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Vol. 33 No. 9 (2021): Vol 33 Issue 9, 2021

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Corrosion Inhibition of Mild Steel in 0.5 M H2SO4 Solution by Plant Extract of Annona squamosa

https://doi.org/10.14233/ajchem.2021.23386
S. Karthikeyan
Department of Chemistry, Jamal Mohamed College (Autonomous), (Affiliated to Bharathidasan University), Tiruchirappalli-620020, India
S.S. Syed Abuthahir
Department of Chemistry, Jamal Mohamed College (Autonomous), (Affiliated to Bharathidasan University), Tiruchirappalli-620020, India
A. Samsath Begum
Department of Chemistry, Jamal Mohamed College (Autonomous), (Affiliated to Bharathidasan University), Tiruchirappalli-620020, India
K. Vijaya
Department of Chemistry, PSNA College of Engineering and Technology (Affiliated to Anna University, Chennai), Dindigul-624622, India

Corresponding Author(s) : S.S. Syed Abuthahir

syedchem05@gmail.com

Asian Journal of Chemistry, Vol. 33 No. 9 (2021): Vol 33 Issue 9, 2021

Abstract

In aqueous solution of 0.5 M H2SO4, the Annona squamosa extract was systematically analyzed to ensure its inhibition mechanism by using potentiodynamics polarization, the weight loss method, and electrochemical impedance spectroscopy (EIS) and its inhibitory effect on mild steel corrosion. For mild steel corrosion in 0.5 M H2SO4 solution, its inhibition efficiency increases and decreases with an increase in its concentration and temperature, respectively. Potentiodynamic polarization analyses revealed that the Annona squamosa behaves as a cathodic inhibitor. In presence of Annona squamosa extract in 0.5 M H2SO4 solution, an increase in the activation energy of corrosion leads to a decrease in the rate of mild steel corrosion. On mild steel surfaces, the adsorption behaviour of the extract conformed to the Temkin isotherm, Langmuir isotherm and Arrhenius equation. The EIS results were correlated with the polarization findings. According to atomic force microscopy (AFM) and scanning electron microscopy (SEM), the inhibition of mild steel corrosion proceeds through the adsorption of the extract on the mild steel surface.

Keywords

Annona squamosa Acid corrosion Acid inhibition
Karthikeyan, S., Syed Abuthahir, S., Samsath Begum, A., & Vijaya, K. (2021). Corrosion Inhibition of Mild Steel in 0.5 M H2SO4 Solution by Plant Extract of Annona squamosa. Asian Journal of Chemistry, 33(9), 2219–2228. https://doi.org/10.14233/ajchem.2021.23386
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References
  1. M. Finšgar and J. Jackson, Corros. Sci., 86, 17 (2014); https://doi.org/10.1016/j.corsci.2014.04.044
  2. I.A. Kartsonakis and C.A. Charitidis, Appl. Sci., 10, 6594 (2020); https://doi.org/10.3390/app10186594
  3. M. Faisal, A. Saeed, D. Shahzad, N. Abbas, F.A. Larik, P.A. Channar, T.A. Fattah, D.M. Khan and S.A. Shehzadi, Corros. Rev., 36, 507 (2018); https://doi.org/10.1515/corrrev-2018-0006
  4. C.I.C. Pinheiro, J.L. Fernandes, L. Domingues, A.J.S. Chambel, I. Graça, N.M.C. Oliveira, H.S. Cerqueira and F.R. Ribeiro, Ind. Eng. Chem. Res., 51, 1 (2012); https://doi.org/10.1021/ie200743c
  5. K. Rose, B.S. Kim, K. Rajagopal, S. Arumugam and K. Devarayan, J. Mol. Liq., 214, 111 (2016); https://doi.org/10.1016/j.molliq.2015.12.008
  6. O. Olawale, B.T. Ogunsemi, J.O. Bello, P.P. Ikubanni, S.J. Ogundipe and T.S. Abayomi, Int. J. Mech Eng. Technol., 9, 1274 (2018).
  7. A. Khadraoui, A. Khelifa, K. Hachama and R. Mehdaoui, J. Mol. Liq., 214, 293 (2016); https://doi.org/10.1016/j.molliq.2015.12.064
  8. N. Gunavathy and S.C. Murugavel, J. Environ. Nanotechnol., 2, 45 (2013); https://doi.org/10.13074/jent.2013.12.132049
  9. A. El Bribri, M. Tabyaoui, B. Tabyaoui, H. El Attari and F. Bentiss, Mater. Chem. Phys., 141, 240 (2013); https://doi.org/10.1016/j.matchemphys.2013.05.006
  10. P. Mourya, S. Banerjee and M.M. Singh, Corros. Sci., 85, 352 (2014); https://doi.org/10.1016/j.corsci.2014.04.036
  11. L. Li, X. Zhang, J. Lei, J. He, S. Zhang and F. Pan, Corros. Sci., 63, 82 (2012); https://doi.org/10.1016/j.corsci.2012.05.026
  12. A. Rajendran, Int. J. Pharm. Tech. Res., 3, 1005 (2011).
  13. O. Olawale, B.T. Ogunsemi, O.O. Agboola, M.B. Ake and G.O. Jawando, Int. J. Mech. Eng. Technol., 9, 282 (2018).
  14. A.Y. El-Etre, Mater. Chem. Phys., 108, 278 (2008); https://doi.org/10.1016/j.matchemphys.2007.09.037
  15. M. Prabakaran, S.H. Kim, K. Kalaiselvi, V. Hemapriya and I.M. Chung, J. Taiwan Inst. Chem. Eng., 59, 553 (2016); https://doi.org/10.1016/j.jtice.2015.08.023
  16. E. Alibakhshi, M. Ramezanzadeh, G. Bahlakeh, B. Ramezanzadeh, M. Mahdavian and M. Motamedi, J. Mol. Liq., 255, 185 (2018); https://doi.org/10.1016/j.molliq.2018.01.144
  17. A. Dehghani, G. Bahlakeh, B. Ramezanzadeh and M. Ramezanzadeh, Constr. Build. Mater., 245, 118464 (2020); https://doi.org/10.1016/j.conbuildmat.2020.118464
  18. M. Keramatinia, B. Ramezanzadeh and M. Mahdavian, J. Taiwan Inst. Chem. Eng., 105, 134 (2019); https://doi.org/10.1016/j.jtice.2019.10.005
  19. M.T. Majd, S. Akbarzadeh, M. Ramezanzadeh, G. Bahlakeh and B. Ramezanzadeh, J. Mol. Liq., 297, 111862 (2020); https://doi.org/10.1016/j.molliq.2019.111862
  20. A. Dehghani, G. Bahlakeh, B. Ramezanzadeh and M. Ramezanzadeh, J. Mol. Liq., 299, 112220 (2020); https://doi.org/10.1016/j.molliq.2019.112220
  21. G. Bahlakeh, A. Dehghani, B. Ramezanzadeh and M. Ramezanzadeh, J. Mol. Liq., 293, 111559 (2019); https://doi.org/10.1016/j.molliq.2019.111559
  22. A. Dehghani, G. Bahlakeh and B. Ramezanzadeh, Bioelectrochem., 130, 107339 (2019); https://doi.org/10.1016/j.bioelechem.2019.107339
  23. R. Anita and M. Chander, Int. J. Pharmacog. Phytochem., 9, 119 (2017).
  24. T.S. Mohamed Saleem and V. Hema Basnett, Nat. Prod. An Indian J., 5, 85 (2009).
  25. K.S. Shanker, S. Kanjilal, B.V. Rao, K.H. Kishore, S. Misra and R.B.N. Prasad, Phytochem. Anal., 18, 7 (2007); https://doi.org/10.1002/pca.942
  26. Z. Begum, I. Younus and S.M. Ali, World J. Pharm. Pharm. Sci., 4, 116 (2015).
  27. S. Gunavathy and S. Murugavel, E-J. Chem., 9, 487 (2012); https://doi.org/10.1155/2012/952402
  28. M.A. El-Hashemy and A. Sallam, J. Mater. Res. Technol., 9, 13509 (2020); https://doi.org/10.1016/j.jmrt.2020.09.078
  29. P. Roy, T. Maji, S. Dey and D. Sukul, RSC Adv., 5, 61170 (2015); https://doi.org/10.1039/C5RA12266J
  30. S. Manimegalai and P. Manjula, J. Mater. Environ. Sci., 6, 1629 (2015).
  31. M. Al-Hashemy and A. Sallam, J. Mater. Environ. Sci., 10, 840 (2019).
  32. A.S. Yaro, R.K. Wael and A.A. Khadom, J. Univ. Chem. Technol. Metallur., 45, 443 (2010).
  33. S.S. Syed Abuthahir A.J. Abdul Nasser and S. Rajendran, Open Mater. Sci. J., 8, 71 (2014); https://doi.org/10.2174/1874088X01408010071
  34. V.R. Nazeera Banu, S. Rajendran and S.S. Syed Abuthahir, Int. J. Chem. Concepts, 3, 161 (2017).
  35. K.K. Kumar, S.K. Selvaraj, M. Pandeeswaran, S.S. Syed Abuthahir and A. John Amalraj, Int. J. Adv. Chem. Sci. Appl., 3, 54 (2015).
  36. F. Zucchi and I.H. Omar, Surf. Technol., 24, 391 (1985); https://doi.org/10.1016/0376-4583(85)90057-3
  37. M.P. Chakravarthy and K.N. Mohana, ISRN Corrosion, 2014, 687276 (2014); https://doi.org/10.1155/2014/687276
  38. R.J. Tuama, M.E. Al-Dokheily and M.N. Khalaf, Int. J. Corros. Scale Inhib., 9, 427 (2020); https://doi.org/10.17675/2305-6894-2020-9-2-3
  39. P.A. Jeeva, G.S. Mali, R. Dinakaran, K. Mohanam and S. Karthikeyan, Int. J. Corros. Scale Inhib., 8, 1 (2019); https://doi.org/10.17675/2305-6894-2019-8-1-1
  40. P. Shanthy, J.A. Thangakani, S. Karthika, S.C. Joycee, S. Rajendran and J. Jeyasundari, Int. J. Corros. Scale Inhib., 10, 331 (2021); https://doi.org/10.17675/2305-6894-2021-10-1-19
  41. M. Barrahi, H. Elhartiti, A. El Mostaphi, N. Chahboun, M. Saadouni, R. Salghi, A. Zarrouk and M. Ouhssine, Int. J. Corros. Scale Inhib., 8, 937 (2019); https://doi.org/10.17675/2305-6894-2019-8-4-9
  42. P. Mahalakshmi, S. Rajendran, G. Nandhini, S.C. Joycee, N. Vijaya, T. Umasankareswari and N. Renuga Devi, Int. J. Corros. Scale Inhib., 9, 706 (2020); https://doi.org/10.17675/2305-6894-2020-9-2-20
  43. W.M.K.W.M. Ikhmal, M.Y.N. Yasmin, M.F.F. Maria1, S.M. Syaizwadi, W.A.W. Rafizah, M.G.M. Sabri and B.M. Zahid, Int. J. Corros. Scale Inhib., 9, 118 (2020); https://doi.org/10.17675/2305-6894-2020-9-1-7
  44. A. Grace Baby, S. Rajendran, V. Johnsirani, A. Al-Hashem, N. Karthiga and P. Nivetha, Int. J. Corros. Scale Inhib., 9, 979 (2020); https://doi.org/10.17675/2305-6894-2020-9-3-12
  45. S. Rajendran, R. Srinivasan, R. Dorothy, T. Umasankareswari and A. Al-Hashem, Int. J. Corros. Scale Inhib., 8, 437 (2019); https://doi.org/10.17675/2305-6894-2019-8-3-1
  46. A. Peter and S.K. Sharma, Int. J. Corros. Scale Inhib., 6, 112 (2017); https://doi.org/10.17675/2305-6894-2017-6-2-2
  47. A. Dehghani, G. Bahlakeh, B. Ramezanzadeh and M. Ramezanzadeh, Constr. Build. Mater., 245, 118464 (2020); https://doi.org/10.1016/j.conbuildmat.2020.118464
  48. N. Kicir, G. Tansug, M. Erbil and T. Tüken, Corros. Sci., 105, 88 (2016); https://doi.org/10.1016/j.corsci.2016.01.006
  49. C. Verma, E.E. Ebenso, I. Bahadur and M.A. Quraishi, J. Mol. Liq., 266, 577 (2018); https://doi.org/10.1016/j.molliq.2018.06.110
  50. Y. Zhu, L. Wang, Y. Behnamian, S. Song, R. Wang, Z. Gao, W. Hu and D.H. Xia, Corros. Sci., 170, 108685 (2020); https://doi.org/10.1016/j.corsci.2020.108685
  51. K. Muthamma, P. Kumari, M. Lavanya and S.A. Rao, J. Bio. Tribo. Corros., 7, 10 (2021); https://doi.org/10.1007/s40735-020-00439-7
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