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Ion Selective Electrode-Copper(II) Based on EDTA as Ionophores in Poly(vinyl chloride) Matrix
Corresponding Author(s) : A.S. Panggabean
Asian Journal of Chemistry,
Vol. 29 No. 2 (2017): Vol 29 Issue 2
Abstract
A research on the preparation and characterization of ion selective electrode Cu(II) based poly(vinyl chloride) (PVC) by using ethylenediaminetetraacetate (EDTA) as ionophores has been done. The physical strength of the membrane can be improved with used poly(vinyl chloride) as matrix and dioctylphenylphosphonate (DOP) as plasticizer. The result showed that the optimum composition of the membrane with comparison was EDTA:PVC:DOP (60:30:10). The optimum dopant concentration of Cu2+ was 1 M with conductivity value was 4.62 × 10-2 Ohm-1 m-1. The electrode exhibited an excellent potentiometric response over a wide concentration range of 1.0 × 10-5 - 1.0 × 10-1 M with a Nernstian factor of 28.8 mV/decade, detection limit was 3.02 × 10-6 M. The sensor works well in the pH range 3-7, can be used for a period of 4 weeks and demonstrated good selectivity towards analyte in the presence of several ions.
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- X.-H. Zhao, Q.-J. Ma, X.-B. Zhang, B. Huang, Q. Jiang, J. Zhang, G.-L. Shen and R.-Q. Yu, Anal. Sci., 26, 585 (2010).
- Y. Zhou, F. Wang, Y. Kim, S.J. Kim and J. Yoon, Org. Lett., 11, 4442 (2009).
- H. Kozlowski, A. Janicka-Klos, J. Brasun, E. Gaggelli, D. Valensin and G. Valensin, Coord. Chem. Rev., 253, 2665 (2009).
- X.-L. Lv, Y. Wei and S.-Z. Luo, Anal. Sci., 28, 749 (2012).
- A.S. Panggabean and B. Yusuf, Int. J. Pharma Bio Sci., 6, 101 (2015).
- T.E. Edmonds, Chemical Sensors, Blackie and Sons, New York (1988).
- M.T. Florence, Proceedings of Electrochemistry-The Royal Australian Chemical Institute, pp. 261-269 (1971).
- P.L. Bailey, Analysis with Ion-Selective Electrodes, Heyden and Sons, New York (1976).
- P. Bühlmann, E. Pretsch and E. Bakker, Chem. Rev., 98, 1593 (1998).
- H. Hotta, T. Mori, A. Takahashi, Y. Kogure, K. Johno, T. Umemura and K. Tsunoda, Anal. Chem., 81, 6357 (2009).
- K. Minakata, I. Yamagishi, H. Nozawa, K. Gonmori, K. Hasegawa, M. Suzuki, F. Horio, K. Watanabe and O. Suzuki, Forensic Toxicol., 30, 149 (2012).
- V.K. Gupta, N.G. Rajendra and R.A. Sharma, Int. J. Electrochem. Sci., 4, 156 (2009).
- X. Yang, S. Johnson, J. Shi, T. Holesinger and B. Swanson, Sens. Actuators B, 45, 87 (1997).
- B. Correa-Lozano, C. Comninellis and A. de Battisti, J. Appl. Electrochem., 26, 83 (1996).
- M.R. Ganjali, A. Ghafarloo, F. Faridbod and P.N. Copper, Int. J. Electrochem. Sci., 7, 3706 (2012).
- Y.K. Albayati, K.H. Al-Saidi and M.A. Hussain, Asian J. Chem., 28, 1962 (2016).
- A. Evans, Potentiometry and Ion Selective Electrodes, John Wiley & Sons, Chichester (1987).
- P.W. Atkins, Physical Chemistry, Oxford Universty Press, Oxford, London (1980).
- W.E. Morf, The Principles of Ion-Selective Electrodes and of Membrane Transport, Elsevier Science Publication Co., Amsterdam (1991).
- L.H. Hidmi and M. Edwards, Environ. Sci. Technol., 33, 2607 (1999).
- H.A. Zamani, G. Rajabzadeh and M.R. Ganjali, Sens. Actuators B, 119, 41 (2006).
- V.K. Gupta, A.K. Jain and G. Maheshwari, Chem. Anal. (Warsaw), 51, 889 (2006).
References
X.-H. Zhao, Q.-J. Ma, X.-B. Zhang, B. Huang, Q. Jiang, J. Zhang, G.-L. Shen and R.-Q. Yu, Anal. Sci., 26, 585 (2010).
Y. Zhou, F. Wang, Y. Kim, S.J. Kim and J. Yoon, Org. Lett., 11, 4442 (2009).
H. Kozlowski, A. Janicka-Klos, J. Brasun, E. Gaggelli, D. Valensin and G. Valensin, Coord. Chem. Rev., 253, 2665 (2009).
X.-L. Lv, Y. Wei and S.-Z. Luo, Anal. Sci., 28, 749 (2012).
A.S. Panggabean and B. Yusuf, Int. J. Pharma Bio Sci., 6, 101 (2015).
T.E. Edmonds, Chemical Sensors, Blackie and Sons, New York (1988).
M.T. Florence, Proceedings of Electrochemistry-The Royal Australian Chemical Institute, pp. 261-269 (1971).
P.L. Bailey, Analysis with Ion-Selective Electrodes, Heyden and Sons, New York (1976).
P. Bühlmann, E. Pretsch and E. Bakker, Chem. Rev., 98, 1593 (1998).
H. Hotta, T. Mori, A. Takahashi, Y. Kogure, K. Johno, T. Umemura and K. Tsunoda, Anal. Chem., 81, 6357 (2009).
K. Minakata, I. Yamagishi, H. Nozawa, K. Gonmori, K. Hasegawa, M. Suzuki, F. Horio, K. Watanabe and O. Suzuki, Forensic Toxicol., 30, 149 (2012).
V.K. Gupta, N.G. Rajendra and R.A. Sharma, Int. J. Electrochem. Sci., 4, 156 (2009).
X. Yang, S. Johnson, J. Shi, T. Holesinger and B. Swanson, Sens. Actuators B, 45, 87 (1997).
B. Correa-Lozano, C. Comninellis and A. de Battisti, J. Appl. Electrochem., 26, 83 (1996).
M.R. Ganjali, A. Ghafarloo, F. Faridbod and P.N. Copper, Int. J. Electrochem. Sci., 7, 3706 (2012).
Y.K. Albayati, K.H. Al-Saidi and M.A. Hussain, Asian J. Chem., 28, 1962 (2016).
A. Evans, Potentiometry and Ion Selective Electrodes, John Wiley & Sons, Chichester (1987).
P.W. Atkins, Physical Chemistry, Oxford Universty Press, Oxford, London (1980).
W.E. Morf, The Principles of Ion-Selective Electrodes and of Membrane Transport, Elsevier Science Publication Co., Amsterdam (1991).
L.H. Hidmi and M. Edwards, Environ. Sci. Technol., 33, 2607 (1999).
H.A. Zamani, G. Rajabzadeh and M.R. Ganjali, Sens. Actuators B, 119, 41 (2006).
V.K. Gupta, A.K. Jain and G. Maheshwari, Chem. Anal. (Warsaw), 51, 889 (2006).