Copyright (c) 2013 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Polyaniline/Graphene-Based Electrochemical Biosensor for Sensitive Detection of Glucose
Corresponding Author(s) : Qinghui Jin
Asian Journal of Chemistry,
Vol. 25 No. 9 (2013): Vol 25 Issue 9
Abstract
A novel approach for glucose biosensor fabrication was described. It based on immobilization of glucose oxidase on polyaniline/graphene composite membrane modified glassy carbon electrode. Cyclic voltammetry demonstrated that modified electrodes owned good electrochemical activity, superior sensitivity and high stability. The good electrocatalytical activity toward H2O2 and O2 might be attributed to the synergistic effect of graphene and polyaniline. The results showed that the electrochemical biosensor had a wide linear response from 0.1 to 10 mM.
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References
R.C. Barry, Y. Lin, J. Wang, G. Liu and C.A. Timchalk, J. Expo. Sci. Environ. Epidemiol., 19, 1 (2009).
V. Velusamy, K. Arshak, O. Korostynska, K. Oliwa and C. Adley, Biotechnol. Adv., 28, 232 (2010).
T. Selvaraju, J. Dasa, S.W. Han and H. Yang, Biosens. Bioelectron., 23, 932 (2008).
D. Chung, K. Kim and S. Choi, Appl. Surf. Sci., 257, 9390 (2011).
B.J. Privett, J.H. Shin and M.H. Schoenfisch, Anal. Chem., 80, 4499 (2008).
N. Alexeyeva, J. Kozlova, V. Sammelselg, P. Ritslaid, H. Mändar and K. Tammeveski, Appl. Surf. Sci., 256, 3040 (2010).
A.K. Geim and K.S. Novoselov, Nat. Mater., 6, 183 (2007).
Z. Liu, Q. Liu, Y. Huang, Y. Ma, S. Yin, X. Zhang, W. Sun and Y. Chen, Adv. Mater., 20, 3924 (2008).
S. Guo and S. Dong, Chem. Soc. Rev., 40, 2644 (2011).
M. Zhou, Y. Zhai and S. Dong, Anal. Chem., 81, 5603 (2009).
Y. Shao, J. Wang and H. Wu, J. Liu, I.A. Aksay and Y. Lin, Electroanalysis, 22, 1027 (2010).
Y. Lin, K.A. Jenkins, A. Valdes-Garcia, J. P. Small, D.B. Farmer and Ph. Avouris, Nano Lett., 9, 422 (2009).
D. Wang, F. Li, J. Zhao, W. Ren, Z. Chen, J. Tan, Z. Wu, I. Gentle, G. Q. Lu and H. Cheng, ACS Nano, 3, 1745 (2009).
C.E. Banks, T.J. Davies, G.G. Wildgoose and R.G.. Compton, Chem. Commun., 7. 829 (2005).
Y. Wang, Y.M. Li, L.H. Tang, J. Lu and J.H. Li, Electrochem. Commun., 11, 889 ( 2009).
S. Alwarappan, A. Erdem, C. Liu and C.Z. Li, J. Phys. Chem. C, 113, 8853 (2009).
W.S. Hummers and R.E. Offeman, J. Am. Chem. Soc., 80, 1339 (1958).
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J.X. Huang and R.B. Kaner, J. Am. Chem. Soc., 126, 851 (2004).
A.F. Diaz, J.A. Logan, J. Electroanal. Chem., 111, 111 (1980).