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Vol. 29 No. 3 (2017): Vol 29 Issue 3

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Synthesis, Structure and Swelling Properties of Hydrogels Based on Polyacrylic Acid

https://doi.org/10.14233/ajchem.2017.20262
S.M. Mammadova
Department of Nanostructured Metal-Polymer Catalysts, Institute of Catalysis and Inorganic Chemistry named after Academic M. Nagiyev, Azerbaijan National Academy of Sciences, Baku AZ1143, H. Javid ave 113, Azerbaijan
Sh. Z. Tapdigov
Department of Nanostructured Metal-Polymer Catalysts, Institute of Catalysis and Inorganic Chemistry named after Academic M. Nagiyev, Azerbaijan National Academy of Sciences, Baku AZ1143, H. Javid ave 113, Azerbaijan
S.F. Humbatova
Department of Nanostructured Metal-Polymer Catalysts, Institute of Catalysis and Inorganic Chemistry named after Academic M. Nagiyev, Azerbaijan National Academy of Sciences, Baku AZ1143, H. Javid ave 113, Azerbaijan
S.A. Aliyeva
Department of Nanostructured Metal-Polymer Catalysts, Institute of Catalysis and Inorganic Chemistry named after Academic M. Nagiyev, Azerbaijan National Academy of Sciences, Baku AZ1143, H. Javid ave 113, Azerbaijan
N.A. Zeynalov
Department of Nanostructured Metal-Polymer Catalysts, Institute of Catalysis and Inorganic Chemistry named after Academic M. Nagiyev, Azerbaijan National Academy of Sciences, Baku AZ1143, H. Javid ave 113, Azerbaijan
Ch. A. Soltanov
Department of Nanostructured Metal-Polymer Catalysts, Institute of Catalysis and Inorganic Chemistry named after Academic M. Nagiyev, Azerbaijan National Academy of Sciences, Baku AZ1143, H. Javid ave 113, Azerbaijan
A.A. Cavadzadeh
Department of Nanostructured Metal-Polymer Catalysts, Institute of Catalysis and Inorganic Chemistry named after Academic M. Nagiyev, Azerbaijan National Academy of Sciences, Baku AZ1143, H. Javid ave 113, Azerbaijan

Corresponding Author(s) : S.M. Mammadova

samira_m@mail.ru

Asian Journal of Chemistry, Vol. 29 No. 3 (2017): Vol 29 Issue 3

Abstract

In polar environment, net shaped polymers with ability of high swelling rate have been synthesized from crosslinking of 5, 10, 15 and 20 % ratio (by weight) of polyacrylic acid having an average molecular weight of 230 kDa with N,N-methylene-bis-acrylamide by using ultraviolet ray. The structure of gel has been studied and explained mechanism of the crosslinking process using infrared spectrometer, scanning electron microscopy and X-ray phase analysis methods. The swelling rate of crosslinked polymer, in polar, non-polar, acidic, neutral and alkali environments, as well as in different concentrations of sugar and physiological (0.9 % NaCl) solutions were also studied. It was determined that obtained polymer hydrogel, in the presence of 10 % (by weight) crosslink reagent in pH = 9-10, has maximum 680 % swelling rate within 4-5 days.

Keywords

Polyacrylic acid Methylen-bis-acrylamide Cross-linking Hydrogel Swelling rate
Mammadova, S., Tapdigov, S. Z., Humbatova, S., Aliyeva, S., Zeynalov, N., Soltanov, C. A., & Cavadzadeh, A. (2016). Synthesis, Structure and Swelling Properties of Hydrogels Based on Polyacrylic Acid. Asian Journal of Chemistry, 29(3), 576–580. https://doi.org/10.14233/ajchem.2017.20262
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