) was prepared by condensation of phenoxymethyl hydrazine with p-tolualdehyde. Further tested as corrosion inhibitor for mild steel via electrochemical methods, potentiodynamic polarization (PDP) and gravimetric experiments. An increasing trend in inhibition efficiency has been seen on raising the concentration of 2POM5PTO. PDP technique reveals the mixed-type inhibitor behaviour of 2POM5PTO. The depressed semicircular Nyquist plot explains that the charge transfer resistance increased with inhibitor concentration while double-layer capacitance (Cdl) decreased. The surface elucidation was done by scanning electron microscopy. The studied inhibitor obeys the Langmuir adsorption isotherm.
Keywords
Download Citation
Endnote/Zotero/Mendeley (RIS)BibTeX
- J. Aslam, R. Aslam, S.H. Alrefaee, M. Mobin, A. Aslam, M. Parveen and C. Mustansar Hussain, Arab. J. Chem., 13, 7744 (2020); https://doi.org/10.1016/j.arabjc.2020.09.008
- F. Boudjellal, H.B. Ouici, A. Guendouzi, O. Benali and A. Sehmi, J. Mol. Struct., 1199, 127051 (2020); https://doi.org/10.1016/j.molstruc.2019.127051
- M. Finšgar and J. Jackson, Corros. Sci., 86, 17 (2014); https://doi.org/10.1016/j.corsci.2014.04.044
- M. Goyal, S. Kumar, I. Bahadur, C. Verma and E.E. Ebenso, J. Mol. Liq., 256, 565 (2018); https://doi.org/10.1016/j.molliq.2018.02.045
- Y. Ye, Y. Zou, Z. Jiang, Q. Yang, L. Chen, S. Guo and H. Chen, J. Alloys Compd., 815, 152338 (2020); https://doi.org/10.1016/j.jallcom.2019.152338
- Y. Ye, D. Yang, H. Chen, S. Guo, Q. Yang, L. Chen, H.C. Zhao and L. Wang, J. Hazard. Mater., 381, 121019 (2020); https://doi.org/10.1016/j.jhazmat.2019.121019
- Y. Ye, Z. Jiang, Y. Zou, H. Chen, S. Guo, Q. Yang and L. Chen, J. Mater. Sci. Technol., 43, 144 (2020); https://doi.org/10.1016/j.jmst.2020.01.025
- V. Kalia, P. Kumar, S. Kumar, P. Pahuja, G. Jha, S. Lata and H. Dahiya, J. Mol. Liq., 313, 11360 (2020); https://doi.org/10.1016/j.molliq.2020.113601
- P. Niu, J. Kang, X. Tian, L. Song, H. Liu, J. Wu, W. Yu and J. Chang, J. Org. Chem., 80, 1018 (2015); https://doi.org/10.1021/jo502518c
- S.K. Saha, Phys. Chem. Chem. Phys., 8, 17898 (2016); https://doi.org/10.1039/C6CP01993E
- M. Edrakia, I.M. Moghadam, M.B. Keivanic and M.H. Fekri, Iran. Chem. Commun., 7, 228 (2019); https://doi.org/10.30473/icc.2018.42617.1486
- H. Lgaz, I.-M. Chung, R. Salghi, I.H. Ali, A. Chaouiki, Y. El Aoufir and M.I. Khan, Appl. Surf. Sci., 463, 647 (2019); https://doi.org/10.1016/j.apsusc.2018.09.001
- W. Zhang, H.-J. Li, L. Chen, S. Zhang, Y. Ma, C. Ye, Y. Zhou, B. Pang and Y.-C. Wu, Carbohydr. Polym., 238, 116216 (2020); https://doi.org/10.1016/j.carbpol.2020.116216
- H. Khaleel, A.A. Ateeq and A.A. Ali, Int. J. Appl. Eng. Res., 13, 3638 (2018).
- A. Anees, J. Chil. Chem. Soc., 3, 2545 (2014).
- F. El-Taib Heakal, M.A. Deyab, M.M. Osman and A.E. Elkholy, Desalination, 425, 111 (2018); https://doi.org/10.1016/j.desal.2017.10.019
- I.B. Onyeachu, M.M. Solomon, S.A. Umoren, I.B. Obot and A.A. Sorour, Desalination, 479, 114283 (2020); https://doi.org/10.1016/j.desal.2019.114283
- D.B. Tripathy, M. Murmu, P. Banerjee and M.A. Quraishi, Desalination, 472, 114128 (2019); https://doi.org/10.1016/j.desal.2019.114128
- Y. Zhou, S. Xu, L. Guo, S. Zhang, H. Lu, Y. Gong and F. Gao, RSC Adv., 5, 14804 (2015); https://doi.org/10.1039/C4RA14449J
- A. Dutta, S.K. Saha, U. Adhikari, P. Banerjee and D. Sukul, Corros. Sci., 123, 256 (2017); https://doi.org/10.1016/j.corsci.2017.04.017
- M. Murmu, S.K. Saha, N.C. Murmu and P. Banerjee, Corros. Sci., 146, 134 (2019); https://doi.org/10.1016/j.corsci.2018.10.002
- M. Faustin, A. Maciuk, P. Salvin, C. Roos and M. Lebrini, Corros. Sci., 92, 287 (2015); https://doi.org/10.1016/j.corsci.2014.12.005
- M.A. Deyab and S.S.A. El-Rehim, J. Taiwan Inst. Chem. Eng., 45, 1065 (2014); https://doi.org/10.1016/j.jtice.2013.09.004
- M. Bahrami, S. Hosseini and P. Pilvar, Corros. Sci., 52, 2793 (2010); https://doi.org/10.1016/j.corsci.2010.04.024
- M. Hegazy, M. Abdallah and H. Ahmed, Corros. Sci., 52, 2897 (2010); https://doi.org/10.1016/j.corsci.2010.04.034
- A.H. Alamri, Desalination, 470, 114100 (2019); https://doi.org/10.1016/j.desal.2019.114100
- F. El-Taib Heakal, A.S. Fouda and M.S. Radwan, Mater. Chem. Phys., 125, 26 (2011); https://doi.org/10.1016/j.matchemphys.2010.08.067
- T. Poornima, J. Nayak and A. Nityananda Shetty, Corros. Sci., 53, 3688 (2011); https://doi.org/10.1016/j.corsci.2011.07.014
- S. Banerjee, V. Srivastava and M. Singh, Corros. Sci., 59, 35 (2012); https://doi.org/10.1016/j.corsci.2012.02.009
- D.K. Yadav, M. Quraishi and B. Maiti, Corros. Sci., 55, 254 (2012); https://doi.org/10.1016/j.corsci.2011.10.030
- A.Y. Musa, A.A.H. Kadhum, A.B. Mohamad, A.A.B. Rahoma and H. Mesmari, J. Mol. Struct., 969, 233 (2010); https://doi.org/10.1016/j.molstruc.2010.02.051
- M. Ouakki, M. Galai, M. Rbaa, A.S. Abousalem, B. Lakhrissi, E.H. Rifi and M. Cherkaoui, Heliyon, 5, e02759 (2019); https://doi.org/10.1016/j.heliyon.2019.e02759
- J.A. Syed, S. Tang, H. Lu and X. Meng, Ind. Eng. Chem. Res., 54, 2950 (2015); https://doi.org/10.1021/ie5046395
- C.B. Verma, M.A. Quraishi and E.E. Ebenso, Int. J. Electrochem. Sci., 9, 5537 (2014).
- S.A. Umoren, U.M. Eduok, M.M. Solomon and A.P. Udoh, Arab. J. Chem., 9, S209 (2016); https://doi.org/10.1016/j.arabjc.2011.03.008
- N.B. Iroha and N.J. Maduelosi, ISOR J. Appl. Chem., 13, 30 (2020).
- N.O. Eddy, H. Momoh-Yahaya and E.E. Oguzie, J. Adv. Res., 6, 203 (2015); https://doi.org/10.1016/j.jare.2014.01.004
- M. Kraljic Rokovic, K. Kvastek, V. Horvat-Radoševic and L. Duic, Corros. Sci., 49, 2567 (2007); https://doi.org/10.1016/j.corsci.2006.12.010
- K.F. Khaled, Mater. Chem. Phys., 112, 290 (2008); https://doi.org/10.1016/j.matchemphys.2008.05.056
- A.O. James and N.B. Iroha, ISOR J. Appl. Chem., 12, 1 (2019).
- M. Özcan and I. Dehri, Corros. Sci., 54, 201 (2012); https://doi.org/10.1016/j.corsci.2011.09.013
- M.E. Belghiti, S. Echihi, A. Dafali, Y. Karzazi, M. Bakasse, H. ElalaouiElabdallaoui, L.O. Olasunkanmi, E.E. Ebenso and M. Tabyaoui, Appl. Surf. Sci., 491, 707 (2019); https://doi.org/10.1016/j.apsusc.2019.04.125
References
J. Aslam, R. Aslam, S.H. Alrefaee, M. Mobin, A. Aslam, M. Parveen and C. Mustansar Hussain, Arab. J. Chem., 13, 7744 (2020); https://doi.org/10.1016/j.arabjc.2020.09.008
F. Boudjellal, H.B. Ouici, A. Guendouzi, O. Benali and A. Sehmi, J. Mol. Struct., 1199, 127051 (2020); https://doi.org/10.1016/j.molstruc.2019.127051
M. Finšgar and J. Jackson, Corros. Sci., 86, 17 (2014); https://doi.org/10.1016/j.corsci.2014.04.044
M. Goyal, S. Kumar, I. Bahadur, C. Verma and E.E. Ebenso, J. Mol. Liq., 256, 565 (2018); https://doi.org/10.1016/j.molliq.2018.02.045
Y. Ye, Y. Zou, Z. Jiang, Q. Yang, L. Chen, S. Guo and H. Chen, J. Alloys Compd., 815, 152338 (2020); https://doi.org/10.1016/j.jallcom.2019.152338
Y. Ye, D. Yang, H. Chen, S. Guo, Q. Yang, L. Chen, H.C. Zhao and L. Wang, J. Hazard. Mater., 381, 121019 (2020); https://doi.org/10.1016/j.jhazmat.2019.121019
Y. Ye, Z. Jiang, Y. Zou, H. Chen, S. Guo, Q. Yang and L. Chen, J. Mater. Sci. Technol., 43, 144 (2020); https://doi.org/10.1016/j.jmst.2020.01.025
V. Kalia, P. Kumar, S. Kumar, P. Pahuja, G. Jha, S. Lata and H. Dahiya, J. Mol. Liq., 313, 11360 (2020); https://doi.org/10.1016/j.molliq.2020.113601
P. Niu, J. Kang, X. Tian, L. Song, H. Liu, J. Wu, W. Yu and J. Chang, J. Org. Chem., 80, 1018 (2015); https://doi.org/10.1021/jo502518c
S.K. Saha, Phys. Chem. Chem. Phys., 8, 17898 (2016); https://doi.org/10.1039/C6CP01993E
M. Edrakia, I.M. Moghadam, M.B. Keivanic and M.H. Fekri, Iran. Chem. Commun., 7, 228 (2019); https://doi.org/10.30473/icc.2018.42617.1486
H. Lgaz, I.-M. Chung, R. Salghi, I.H. Ali, A. Chaouiki, Y. El Aoufir and M.I. Khan, Appl. Surf. Sci., 463, 647 (2019); https://doi.org/10.1016/j.apsusc.2018.09.001
W. Zhang, H.-J. Li, L. Chen, S. Zhang, Y. Ma, C. Ye, Y. Zhou, B. Pang and Y.-C. Wu, Carbohydr. Polym., 238, 116216 (2020); https://doi.org/10.1016/j.carbpol.2020.116216
H. Khaleel, A.A. Ateeq and A.A. Ali, Int. J. Appl. Eng. Res., 13, 3638 (2018).
A. Anees, J. Chil. Chem. Soc., 3, 2545 (2014).
F. El-Taib Heakal, M.A. Deyab, M.M. Osman and A.E. Elkholy, Desalination, 425, 111 (2018); https://doi.org/10.1016/j.desal.2017.10.019
I.B. Onyeachu, M.M. Solomon, S.A. Umoren, I.B. Obot and A.A. Sorour, Desalination, 479, 114283 (2020); https://doi.org/10.1016/j.desal.2019.114283
D.B. Tripathy, M. Murmu, P. Banerjee and M.A. Quraishi, Desalination, 472, 114128 (2019); https://doi.org/10.1016/j.desal.2019.114128
Y. Zhou, S. Xu, L. Guo, S. Zhang, H. Lu, Y. Gong and F. Gao, RSC Adv., 5, 14804 (2015); https://doi.org/10.1039/C4RA14449J
A. Dutta, S.K. Saha, U. Adhikari, P. Banerjee and D. Sukul, Corros. Sci., 123, 256 (2017); https://doi.org/10.1016/j.corsci.2017.04.017
M. Murmu, S.K. Saha, N.C. Murmu and P. Banerjee, Corros. Sci., 146, 134 (2019); https://doi.org/10.1016/j.corsci.2018.10.002
M. Faustin, A. Maciuk, P. Salvin, C. Roos and M. Lebrini, Corros. Sci., 92, 287 (2015); https://doi.org/10.1016/j.corsci.2014.12.005
M.A. Deyab and S.S.A. El-Rehim, J. Taiwan Inst. Chem. Eng., 45, 1065 (2014); https://doi.org/10.1016/j.jtice.2013.09.004
M. Bahrami, S. Hosseini and P. Pilvar, Corros. Sci., 52, 2793 (2010); https://doi.org/10.1016/j.corsci.2010.04.024
M. Hegazy, M. Abdallah and H. Ahmed, Corros. Sci., 52, 2897 (2010); https://doi.org/10.1016/j.corsci.2010.04.034
A.H. Alamri, Desalination, 470, 114100 (2019); https://doi.org/10.1016/j.desal.2019.114100
F. El-Taib Heakal, A.S. Fouda and M.S. Radwan, Mater. Chem. Phys., 125, 26 (2011); https://doi.org/10.1016/j.matchemphys.2010.08.067
T. Poornima, J. Nayak and A. Nityananda Shetty, Corros. Sci., 53, 3688 (2011); https://doi.org/10.1016/j.corsci.2011.07.014
S. Banerjee, V. Srivastava and M. Singh, Corros. Sci., 59, 35 (2012); https://doi.org/10.1016/j.corsci.2012.02.009
D.K. Yadav, M. Quraishi and B. Maiti, Corros. Sci., 55, 254 (2012); https://doi.org/10.1016/j.corsci.2011.10.030
A.Y. Musa, A.A.H. Kadhum, A.B. Mohamad, A.A.B. Rahoma and H. Mesmari, J. Mol. Struct., 969, 233 (2010); https://doi.org/10.1016/j.molstruc.2010.02.051
M. Ouakki, M. Galai, M. Rbaa, A.S. Abousalem, B. Lakhrissi, E.H. Rifi and M. Cherkaoui, Heliyon, 5, e02759 (2019); https://doi.org/10.1016/j.heliyon.2019.e02759
J.A. Syed, S. Tang, H. Lu and X. Meng, Ind. Eng. Chem. Res., 54, 2950 (2015); https://doi.org/10.1021/ie5046395
C.B. Verma, M.A. Quraishi and E.E. Ebenso, Int. J. Electrochem. Sci., 9, 5537 (2014).
S.A. Umoren, U.M. Eduok, M.M. Solomon and A.P. Udoh, Arab. J. Chem., 9, S209 (2016); https://doi.org/10.1016/j.arabjc.2011.03.008
N.B. Iroha and N.J. Maduelosi, ISOR J. Appl. Chem., 13, 30 (2020).
N.O. Eddy, H. Momoh-Yahaya and E.E. Oguzie, J. Adv. Res., 6, 203 (2015); https://doi.org/10.1016/j.jare.2014.01.004
M. Kraljic Rokovic, K. Kvastek, V. Horvat-Radoševic and L. Duic, Corros. Sci., 49, 2567 (2007); https://doi.org/10.1016/j.corsci.2006.12.010
K.F. Khaled, Mater. Chem. Phys., 112, 290 (2008); https://doi.org/10.1016/j.matchemphys.2008.05.056
A.O. James and N.B. Iroha, ISOR J. Appl. Chem., 12, 1 (2019).
M. Özcan and I. Dehri, Corros. Sci., 54, 201 (2012); https://doi.org/10.1016/j.corsci.2011.09.013
M.E. Belghiti, S. Echihi, A. Dafali, Y. Karzazi, M. Bakasse, H. ElalaouiElabdallaoui, L.O. Olasunkanmi, E.E. Ebenso and M. Tabyaoui, Appl. Surf. Sci., 491, 707 (2019); https://doi.org/10.1016/j.apsusc.2019.04.125