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Studies on Swelling Kinetics and Temperature-Sensitive Superabsorbent Hydrogels Based on Carboxymethylcelloluse
Corresponding Author(s) : Mohammad Sadeghi
Asian Journal of Chemistry,
Vol. 25 No. 9 (2013): Vol 25 Issue 9
Abstract
To develop materials with improved controllability and specificity, we have investigated swelling kinetics and temperature-sensitive properties using thermal cross-linking of a superabsorbing hydrogel based on carboxymethylcellulose and N-isopropylacrylamide and methacrylamide in a homogeneous solution. The hydrogels exhibited tem-sensitivity and cation exchange properties. The temperature and pH-reversibility properties of the hydrogels make the smart polymers as good candidates for considering as potential carriers for bioactive agents, e.g., drugs. The swelling variations of hydrogels were also explained according to swelling theory based on the hydrogel chemical structure.
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- F.L. Buchholz and A.T. Graham, Modern Superabsorbent Polymer Technology, Wiley, New York (1997).
- V.D. Athawale and V. Lele, Carbohydr. Polym., 35, 21 (1998).
- D. Castal, A. Ricard and R. Audebert, J. Appl. Polym. Sci., 39, 11 (1990).
- S. Hua and A. Wang, Carbohydr. Polym., 75, 79 (2009).
- J. Kost, Encyclopedia of Controlled Drug Delivery, Intelligent Drug Delivery Systems, Wiley, New York, Vol. 1 (1999).
- W.F. Lee and W.Y. Yuan, J. Appl. Polym. Sci., 77, 1760 (2000).
- G.R. Mahdavinia, A. Pourjavadi, H. Hosseinzadeh and M.J. Zohuriaan, Eur. Polym. J., 40, 1399 (2004).
- R. Po, J. Macromol. Sci.-Rev. Macromol. Chem. Phys., C34, 607 (1994).
- A. Pourjavadi, A.M. Harzandi and H. Hosseinzadeh, Eur. Polym. J., 40, 1363 (2004).
- P.J. Flory, Principles of Polymer Chemistry, Cornell University Press, Ithaca, New York (1953).
- M. Sadeghi and H. Hosseinzadeh, Turk. J. Chem., 32, 739 (2010).
- H. Yan, A. Saiani, J.E. Gough and A.F. Miller, Biomacromolecules, 7, 2776 (2006).
- M.J. Zohuriaan-Mehr and A. Pourjavadi, J. Polym. Mater., 20, 113 (2003).
- A. Pourjavadi and M. Kurdtabar, Eur. Polym. J., 43, 877 (2007).
- J. Chen and Y. Zhao, J. Appl. Polym. Sci., 75, 808 (2000).
- H. Hosseinzadeh and M. Sadeghi, Asian J. Chem., 24, 85 (2011).
- M. Sadeghi and N. Ghasemi, Asian J. Chem., 24, 2049 (2012).
References
F.L. Buchholz and A.T. Graham, Modern Superabsorbent Polymer Technology, Wiley, New York (1997).
V.D. Athawale and V. Lele, Carbohydr. Polym., 35, 21 (1998).
D. Castal, A. Ricard and R. Audebert, J. Appl. Polym. Sci., 39, 11 (1990).
S. Hua and A. Wang, Carbohydr. Polym., 75, 79 (2009).
J. Kost, Encyclopedia of Controlled Drug Delivery, Intelligent Drug Delivery Systems, Wiley, New York, Vol. 1 (1999).
W.F. Lee and W.Y. Yuan, J. Appl. Polym. Sci., 77, 1760 (2000).
G.R. Mahdavinia, A. Pourjavadi, H. Hosseinzadeh and M.J. Zohuriaan, Eur. Polym. J., 40, 1399 (2004).
R. Po, J. Macromol. Sci.-Rev. Macromol. Chem. Phys., C34, 607 (1994).
A. Pourjavadi, A.M. Harzandi and H. Hosseinzadeh, Eur. Polym. J., 40, 1363 (2004).
P.J. Flory, Principles of Polymer Chemistry, Cornell University Press, Ithaca, New York (1953).
M. Sadeghi and H. Hosseinzadeh, Turk. J. Chem., 32, 739 (2010).
H. Yan, A. Saiani, J.E. Gough and A.F. Miller, Biomacromolecules, 7, 2776 (2006).
M.J. Zohuriaan-Mehr and A. Pourjavadi, J. Polym. Mater., 20, 113 (2003).
A. Pourjavadi and M. Kurdtabar, Eur. Polym. J., 43, 877 (2007).
J. Chen and Y. Zhao, J. Appl. Polym. Sci., 75, 808 (2000).
H. Hosseinzadeh and M. Sadeghi, Asian J. Chem., 24, 85 (2011).
M. Sadeghi and N. Ghasemi, Asian J. Chem., 24, 2049 (2012).