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Study on Toughening Mechanism of Epoxy Adhesive Modified by Nano-SiO2
Corresponding Author(s) : R.M. Wang
Asian Journal of Chemistry,
Vol. 25 No. 9 (2013): Vol 25 Issue 9
Abstract
Epoxy resin adhesives are widely used in various sectors, particularly in the aerospace and automotive industries. However, the solidification of the three-dimensional network structure of pure epoxy resin, which causes greater density and brittleness, results in poor system resilience. With the ultimate goal of improving the resilience of epoxy resin, nano-sized SiO2 particles were introduced to improve the adhesion strength of both modified and unmodified epoxy adhesive. The results indicated increases of shearing strength from 16.66-Mpa to 18.01 -Mpa, impact strength from 15.4 -kJ/m2 to 33.68- kJ/m2 and flexural strength from 70.5 -Mpa to 80.94 Mpa.
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References
R.F. Service, Science, 294, 1448 (2001).
S. Auer and D. Frenkel, Nature, 413, 711 (2001).
L. Kozma and I. Olefjord, J. Mater. Sci. Technol., 3, 954 (1987).
F. Lapique and K. Redford, Int. J. Adhes. Adhes., 22, 337 (2002).
G. Abraham, S. Packirisamy, T.M. Vijayan and R. Ramaswamy, J. Appl. Polym. Sci., 88, 1737 (2003).
T. Lan and T. Pinnavaia, J. Chem. Mater., 6, 2216 (1994).
J.W. Gilman, T. Kashiwagi and D. Lichtenhan, SAMPE J., 33, 40 (1997).
E. Sancaktar and J. Kuznicki, Int. J. Adhes. Adhes., 31, 286 (2011).
B. Li and X.-L. Li, Chem. Mater. Construct., 19, 38 (2003).
J. Van den Brand, S. Van Gils, P.C.J. Beentjes, H. Terryn, V. Sivel and J.H.W. de Wit, Prog. Org. Coat., 51, 339 (2004).
J. Friedrich, G. Kuhn, R. Mix, A. Fritz and A. Schonhals, Adhes. Sci. Technol., 17, 1591 (2003).
T. Hjertberg and J.E. Lakso, Appl. Polym. Sci., 37, 1287 (1989).