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Rapid Determination of Phenolic Compounds in Extracts of the Leaves of Ipomoea batatas (L.) Lam. by HPLC-DAD-ESI-MS
Corresponding Author(s) : Fan Qiu
Asian Journal of Chemistry,
Vol. 25 No. 9 (2013): Vol 25 Issue 9
Abstract
Ipomoea batatas (L.) Lam. (Sweet potato) is not only used as staple food, but also is a traditional herbal drug in China for the treatment of various disease. For analyze the component of the extraction, we have developed a chromatography electrospray ionization tandem mass spectrometry (HPLC-ESI-MS/MS) method to characterize th fraction of ethyl acetate, which gtave prominent [M-H]– ions by electrospray ionization menitored in the negative ion mode. A total of ten phenolic compounds were identified or tentatively characterized based on the UV spectra and Tandem mass spectra of the HPLC peaks. The tandem mass spectrometric fragmentation behaviour of caffeoylqinic acid derivatives and flavonoids have been investigated extensively.
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- K.D. Sarwan, P.S. Hari and D. Seema, Compendium of Transgenic Crop Plants: Sweet Potato, Wiley Online Library (2009).
- M.S. Islam, M. Yoshimoto, S. Yahara, S. Okuno, K. Ishiguro and O. Yamakawa, J. Agric. Food. Chem., 50, 3718 (2002).
- M. Takenaka, K. Nanayama, S. Isobe abd M. Murata, Biosci. Biotechnol. Biochem., 70, 172 (2006).
- W. Zheng and M.N. Clifford, Food Chem., 106, 147 (2008).
- J.-K. Jung, S.-U. Lee, N. Kozukue, C.E. Levin and M. Friedman, J. Food Compos. Anal., 24, 29 (2011).
- S. Kaviarasan, A.S. Sivakumar, A. Barik, A. Kunwar, G.H. Naik and K.I. Priyadarsini, J. Food. Biochem., 35, 596 (2011).
- M.T. Pochapski, E.C. Fosquiera, L.A. Esmerino, E.B. Santos, P.V. Fargo, F.A. Santos and F.C. Groppo, Pharmacog. Mag., 7, 165 (2011).
- S. Islam, J. Food Sci., 71, R13 (2006).
- D. Kammerer, R. Carle and A. Schieber, Rapid Commun. Mass Spectrom., 18, 1331 (2004).
- V. Ossipov, K. Nurmi, J. Loponen, E. Haukioja and K. Pihlaja, J. Chromatogr. A, 721, 59 (1996).
- E.C. Tatsis, S. Boeren, V. Exarchou, A.N. Troganis, J. Vervoort and I.P. Gerothanassis, Phytochemistry, 68, 383 (2007).
- A. Ribas-Agustí, M. Gratacós-Cubarsí, S. Sárraga, J.A. García-Regueiro and M. Castellari, Phytochem. Anal., 22, 555 (2011).
- H. Budzikiewicz, C. Djerassi and D.H. Williams, Mass Spectrometry of Organic Compounds, Holden-Day: San Francisco, p. 219 (1967).
- M.N. Clifford, S. Knight and N. Kuhnert, J. Agric. Food. Chem., 53, 3821 (2005).
- Y. Zhang, P. Shi, H. Qu and Y. Cheng, Rapid Commun. Mass Spectrom., 21, 2971 (2007).
References
K.D. Sarwan, P.S. Hari and D. Seema, Compendium of Transgenic Crop Plants: Sweet Potato, Wiley Online Library (2009).
M.S. Islam, M. Yoshimoto, S. Yahara, S. Okuno, K. Ishiguro and O. Yamakawa, J. Agric. Food. Chem., 50, 3718 (2002).
M. Takenaka, K. Nanayama, S. Isobe abd M. Murata, Biosci. Biotechnol. Biochem., 70, 172 (2006).
W. Zheng and M.N. Clifford, Food Chem., 106, 147 (2008).
J.-K. Jung, S.-U. Lee, N. Kozukue, C.E. Levin and M. Friedman, J. Food Compos. Anal., 24, 29 (2011).
S. Kaviarasan, A.S. Sivakumar, A. Barik, A. Kunwar, G.H. Naik and K.I. Priyadarsini, J. Food. Biochem., 35, 596 (2011).
M.T. Pochapski, E.C. Fosquiera, L.A. Esmerino, E.B. Santos, P.V. Fargo, F.A. Santos and F.C. Groppo, Pharmacog. Mag., 7, 165 (2011).
S. Islam, J. Food Sci., 71, R13 (2006).
D. Kammerer, R. Carle and A. Schieber, Rapid Commun. Mass Spectrom., 18, 1331 (2004).
V. Ossipov, K. Nurmi, J. Loponen, E. Haukioja and K. Pihlaja, J. Chromatogr. A, 721, 59 (1996).
E.C. Tatsis, S. Boeren, V. Exarchou, A.N. Troganis, J. Vervoort and I.P. Gerothanassis, Phytochemistry, 68, 383 (2007).
A. Ribas-Agustí, M. Gratacós-Cubarsí, S. Sárraga, J.A. García-Regueiro and M. Castellari, Phytochem. Anal., 22, 555 (2011).
H. Budzikiewicz, C. Djerassi and D.H. Williams, Mass Spectrometry of Organic Compounds, Holden-Day: San Francisco, p. 219 (1967).
M.N. Clifford, S. Knight and N. Kuhnert, J. Agric. Food. Chem., 53, 3821 (2005).
Y. Zhang, P. Shi, H. Qu and Y. Cheng, Rapid Commun. Mass Spectrom., 21, 2971 (2007).