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Development of Cypermethrin Pesticide Detection Method using Ultra Violet-Visible Spectrophotometry
Corresponding Author(s) : Mashuni
Asian Journal of Chemistry,
Vol. 29 No. 2 (2017): Vol 29 Issue 2
Abstract
Cypermethrin is a pesticide that is widely used in agriculture of residue accumulation, which may remain in food causing concern of human health. The aim of this study was to develop a method of quantitative analysis for cypermethrin which generally used by gas chromatography technique. In this study, cypermethrin analysis was developed with ultra violet-visible spectrophotometry. The method is based on hydrolysis of cypermethrin in alkaline solution to cyanide ion and reacts with iron(III) ions to form coloured complex compounds and the concentration of cypermethrin can be measured quantitatively with a spectrophotometer. Ferricyanide complex ions are formed by adding iron(III) chloride, then it is measured the absorption to determine of cypermethrin concentration. In this experiments, maximum wavelength absorption was obtained at 420 nm and the method has a working range of concentration from 0.076 to 1.60 ppm with r ³ 0.9998. Limits of detection and limits of quantitation are 0.023 and 0.076 ppm, respectively. Based on accuracy and precision analysis, this methods can be used accurately and have good precision with value of recovery tested is 101.10 % and RSD is 0.25 %.
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- P. Wexler, Encyclopedia of Toxicology, Elsevier Inc., San Diego, edn 3 (2014).
- R.L. Metcalf, Insect Control, Ullmann’s Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim (2000).
- R. Krieger, Hayes Handbook of Pesticide Toxicology, Elsevier Inc., San Diego, edn 3 (2010).
- K.R.I. Kementerian, Pedoman Penggunaan Insektisida (Pestisida) dalam Pengendalian Vektor, Winarno, Jakarta, Indonesia (2012).
- J. Orgoványi, K.H. Otta, L. Pöppl, E. Fenyvesi and G. Záray, Microchem. J., 79, 77 (2005).
- I. Narwanti, E. Sugiharto and C. Anwar, J. Ilmiah Kefarmasian, 2, 119 (2012).
- S. Zawiyah, Y.B. Che Man, S.A.H. Nazimah, C.K. Chin, I. Tsukamoto, A.H. Hamanyza and I. Norhaizan, Food Chem., 102, 98 (2007).
- M.S. Khan, M.M. Shah, Q. Mahmood, A. Hassan and K. Akbar, J. Chem. Soc. Pak., 33, 816 (2011).
- A.M.Z. Chowdhury, S. Bhattacharjee, A.N.M. Fakhruddin, M.N. Islam and M.K. Alam, World J. Agric. Res., 1, 30 (2013).
- J.-J. Zhang, L.G. Zang, J.E. Zhang, G.W. Cui, B. Tang, X.Y. Li and L. Zhou, Bull. Chem. Soc. Ethiop., 23, 97 (2009).
- G. Efiyatni, U. Loekman and Yefrida, J. Kimia Unand, 2, 128 (2013).
- S. Armenta, G. Quintás, S. Garrigues and M. de la Guardia, Talanta, 67, 634 (2005).
- Mashuni, L.O.A.N. Ramadhan, M. Jahiding and Herniati, Mater. Sci. Eng., 107, 012013 (2016).
- E.K. Janghel, J.K. Rai, M.K. Rai and V.K. Gupta, J. Braz. Chem. Soc., 18, 590 (2007).
- P.K. Sharma and S.K. Rajput, J. Appl. Chem., 1, 490 (2012).
- G.H. Jeffery, J. Basset, J. Mendham and R.C. Denney, Vogels Textbook of Quantitative Chemical Analysis, Longman Scientific & Technical, London, edn 5 (1989).
- T.H. Huang, G. Salter, S.L. Kahn and Y.M. Gindt, J. Chem. Educ., 84, 1461 (2007).
- D. Harvey, Modern Analytical Chemistry, The McGraw-Hill Companies, United States (2000).
- J.N. Miller and J.C. Miller, Statistics and Chemometrics for Analytical Chemistry, Ellis HorwoodPTR Prentice Hall, England, edn 5 (2005).
- G.D. Christian, Analytical Chemistry, John Wiley & Sons, United States, edn 5 (2004).
References
P. Wexler, Encyclopedia of Toxicology, Elsevier Inc., San Diego, edn 3 (2014).
R.L. Metcalf, Insect Control, Ullmann’s Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim (2000).
R. Krieger, Hayes Handbook of Pesticide Toxicology, Elsevier Inc., San Diego, edn 3 (2010).
K.R.I. Kementerian, Pedoman Penggunaan Insektisida (Pestisida) dalam Pengendalian Vektor, Winarno, Jakarta, Indonesia (2012).
J. Orgoványi, K.H. Otta, L. Pöppl, E. Fenyvesi and G. Záray, Microchem. J., 79, 77 (2005).
I. Narwanti, E. Sugiharto and C. Anwar, J. Ilmiah Kefarmasian, 2, 119 (2012).
S. Zawiyah, Y.B. Che Man, S.A.H. Nazimah, C.K. Chin, I. Tsukamoto, A.H. Hamanyza and I. Norhaizan, Food Chem., 102, 98 (2007).
M.S. Khan, M.M. Shah, Q. Mahmood, A. Hassan and K. Akbar, J. Chem. Soc. Pak., 33, 816 (2011).
A.M.Z. Chowdhury, S. Bhattacharjee, A.N.M. Fakhruddin, M.N. Islam and M.K. Alam, World J. Agric. Res., 1, 30 (2013).
J.-J. Zhang, L.G. Zang, J.E. Zhang, G.W. Cui, B. Tang, X.Y. Li and L. Zhou, Bull. Chem. Soc. Ethiop., 23, 97 (2009).
G. Efiyatni, U. Loekman and Yefrida, J. Kimia Unand, 2, 128 (2013).
S. Armenta, G. Quintás, S. Garrigues and M. de la Guardia, Talanta, 67, 634 (2005).
Mashuni, L.O.A.N. Ramadhan, M. Jahiding and Herniati, Mater. Sci. Eng., 107, 012013 (2016).
E.K. Janghel, J.K. Rai, M.K. Rai and V.K. Gupta, J. Braz. Chem. Soc., 18, 590 (2007).
P.K. Sharma and S.K. Rajput, J. Appl. Chem., 1, 490 (2012).
G.H. Jeffery, J. Basset, J. Mendham and R.C. Denney, Vogels Textbook of Quantitative Chemical Analysis, Longman Scientific & Technical, London, edn 5 (1989).
T.H. Huang, G. Salter, S.L. Kahn and Y.M. Gindt, J. Chem. Educ., 84, 1461 (2007).
D. Harvey, Modern Analytical Chemistry, The McGraw-Hill Companies, United States (2000).
J.N. Miller and J.C. Miller, Statistics and Chemometrics for Analytical Chemistry, Ellis HorwoodPTR Prentice Hall, England, edn 5 (2005).
G.D. Christian, Analytical Chemistry, John Wiley & Sons, United States, edn 5 (2004).