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Synthesis and Characterization of Some Copper(I) Complexes Formed by the Insertion of Carbon Disulfide in L2CuCl (L = PPh3, AsPh3 and SbPh3)
Corresponding Author(s) : P.K. Gogoi
Asian Journal of Chemistry,
Vol. 29 No. 3 (2017): Vol 29 Issue 3
Abstract
Insertion reaction of carbon disulfide with bis(triphenyl phosphine), bis(triphenyl arsine) or bis(triphenyl stibine) copper(I) chloride in a mixed solvent of dichloromethane and ethanol results in the formation of new class of copper (I) complexes of the type [L2Cu(S2COEt)] (L = PPh3, AsPh3 and SbPh3). These three new complexes have been characterized by chemical analysis, DTA, TGA and infrared spectroscopic method. The molar conductances of these complexes are measured in dichloromethane (10-3 M) at room temperature.
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- P. Mathur, A.K. Ghosh, S. Mukhopadhyay, C. Srinivasu and S.M. Mobin, J. Organomet. Chem., 678, 142 (2003).
- Z. Dong, L. Guanliang, Z. Liang and Z. Chuanjan, Indian J. Chem., 42A, 1102 (2004).
- D. Theodoropoulos, J. Gazopoulos, I. Souchleris, F.L. Allen, R.E. Jewell, H. Suschitzky, E.D. Bergmann, I. Shahak, E.R.S. Winter, L.D. Eaton, A.G. Massey, H. Irving, R.D. Gillard, F.A. Cotton, D.M.L. Goodgame, F.D. Popp, I.L. Finar, K. Utting, P.K. Grant, R. Hodges, R. Colton, R. Levitus and G. Wilkinson, J. Chem. Soc., 5257 (1960).
- P.K. Gogoi, G. Borah, N. Bharali and D. Saikia, Indian J. Chem., 46A, 1113 (2007).
- D.F. Evans, J. Chem. Soc., 2003 (1959).
- C. Mealli, R. Hoffmann and A. Stockis, Inorg. Chem., 23, 56 (1984).
- T. Ziegler, Inorg. Chem., 25, 2721 (1986).
- S. Sakaki, K. Kitaura and K. Morokuma, Inorg. Chem., 21, 760 (1982).
- A. Rosi, A. Sgamellotti, F. Tarantelli and C. Floriani, Inorg. Chem., 26, 3805 (1987).
- F.G. Moers, R.W.M. Ten Hoedt and J.P. Langhout, Inorg. Chem., 12, 2196 (1973).
References
P. Mathur, A.K. Ghosh, S. Mukhopadhyay, C. Srinivasu and S.M. Mobin, J. Organomet. Chem., 678, 142 (2003).
Z. Dong, L. Guanliang, Z. Liang and Z. Chuanjan, Indian J. Chem., 42A, 1102 (2004).
D. Theodoropoulos, J. Gazopoulos, I. Souchleris, F.L. Allen, R.E. Jewell, H. Suschitzky, E.D. Bergmann, I. Shahak, E.R.S. Winter, L.D. Eaton, A.G. Massey, H. Irving, R.D. Gillard, F.A. Cotton, D.M.L. Goodgame, F.D. Popp, I.L. Finar, K. Utting, P.K. Grant, R. Hodges, R. Colton, R. Levitus and G. Wilkinson, J. Chem. Soc., 5257 (1960).
P.K. Gogoi, G. Borah, N. Bharali and D. Saikia, Indian J. Chem., 46A, 1113 (2007).
D.F. Evans, J. Chem. Soc., 2003 (1959).
C. Mealli, R. Hoffmann and A. Stockis, Inorg. Chem., 23, 56 (1984).
T. Ziegler, Inorg. Chem., 25, 2721 (1986).
S. Sakaki, K. Kitaura and K. Morokuma, Inorg. Chem., 21, 760 (1982).
A. Rosi, A. Sgamellotti, F. Tarantelli and C. Floriani, Inorg. Chem., 26, 3805 (1987).
F.G. Moers, R.W.M. Ten Hoedt and J.P. Langhout, Inorg. Chem., 12, 2196 (1973).