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Vol. 25 No. 8 (2013): Vol 25 Issue 8

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Synthesis, Crystal Structure and Antitumor Activity of 1D Coordination Polymer of Ca(II) and Na(I) with N-p-tolylsulfonyl-glycine

https://doi.org/10.14233/ajchem.2013.13992
Tai Xi-Shi
College of Chemistry and Chemical Engineering, Weifang University, Weifang 261061, P.R. China
Li Fa-Hui
College of Chemistry and Chemical Engineering, Weifang University, Weifang 261061, P.R. China

Corresponding Author(s) : Tai Xi-Shi

taixs@wfu.edu.cn; taixishi@lzu.edu.cn

Asian Journal of Chemistry, Vol. 25 No. 8 (2013): Vol 25 Issue 8

Abstract

1D coordination polymer formed by Ca(II) and Na(I) was synthesized by the reaction of calcium perchlorate, NaOH with N-p-tolylsulfonyl-glycine in the CH3CH2OH/H2O (v:v = 3:1). It was characterized by elemental analysis, IR and X-ray single crystal diffraction analysis. The crystal of the complex belongs to triclinic, space group P-1 with a = 0.95657(10) nm, b = 1.09171(11) nm, c = 1.8292(2) nm, a = 80.6790(10)º, b = 86.831(2)º, g = 89.957(2)º, V = 1.8821(3) nm3, Z = 2, Dc = 1.599 Mg m-3, μ = 0.507 mm-1, F(000) = 936 and final R1 = 0.0981, wR2 = 0.2262. The complex comprises a seven-coordinated Ca(II) center, with a O7 distorted pengonal coordination environment and a six-coordinated Na(I) center, with distorted octahedron environment. The molecules are connected by the oxygen atoms of carboxylates to form one dimensional chain structure. The antitumor activities against gastric cancer cells of free ligand and its Ca(II) complex were studied by MTT method.

Keywords

N-p-Tolysulfonyl-glycine Ca(II) complex Synthesis Crystal structure Antitumor activity
Xi-Shi, T., & Fa-Hui, L. (2013). Synthesis, Crystal Structure and Antitumor Activity of 1D Coordination Polymer of Ca(II) and Na(I) with N-p-tolylsulfonyl-glycine. Asian Journal of Chemistry, 25(8), 4401–4403. https://doi.org/10.14233/ajchem.2013.13992
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References
  1. W.G. Liu, L. Jiang, X.L. Feng and T.B. Lu, Cryst. Growth Des., 6, 564 (2006).
  2. L.G. Tian, H.J. Yang, X.L. Zheng, Z.H. Ni, D.M. Yan, L.L. Tu and J.Z. Jiang, Appl. Organomet. Chem., 23, 24 (2009).
  3. L.F. Wang, Y.X. Hu and W.W. Ren, Chin. J. Inorg. Chem., 27, 542 (2011).
  4. X.M. Jin, Q.F. Xu, Q.X. Zhou, J.M. Lu and L.H. Wang, Chin. J. Inorg. Chem., 25, 539 (2009).
  5. Y. Ding, Z.J. Ku, H.B. Zhou, D.S. Gao and C.L. Li, Chin. J. Inorg. Chem.. 25, 544 (2009).
  6. X.S. Tai, J. Yin and Y.M. Feng, Chin. J. Inorg. Chem., 23, 1812 (2007).
  7. G.M. Sheldrick, SHELXL-97, Program for Crystal Structure Solution; University of GÖttingen: GÖttingen, Germany (1997).
  8. G.M. Sheldrick, SHELXTL-97, Program for Crystal Structure Solution; University of GÖttingen: GÖttingen, Germany (1997).
  9. N. Dodoff, K. Grancharow and R. Gugova, J. Inorg. Biochem., 54, 221 (1994).
  10. K. Nakamoto, Infrared and Ramen Spectra of Inorganic and Coordination Compounds, New York: John Wiley and Sons, American, edn. 3 (1978).
  11. X.S. Tai, Y.M. Feng, F.Y. Kong, D.Q. Wang and M.Y. Tan, Chin. J. Inorg. Chem., 24, 831 (2008).
  12. X.S. Tai, J. Yin and M.Y. Hao, Acta Cryst., E63, m1935 (2007).
  13. X.S. Tai, Adv. Mater. Res., 282-283, 96, 108 (2011).
  14. P. Patricia and J.M. Trevor, Cancer Res., 50, 1392 (1990).
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