Studies on Electrochemical Behaviour of Copper(II)-Dithiocarbamate Complexes at DME: Applications to Environmental and Biological Samples

Niranjan Thondavada; Suvardhan Kanchi; Giridhar Chembeti; Bisetty Krishna; Venkatasubba Naidu Nuthalapati

doi:10.14233/ajchem.2017.20274

Issue

Vol. 29 No. 3 (2017): Vol 29 Issue 3

Issue Published : December 30, 2016

This work is licensed under a Creative Commons Attribution 4.0 International License.

Studies on Electrochemical Behaviour of Copper(II)-Dithiocarbamate Complexes at DME: Applications to Environmental and Biological Samples

https://doi.org/10.14233/ajchem.2017.20274

Niranjan Thondavada

Department of Chemistry, Sri Venkateswara University, Tirupati-517 502, India

Suvardhan Kanchi

Department of Chemistry, Durban University of Technology, P.O. Box 1334, Durban 4000, South Africa

Giridhar Chembeti

Department of Chemistry, Sri Venkateswara University, Tirupati-517 502, India

Bisetty Krishna

Department of Chemistry, Durban University of Technology, P.O. Box 1334, Durban 4000, South Africa

Venkatasubba Naidu Nuthalapati

Department of Chemistry, Sri Venkateswara University, Tirupati-517 502, India

Corresponding Author(s) : Venkatasubba Naidu Nuthalapati

nvsn69@gmail.com

Asian Journal of Chemistry, Vol. 29 No. 3 (2017): Vol 29 Issue 3
Article Published : December 30, 2016

Abstract

Catalytic hydrogen current method has been explained for the sensitive and selective detection of copper(II) using ammonium 4-phenylpiperazine-1-dithiocarbamate (Amm 4-PP-DTC) and ammonium 4-benzylpiperidine-1-dithiocarbamate (Amm 4-BP-DTC) in different environmental and biological matrices. It was mainly depends on the interaction of copper(II) with 4-Amm 4-PP-DTC and Amm 4-BP-DTC in background electrolyte (NH₄Cl-NH₄OH) medium at pH 6.6. The pronounced parabolic shaped peaks were observed at -0.31 V and -0.48 V vs. SCE, respectively due to the catalytic hydrogen currents produced from the dithiocarbamate-metal complexes. Then after, catalytic hydrogen currents were recorded using D.C polarography. pH effect, background electrolyte (NH₄Cl-NH₄OH) effect and dithiocarbamates and copper(II) ion effects were optimized in this study. The present developed method was fruitfully applied to analyze copper(II) in various sample of environmental and biological importance. The recovery percentages obtained from this study were found to be 95-99 % and comparable with AAS method.

Keywords

Polarography Copper(II) Ammonium 4-arylpiperazine-1-dithiocarbamate Atomic absorption spectroscopy

Thondavada, N., Kanchi, S., Chembeti, G., Krishna, B., & Nuthalapati, V. N. (2016). Studies on Electrochemical Behaviour of Copper(II)-Dithiocarbamate Complexes at DME: Applications to Environmental and Biological Samples. Asian Journal of Chemistry, 29(3), 609–613. https://doi.org/10.14233/ajchem.2017.20274

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References

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S.P. Ananda and O. Donald, Trace Elem. Human Health Diseases, 1, (1976).

G.L. Eichhorn, Inorganic Bio-Chemistry, Elsevier Scientific Publishing Company, New York,(1975).

R.A. Romeno, J.A. Navarro, B. Rodriguez, R. Garlica, O.E. Parra and T. Grandillo, Trace Elem. Med., 7, 176 (1970).

J. Shen, S. Chen and C. Zhang, Shanghai Yixue, 14, 603 (1991).

P.A. Waldravens, Clin. Chem., 26, 185 (1980).

I.H. Scheinberg and I. Sternleib, Pharmacol. Rev., 12, 204 (1933).

E.J. Underwood, Trace Elements in Human and Animal Nutrition, Academic Press, New York, edn 4 (1979).

P.L. Malvankar and V.M. Shinde, Analyst, 116, 1081 (1991).

P.M. Rao and S.B. Rao, Indian J. Chem., 9, 1014 (1971).

P.M. Rao and S.B. Rao, Indian J. Chem., 11, 1160 (1973).

D. Rekha, N.Y. Sreedhar and P.R. Prasad, Global J. Sci. Front. Res., 10, 21 (2010).

Z. Huang and X. Du, Huanjing Huaxue, 7, 72 (1988); Chem Abstr.,109, 236563 (1988).

Y. Guiyou, X. Jiaoyun and W. Yan, Yijin Fenxi, 19, 37 (1989).

Z. Zhengaqi and Z.S. Zong, Fenxi Shiyanshi, 11, 21 (1976).

J. Biernat and A. Syzmaszek, Bull. Acad Pol. Sci., Ser. Sci. Chim., 24, 133 (1976).

B. Johansson and S. Wendsjo, J. Electroanal. Chem. Interfacial Electrochem., 167, 165 (1984).

S. Lei, Fenxi Shiyanshi, 7, 32 (1988).

Z. Zhao and Y. Wang, Huaxue Xuebao, 41, 761 (1983).

R. Palaniappan and V. Revathi, J. Indian Coun. Chem, 4, 1 (1988).

K. Saraswathi and N.V.S. Naidu, Chem. Environ. Res., 8, 271 (1999).

K. Saraswathi, N.V.S. Naidu, K.P. Naidu and N. Krishnaiah, Anal. Chem.: An Indian J., 7, 279 (2008).

S. Wang, L. Du, A. Zhang and D. Liu, Anal. Lett., 31, 1757 (1998).

S. Kanchi, P. Krishnamurthy, K. Saraswathi and N.V. Naidu, Chem. Technol.: An Indian J., 6, 6 (2011).

S. Kanchi, T. Niranjan, K. Saraswathi and N.V. Naidu, Anal. Chem: An Indian J., 10, 231 (2011).

S. Kanchi, M. Sulochana, K.B. Naidu, K. Saraswathi and N.V. Naidu, Food Anal. Methods, 4, 453 (2011).

S. Kanchi, P. Singh, M.I. Sabela, K. Bisetty and N.V. Naidu, Int. J. Electrochem. Sci., 8, 4260 (2013).

S. Kanchi, P. Anuradha, B.N. Kumar, K. Gopalakrishnam and P. Ravi, Arabian J. Chem., (2012); doi:10.1016/j.arabjc.2012.08.001.

S. Kanchi, P. Singh and K. Bisetty, Arab. J. Chem., 7, 11 (2014).

S. Kanchi, M.I. Sabela, P. Singh and K. Bisetty, Arabian J. Chem., (2013); doi:10.1016/i.arabjc.2013.07.061.

T. Niranjan, S. Kanchi, K. Bisetty and N.V. Naidu, Asian J. Chem., 27, 3598 (2015).

Issue

Vol. 29 No. 3 (2017): Vol 29 Issue 3

Studies on Electrochemical Behaviour of Copper(II)-Dithiocarbamate Complexes at DME: Applications to Environmental and Biological Samples

Corresponding Author(s) : Venkatasubba Naidu Nuthalapati

Abstract

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