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Vol. 29 No. 2 (2017): Vol 29 Issue 2

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Synthesis, Characterization and Radical Polymerization of Novel Furan Substituted Acrylamide

https://doi.org/10.14233/ajchem.2017.20283
Mustafa Tombul
Department of Chemistry, Faculty of Science & Letters, Kirikkale University, 71450 Yahsihan, Kirikkale, Turkey
Adnan Bulut
Department of Chemistry, Faculty of Science & Letters, Kirikkale University, 71450 Yahsihan, Kirikkale, Turkey
Halil Ünver
Department of Chemistry, Faculty of Science & Letters, Kirikkale University, 71450 Yahsihan, Kirikkale, Turkey

Corresponding Author(s) : Mustafa Tombul

mtombul@kku.edu.tr

Asian Journal of Chemistry, Vol. 29 No. 2 (2017): Vol 29 Issue 2

Abstract

N-[(Furan-2-yl)methyl]acrylamide (FMA) was synthesized via the reaction of furfurylamine with acryloyl chloride and the chemical structure was elucidated by 1H NMR, 13C NMR and FTIR analyses. Free radical polymerization of N-[(furan-2-yl)methyl]acrylamide was performed employing benzoyl peroxide (BPO) initiator under inert atmosphere of nitrogen in toluene. The monomer concentration and initiator concentration ranges were 8.8 × 10-2 to 13.2 × 10-2 mol L-1 and 3.4 × 10-3 to 20.7 × 10-3 mol L-1, respectively. The rate of polymerization (Rp) was found to be Rp = k[BPO]0.51[FMA]1.69. The overall activation energy of 84 kJ mol-1 was obtained in the temperature range 70-90 °C. The FTIR spectra of the prepared polymer indicate disappearance of the band at 1620 cm-1, which is basically due to the olefinic C=C stretching, confirming the polymerization of N-[(furan-2-yl)methyl]acrylamide.

Keywords

Radical polymerization Furan Arylamide
Tombul, M., Bulut, A., & Ünver, H. (2016). Synthesis, Characterization and Radical Polymerization of Novel Furan Substituted Acrylamide. Asian Journal of Chemistry, 29(2), 457–460. https://doi.org/10.14233/ajchem.2017.20283
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