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Vol. 29 No. 3 (2017): Vol 29 Issue 3

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Synthesis, Characterization and Biocidal Properties of Oxovanadium Complexes

https://doi.org/10.14233/ajchem.2017.20286
Ashfaque Karim
Institute of Bio-Chemistry, Magadh University, Bodh Gaya-824 234, India
Rekha Rani
Institute of Bio-Chemistry, Magadh University, Bodh Gaya-824 234, India
Rajeeva Ranjan
Institute of Bio-Chemistry, Magadh University, Bodh Gaya-824 234, India
Umesh Kumar
Institute of Bio-Chemistry, Magadh University, Bodh Gaya-824 234, India
Vijay Kumar
P.G. Department of Chemistry, Raj Narain College, Hazipur-844 101, India
Shivadhar Sharma
Institute of Bio-Chemistry, Magadh University, Bodh Gaya-824 234, India

Corresponding Author(s) : Shivadhar Sharma

sharma.shivadhar@gmail.com

Asian Journal of Chemistry, Vol. 29 No. 3 (2017): Vol 29 Issue 3

Abstract

VO(II) and VO(III) undergo complexation with tetradentate ligands viz. N,N’-bis(3-hydroxy quinoxaline-2-carboxalidene)-1,2-diaminocyclohexane (NQCH), N,N’-bis(3-hydroxyquinoxaline-2-carboxalidene)-1,8-diaminonapthaline (NQAN) and N,N’-(3-hydroxy quinoxaline-2-carboxalidene)-2,3-diaminomaleonitrile (NQAM). On the basis of micro analytical data, the complexes are formulated as [VOL(H2O)]SO4, [VOL(H2O)]Cl2 and [VOL(H2O)]Cl3 where L is NQCH, NQAN or NQAM. These complexes have been characterized by infrared spectroscopy, molar conductivity, magnetic moment and electronic spectra. VO(II) complexes are found tetragonally distorted octahedral with –ve Dt value indicating compression along Z-axis. VO(III) complexes are diamagnetic in nature. The ligands as well as their oxovanadium complexes have been screened against some bacteria E. coli and S. aureus and plant pathogenic fungi, A. niger and C. albicans. All the complexes are found to be more active than the corresponding ligands against both bacteria and fungi.

Keywords

Tetragonally distorted octahedral Antimicrobials activity Tetradentate ligand
Karim, A., Rani, R., Ranjan, R., Kumar, U., Kumar, V., & Sharma, S. (2016). Synthesis, Characterization and Biocidal Properties of Oxovanadium Complexes. Asian Journal of Chemistry, 29(3), 626–630. https://doi.org/10.14233/ajchem.2017.20286
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