Copyright (c) 2017 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Adsorption of Fe3+ Ion from Aqueous Solution by Activated Carbon Prepared from Leucas aspera: Thermodynamic, Kinetic and Equilibrium Approach
Corresponding Author(s) : N. Ramalakshmi
Asian Journal of Chemistry,
Vol. 29 No. 3 (2017): Vol 29 Issue 3
Abstract
The adsorption process using low cost adsorbent carbon prepared from useless agricultural plant is very potential method to removing both organic and inorganic pollutants especially heavy metals. The present study reports the removal of iron(III) ions from contaminated aqueous solution by using roots and leaves of Leucas aspera. The adsorption process is also affected by various factors like temperature, contact time, adsorbent dosage and pH of the solution. The fitness of present study is also confirmed by verifying of Feundlich isotherm and Langmuir isotherm. The feasibility and nature of the process is also confirmed by thermodynamic parameters like DG, DH and DS. And also calculate kinetic parameters verifying by pseudo-second order kinetics, Elovich model and intra-particle diffusion model. Finally, the adsorption process is confirmed by FT-IR, XRD of before and after adsorption process of adsorbent.
Keywords
Download Citation
Endnote/Zotero/Mendeley (RIS)BibTeX
- M.W. Hodgate, A Perspective of Environmental Pollution, (Cambridge University Press, Cambridge) 1979.
- P.E.Vladimir Novotny, and Gordon Chesters, Handbook of Non-point Pollution: Sources and Management, (Van Nostrand Reinhold Company, New York) 1991.
- G.Z. Kyzas and M. Kostoglou, Materials, 7, 333 (2014).
- F.L. Fu and Q. Wang, J. Environ. Manag., 92, 407 (2011).
- A.K. Patil and V.S. Shrivastava, Arch. Appl. Sci. Res., 2, 404 (2010).
- F.C. Wu, R.-L. Tseng and R.-S. Juang, J. Environ. Manage., 91, 798 (2010).
- K. Kaikake, K. Hoaki, H. Sunada, R.P. Dhakal and Y. Baba, Bioresour. Technol., 98, 2787 (2007).
- N. Das and R.K. Jana, J. Colloid Interface Sci., 293, 253 (2006).
- N. Fiol, I. Villaescusa, M. Martinez, N. Miralles, J. Poch and J. Serarols, Sep. Purif. Technol., 50, 132 (2006).
- S. Saxena and S.F. D’Souza, Environ. Int., 32, 199 (2006).
- E. Chockalingam and S. Subramanian, Chemosphere, 62, 699 (2006).
- S.R. Shukla, R.S. Pai and A.D. Shendarkar, Sep. Purif. Technol., 47, 141 (2006).
- S. Wang, M. Soudi, L. Li and Z.H. Zhu, J. Hazard. Mater., 133, 243 (2006).
- C. Namasivayam and D. Sangeetha, J. Hazard. Mater., 135, 449 (2006).
- S.M. Nomanbhay and K. Palanisamy, Electron. J. Biotechnol., 8, 43 (2005).
- B.H. Hameed, R.R. Krishni and S.A. Sata, J. Hazard. Mater., 162, 305 (2009).
- R. Sudha, K. Kalpana, T. Rajachandrasekar and S. Arivoli, E-J. Chem., 4, 238 (2007).
- D.I. Mall, V.C. Srivastava and N.K. Agarwal, Dyes Pigments, 69, 210 (2006).
- Sivaraj, C. Namasivayam and K. Kadirvelu, Waste Manag., 21, 105 (2001).
- H. Freundlich, Z. Phys. Chem., 57, 385 (1906).
- S. Arivoli, Ph.D. Thesis, Kinetic and Thermodynamic Studies on the Adsorption of Some Metal Ions and Dyes on to Low Cost Activated Carbons, Gandhigram Rural University, Gandhigram, India (2007).
- X. Luo, X. Su, W. Gao, G. Zhan and X. Chang, Analyst, 117, 145 (1992).
- R. Schmuhl, H.M. Krieg and K. Keizerk, Water SA, 27, 1 (2001).
- I. Langmuir, J. Am. Chem. Soc., 40, 1361 (1918).
- T.W. Weber and R.K. Chakravorti, J. Am. Inst. Chem. Eng., 20, 228 (1974).
- G. McKay, H.S. Blair and J.R. Gardner, J. Appl. Polym. Sci., 27, 3043 (1982).
- A.A. Khan and R.P. Singh, J. Colloid Interface Sci., 24, 33 (1987).
- Y.S. Ho, Water Res., 34, 735 (2000).
- S.H. Chien and W.R. Clayton, Soil Sci. Soc. Am. J., 44, 265 (1980).
- W.J. Weber and J.C. Morris, J. Sanit. Engg. Div., 90, 79 (1964).
References
M.W. Hodgate, A Perspective of Environmental Pollution, (Cambridge University Press, Cambridge) 1979.
P.E.Vladimir Novotny, and Gordon Chesters, Handbook of Non-point Pollution: Sources and Management, (Van Nostrand Reinhold Company, New York) 1991.
G.Z. Kyzas and M. Kostoglou, Materials, 7, 333 (2014).
F.L. Fu and Q. Wang, J. Environ. Manag., 92, 407 (2011).
A.K. Patil and V.S. Shrivastava, Arch. Appl. Sci. Res., 2, 404 (2010).
F.C. Wu, R.-L. Tseng and R.-S. Juang, J. Environ. Manage., 91, 798 (2010).
K. Kaikake, K. Hoaki, H. Sunada, R.P. Dhakal and Y. Baba, Bioresour. Technol., 98, 2787 (2007).
N. Das and R.K. Jana, J. Colloid Interface Sci., 293, 253 (2006).
N. Fiol, I. Villaescusa, M. Martinez, N. Miralles, J. Poch and J. Serarols, Sep. Purif. Technol., 50, 132 (2006).
S. Saxena and S.F. D’Souza, Environ. Int., 32, 199 (2006).
E. Chockalingam and S. Subramanian, Chemosphere, 62, 699 (2006).
S.R. Shukla, R.S. Pai and A.D. Shendarkar, Sep. Purif. Technol., 47, 141 (2006).
S. Wang, M. Soudi, L. Li and Z.H. Zhu, J. Hazard. Mater., 133, 243 (2006).
C. Namasivayam and D. Sangeetha, J. Hazard. Mater., 135, 449 (2006).
S.M. Nomanbhay and K. Palanisamy, Electron. J. Biotechnol., 8, 43 (2005).
B.H. Hameed, R.R. Krishni and S.A. Sata, J. Hazard. Mater., 162, 305 (2009).
R. Sudha, K. Kalpana, T. Rajachandrasekar and S. Arivoli, E-J. Chem., 4, 238 (2007).
D.I. Mall, V.C. Srivastava and N.K. Agarwal, Dyes Pigments, 69, 210 (2006).
Sivaraj, C. Namasivayam and K. Kadirvelu, Waste Manag., 21, 105 (2001).
H. Freundlich, Z. Phys. Chem., 57, 385 (1906).
S. Arivoli, Ph.D. Thesis, Kinetic and Thermodynamic Studies on the Adsorption of Some Metal Ions and Dyes on to Low Cost Activated Carbons, Gandhigram Rural University, Gandhigram, India (2007).
X. Luo, X. Su, W. Gao, G. Zhan and X. Chang, Analyst, 117, 145 (1992).
R. Schmuhl, H.M. Krieg and K. Keizerk, Water SA, 27, 1 (2001).
I. Langmuir, J. Am. Chem. Soc., 40, 1361 (1918).
T.W. Weber and R.K. Chakravorti, J. Am. Inst. Chem. Eng., 20, 228 (1974).
G. McKay, H.S. Blair and J.R. Gardner, J. Appl. Polym. Sci., 27, 3043 (1982).
A.A. Khan and R.P. Singh, J. Colloid Interface Sci., 24, 33 (1987).
Y.S. Ho, Water Res., 34, 735 (2000).
S.H. Chien and W.R. Clayton, Soil Sci. Soc. Am. J., 44, 265 (1980).
W.J. Weber and J.C. Morris, J. Sanit. Engg. Div., 90, 79 (1964).