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Vol. 33 No. 11 (2021): Vol 33 Issue 11, 2021

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Synergetic Effects of Temperature and Perpendicular Magnetic Field on Zn-Ni Alloy Electrodepositing Process

https://doi.org/10.14233/ajchem.2021.23398
N. Benachour
Department of Chemistry, Faculty of Science, University of 20th August 1955, Skikda, Algeria ; Department of Chemistry, Faculty of Science, University of Badji Mokhtar, Annaba, Algeria
S. Chouchane
Department of Chemistry, Faculty of Science, University of Badji Mokhtar, Annaba, Algeria
J.P. Chopart
Laboratoire Ingénierie et Sciences des Matériaux, LISM EA 4695, 21 rue Clément ADER, 51685 REIMS Cedex 2, France

Corresponding Author(s) : N. Benachour

naimabenachour2018@gmail.com

Asian Journal of Chemistry, Vol. 33 No. 11 (2021): Vol 33 Issue 11, 2021

Abstract

The zinc-nickel alloys were electrodeposited on stainless steel substrates during a chloride acid bath. The electroplating processes were investigated under a moderate perpendicular magnetic flux at uncommon temperatures. The coatings obtained were characterized by scanning microscopy (SEM) including EDX and X-ray diffraction (XRD). Chronopotentiometric curves were additionally implemented for electrochemical analysis. Structural analysis revealed that the obtained alloys consisted of a mix of the homogeneous phase γ-Ni3Zn22 and α-Zn-Ni at 70 ºC. The alloys variations observed within the chemical composition, crystallographic phases and morphology of the alloys. It is often explained particularly, by the progressive hydrogen reaction and therefore the evolution of the adsorbed intermediate species. The synergetic effect was significant at 70 ºC within the 1T field, including the appearance of normal co-deposition.

Keywords

Zinc-nickel Electrodeposition Perpendicular magnetic field Temperature
Benachour, N., Chouchane, S., & Chopart, J. (2021). Synergetic Effects of Temperature and Perpendicular Magnetic Field on Zn-Ni Alloy Electrodepositing Process. Asian Journal of Chemistry, 33(11), 2839–2844. https://doi.org/10.14233/ajchem.2021.23398
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