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Transportation of Pollutants of the Danube River into the (Western) Black Sea
Corresponding Author(s) : A.E. Muftuoglu
Asian Journal of Chemistry,
Vol. 25 No. 9 (2013): Vol 25 Issue 9
Abstract
At 14 stations on the Western Black Sea shelf, water and sediment samples were collected from the water column and the sea-bed during August 2003 and June 2004. The metals content (Al, Fe, Mn, Pb, Cu, Zn, Ni, Cd, Cr and Hg) of these samples was investigated to determine the influence and transportation of metal pollutants in the Danube River on the Western Black Sea. Pb, Cd, Hg and Cr concentration in the sediment was above the shale average (20, 0.2, 300 and 100 μg g-1 respectively) while Fe, Cu, Zn including Ni concentration was determined to be below the shale average (4.7 %, 50, 90 and 80 μg g-1 respectively). High total organic carbon (TOC, 2.5-4.11 %) and dissolved hydrogen sulfur (DHS, 249-419 μg g-1) observed, suggested widespread pollution, cause by carry-over water and suspended solids in the Danube River. Additionally, the high concentration of Pb, Cd and Hg, in the surface sediment indicated that anthropogenic input is a major contributor of pollution via the Danube River.
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References
C. Humborg, V. Ittekkok, A. Cociasu and B. Bodungen, Nature, 386, 385 (1997).
O. Basturk, E. Yakushev, S. Tugrul and I. Salihoglu, Characteristic Chemical Features and Biogeochemical Cycles in the Black Sea, in Environmental Degradation of the Black Sea: Challanges and Remedies,
S. Besiktepe, Ü. Ünlüata and A.S. Bologa (eds), NATO Science Series/Second Environmental Security, The Netherlands, pp. 43-57 (1999).
T. Oguz, State of the Enviroment of the Black Sea 2001-2006/7. Commission on the Protection of the Black Sea Against Pollution, Istanbul (2008).
H.I. Sur, T. Oguz, E. Özsoy and U. Unluata, Features of the Circulation and Dynamics of the Black Sea as Inferred from Hydrographic Data and Satellite Imagery. NATO Workshop on Satellite Oceanography and its
Applications. University of Lisbon, Lisbon (Portugal), 25-27 November 1991. in, Proceedings of Workshop, A.F.G. Fiuza (ed.), Lisbon, Portugal, University of Lisbon, p. 11 (1994).
A.G. Greenberg, R.R. Trussel, L.S. Clesceri and M.A.H. Franson. Standard Methods for the Examination of Water and Wastewater, American Water Work Association (APHA, AWWA and WPCF), Washington edn. 16 (1985).
J.D.H. Strickland and T.R. Parsons, A Practical Handbook of Seawater Analysis Oxford Press, Canada, edn. 2 (1972).
K.W. Bruland, R.P. Fanks, G.A. Knauer and J.H. Martin, Anal. Chem. Acta, 105, 223 (1979).
K.W. Bruland, K.H. Coale and L. Mart, Marine Chem., 17, 285 (1985).
V. Medera, H.E. Allen and R.C. Minear, Chem. Radiol. Exam., 2, 169 (1982).
W.M. Landing and B.L. Lewis. in eds.: E. Izdar and J.W. Murray, Thermodynamic Modeling of Trace Metal Speciation in the Black Sea. In: NATO-ASI Symposium Series, Black Sea Oceanography, pp. 125-160.(1991).
A. Boughriet, M. Wartel, C. Cordier, C. Douez, L. Deram, E. Martin, B. Ouddane, H. Chamley and P. Recourt, Marine Pollut. Bull., 28, 541 (1994).
D.H. Loring and R.T.T. Rantala, Earth Sci. Rev., 32, 235 (1992).
T. Oguz and S. Besiktepe, Black Sea Deep-Sea Res., I 46, 1733 (1999).
I. Salihoglu and E. Mutlu, Mediterrenian, Marmara Sea, Turkish Bosphorus Systems, Black Sea and Atmosphere Projects, 1995-1999 Period Report, Middle East Technical University. DAP and International Marine Research and Monitoring Program (2000).
D. Ayas, M. Kalay and M.K. Sangun, Ekoloji, 70, 32 (2009).
N.B. Price, J. Pates, S. Mowbray, F.S. Lindsay, H.R. Stewart, F. Nyfeller and C.H. Godet, Seasonal Variability and Transport Pathways of the Elements of Suspended Particulate Matter. In: Transfer Pathways and Fluxes of Organic Matter and Related Elements in Water and Sediments of the Northern Adriatic Sea and Their Importance on the Eastern Mediterrenean Sea. Final Report (1996).
S.P.C. Tankere, F.L.L. Muller, J.D. Burton, P.C. Statham, C. Guieu and J.M. Martin, Continental Self Res., 27, 521 (2001).
K.B. Krauskopf, Introduction to Geochemistry, International Series in the Earth and Planetary Scienes. McGraw-Hill, Tokyo, p. 617 (1979).
M.A. Glagoleva, Am. Geol. Inst., 135, 1 (1961).
G.N. Baturin and A.V. Kochenov, Oceanology, 7, 792 (1968).
I.I. Volkov and L.S. Fomina, Chem. Biol., M20, 456 (1974).
M.N. Cagatay, T. Saltoglu and A. Gedik, Geol. Eng., 30-31, 47 (1987).
S. Topcuoglu, C. Kirbasoglu and N. Gungor, Environ. Int., 27, 521 (2001).
B. Mason and C. Moore, Principles of Geochemistry: New York, NY, John Wiley & Sons, edn. 4, p. 344 (1982).
T. Gaye, K. Turan, I.B. Turgut, C.F. Gökçay, A. Sezer, Y. Coskun and T. Gurdal, Marine Pollut. Bull., 36, 409 (1998).
H.Z. Sarikaya, M.F. SevimLi and E. Çitil, Water Sci. Technol., 39, 193 (1999).