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Vol. 29 No. 2 (2017): Vol 29 Issue 2

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Electrochemical Synthesis of Cadmium(II) Carboxylates Compounds at Sacrificial Cadmium Anode

https://doi.org/10.14233/ajchem.2017.20186
Kanchan Bala
Department of Chemistry, Punjabi University, Patiala-147 002, India
Baljit Singh
Department of Chemistry, Punjabi University, Patiala-147 002, India

Corresponding Author(s) : Baljit Singh

baljit_chemz@yahoo.co.in

Asian Journal of Chemistry, Vol. 29 No. 2 (2017): Vol 29 Issue 2

Abstract

Cadmium carboxylates and their coordination complexes are synthesized by using an electrochemical technique in the presence of different carboxylic acids (RCOOH) using cadmium and a platinum as the anode and cathode respectively and tetrabutyl ammonium chloride as a supporting electrolyte. The electrochemical oxidation of anodic cadmium in acetonitrile solution with different carboxylic acids or with 1,10-phenanthroline (phen) and 2,2’-bipyridyl (bipy) yield the complexes Cd(OOCR)2 and Cd(OOCR)2L (L = phen or bipy), respectively. The results from spectroscopic studies FTIR, elemental analysis and physical measurements confirm the existence of bonding between the carboxylate groups of different carboxylic acids with cadmium. Current efficiencies of all these synthesized compounds are also discussed.

Keywords

Sacrificial cadmium anode Electrochemical synthesis Cadmium(II) carboxylates Coordination complexes
Bala, K., & Singh, B. (2016). Electrochemical Synthesis of Cadmium(II) Carboxylates Compounds at Sacrificial Cadmium Anode. Asian Journal of Chemistry, 29(2), 336–340. https://doi.org/10.14233/ajchem.2017.20186
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