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Vol. 33 No. 11 (2021): Vol 33 Issue 11, 2021

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Metal Complexes of Schiff Bases of 3-Hydroxyquinoxaline-2-carboxaldehyde Encapsulated in Zeolite Y Cages: Potential Catalyst for Removing Phenol from Effluent Media

https://doi.org/10.14233/ajchem.2021.23387
N.R. Suja
Post Graduate and Research Department of Chemistry, Maharaja’s College, Ernakulam, Kochi-682011, India
T.K. Bindu Sharmila
Post Graduate and Research Department of Chemistry, Maharaja’s College, Ernakulam, Kochi-682011, India
S.R. Amrutha
Post Graduate and Research Department of Chemistry, Maharaja’s College, Ernakulam, Kochi-682011, India

Corresponding Author(s) : N.R. Suja

drsuja@maharajas.ac.in

Asian Journal of Chemistry, Vol. 33 No. 11 (2021): Vol 33 Issue 11, 2021

Abstract

Transition metal complexes are known to be efficient catalyst for many organic transformations. Encapsulation of metal complexes in zeolite cage brings many significant modifications in the structure of the metal complexes, which are very interesting from the catalytic point of view. This study aims in a comparative evaluation of the influence of structure of neat and encapsulated complexes in their catalytic activity. Phenol is one of the major industrial pollutants. Heterogenizing transition metal Schiff bases by encapsulation inside the zeolite would help to minimize the reuse problem of transition metal complexes. This article deals with the synthesis, characterization and catalytic activity studies of Co(II), Ni(II) and Cu(II) complexes of 3-hydroxyquinoxaline-2-carboxaldehyde with ethylenediamine (L1) and an o-phenylene diamine (L2).

Keywords

3-Hydroxyquinoxaline-2-carboxaldehyde Schiff bases Zeolite encapsulation Catalysis Phenol hydroxylation.
Suja, N., Bindu Sharmila, T., & Amrutha, S. (2021). Metal Complexes of Schiff Bases of 3-Hydroxyquinoxaline-2-carboxaldehyde Encapsulated in Zeolite Y Cages: Potential Catalyst for Removing Phenol from Effluent Media. Asian Journal of Chemistry, 33(11), 2746–2754. https://doi.org/10.14233/ajchem.2021.23387
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References
  1. R.A Sheldon, Green Chem., 7, 267 (2005); https://doi.org/10.1039/B418069K
  2. M.E. Ali, M.M. Rahman, S.M. Sarkar and S.B.A. Hamid, J. Nanometer., 2014, 192038 (2014); https://doi.org/10.1155/2014/192038
  3. B. Dutta, S. Jana, R. Bera, P.K. Saha and S. Koner, Appl. Catal. A, 318, 89 (2007); https://doi.org/10.1016/j.apcata.2006.10.041
  4. A.H. Ahmed, Rev. Inorg. Chem., 34, 153 (2014); https://doi.org/10.1515/revic-2013-0013
  5. D.R. Godhani, H.D. Nakum, D.K. Parmar, J.P. Mehta and N.C. Desai, Inorg. Chem. Commun., 72, 105 (2016); https://doi.org/10.1016/j.inoche.2016.08.017
  6. N. Kosinov, C. Liu, E.J.M. Hensen and E.A. Pidko, Chem. Mater., 30, 3177 (2018); https://doi.org/10.1021/acs.chemmater.8b01311
  7. C.K. Modi, P.M. Trivedi, J.A. Chudasama, H.D. Nakum, D.K. Parmar, S.K. Gupta and P.K. Jha, Green Chem. Lett. Rev., 7, 278 (2014); https://doi.org/10.1080/17518253.2014.946101
  8. Y. Li, L. Li and J. Yu, Chem, 3, 928 (2017); https://doi.org/10.1016/j.chempr.2017.10.009
  9. D. Xu, H. Lv and B. Liu, Front. Chem., 6, 550 (2018); https://doi.org/10.3389/fchem.2018.00550
  10. I.Kuzniarska-Biernacka, K. Biernacki, A.L. Magalhães, A.M. Fonseca,
  11. and I.C. Neves, J. Catal., 278, 102 (2011); https://doi.org/10.1016/j.jcat.2010.11.022
  12. A. Corma and H. Garcia, Eur. J. Inorg. Chem., 1143 (2004); https://doi.org/10.1002/ejic.200300831
  13. J.M. Thomas and R. Raja, Stud. Surf. Sci. Catal., 148, 163 (2004); https://doi.org/10.1016/S0167-2991(04)80198-8
  14. B. Meier, T. Werner, I. Klimant and O.S. Wolfbeis, Sens. Actuators B Chem., 29, 240 (1995); https://doi.org/10.1016/0925-4005(95)01689-9
  15. M.M. Heravi, B. Heidari, V. Zadsirjan and L. Mohammadi, RSC Adv., 10, 24893 (2020); https://doi.org/10.1039/D0RA02341H
  16. F. Bedioui, Coord. Chem. Rev., 144, 39 (1995); https://doi.org/10.1016/0010-8545(94)08000-H
  17. K.J. Balkus Jr. and A.G. Gabrielov, J. Incl. Phenom. Macrocycl. Chem., 21, 159 (1995); https://doi.org/10.1007/BF00709415
  18. C. Dai, K. Du, C. Song and X. Guo, Adv. Catal., 67, 91 (2020); https://doi.org/10.1016/bs.acat.2020.10.001
  19. Z. Khodadadi and R. Mahmoudian, React. Kinet. Mech. Catal., 119, 685 (2016); https://doi.org/10.1007/s11144-016-1072-z
  20. R.J. Taylor, R.S. Drago and J.E. George, J. Am. Chem. Soc., 111, 6610 (1989); https://doi.org/10.1021/ja00199a020
  21. S. Deshpande, D. Srinivas and P. Ratnasamy, J. Catal., 188, 261 (1999); https://doi.org/10.1006/jcat.1999.2662
  22. K.K. Bania and R.C. Deka, J. Phys. Chem. C, 115, 9601 (2011); https://doi.org/10.1021/jp2003672
  23. H.B. Li, C. Qin, W.B. Yang, X.P. Hu and S.Y. Qin, Chin. Chem. Lett., 18, 103 (2007); https://doi.org/10.1016/j.cclet.2006.11.011
  24. A.A.A. Emara, A.M. Ali, A.F. El-Asmy and E.-S.M. Ragab, J. Saudi Chem. Soc., 18, 762 (2014); https://doi.org/10.1016/j.jscs.2011.08.002
  25. N. Herron, Inorg. Chem., 25, 4714 (1986); https://doi.org/10.1021/ic00246a025
  26. F. Bedioui, L. Roue, J. Devynck and K.J. Balkus Jr., Stud. Surf. Sci. Catal., 84, 917 (1994); https://doi.org/10.1016/S0167-2991(08)63624-1
  27. K.J. Balkus Jr., A.A. Welch and B.E. Gnade, Zeolites, 10, 722 (1990); https://doi.org/10.1016/0144-2449(90)90053-T
  28. C.J. Dhanaraj, J. Johnson, J. Joseph and R.S. Joseyphus, J. Coord. Chem., 66, 1416 (2013); https://doi.org/10.1080/00958972.2013.782008
  29. J. Mathew, Ph.D. Thesis, Cochin University of Science and Technology, Cochin, India (1995).
  30. C. Naccache and B.T.Z. Younès, Science and Technology, Springer (1984).
  31. L. Wu and A. Navrotsky, Phys. Chem. Chem. Phys., 18, 10116 (2016); https://doi.org/10.1039/C5CP07918G
  32. C.R Jacob., S.P. Varkey and P. Ratnasamy, Appl. Catal. A, 168, 353 (1998); https://doi.org/10.1016/S0926-860X(97)00365-7
  33. J. Poltowicz, K. Pamin, E. Tabor, J. Haber, A. Adamski and Z. Sojka, Appl. Catal. A, 299, 235 (2006); https://doi.org/10.1016/j.apcata.2005.10.034.
  34. R. Abraham, Ph.D. Thesis, Cochin University of Science and Technology, Cochin, India (1999).
  35. K. Mori, K. Kagohara and H. Yamashita, J. Phys. Chem. C, 112, 2593 (2008); https://doi.org/10.1021/jp709571v
  36. C.N. Satterfield, Heterogeneous Catalysis in Industrial Practice, McGraw-Hill, Singapore Ed. 2 (1993).
  37. P. Gallezot, Y. Ben Taarit and B. Imelik, J. Catal., 26, 295 (1972); https://doi.org/10.1016/0021-9517(72)90087-5
  38. D. Simpson and H. Steinfink, J. Am. Chem. Soc., 91, 6225 (1969); https://doi.org/10.1021/ja01051a003
  39. S.P. Varkey, C. Ratnasamy and P. Ratnasamy, J. Mol. Catal. Chem., 135, 295 (1998); https://doi.org/10.1016/S1381-1169(97)00307-5
  40. A.H. Kianfar, L. Keramat, M. Dostani, M. Shamsipur, M. Roushani and F. Nikpour, Spectrochim. Acta A Mol. Spectrosc., 77, 424 (2010); https://doi.org/10.1016/j.saa.2010.06.008
  41. V. Arun, S. Mathew, P.P. Robinson, M. Jose, V.P.N. Nampoori and K.K.M. Yusuff, Dyes Pigments, 87, 149 (2010); https://doi.org/10.1016/j.dyepig.2009.01.010
  42. S. Chavan, D. Srinivas, P. Ratnasamy, J. Catal., 192, 286 (2000); https://doi.org/10.1006/jcat.2000.2851
  43. S.P. Varkey and C.R. Jacob, Indian J. Chem., 38A, 320 (1999).
  44. U. Sakaguchi and A.W. Addison, J. Chem. Soc., Dalton Trans., 4, 600 (1979); https://doi.org/10.1039/dt9790000600
  45. M.R. Maurya, A.K. Chandrakar and S. Chand, J. Mol. Catal. Chem., 274, 192 (2007); https://doi.org/10.1016/j.molcata.2007.05.018
  46. M. Goodgame, D.M.L. Goodgame and F.A. Cotton, J. Am. Chem. Soc., 83, 4161 (1961); https://doi.org/10.1021/ja01481a014
  47. T. Hatakeyama and Z. Liu, Handbook of Thermal Analysis, John Wiley and Sons: New York (1998).
  48. M.R. Maurya, H. Saklani, A. Kumar and S. Chand, Catal. Lett., 93, 121 (2004); https://doi.org/10.1023/B:CATL.0000016959.93948.d7
  49. K.K. Bania and R.C. Deka, J. Phys. Chem. C, 117, 11663 (2013); https://doi.org/10.1021/jp402439x
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