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Lipase Catalyzed Synthesis of Fatty Acid Xylose Esters and their Surfactant Properties
Corresponding Author(s) : C. Bidjou-Haiour
Asian Journal of Chemistry,
Vol. 25 No. 8 (2013): Vol 25 Issue 8
Abstract
Enzymatic synthesis of non-ionic surfactants from renewable sources represents a new challenge in biotechnology. In this paper, lipase catalyzed synthesis of xylose esters with fatty acid in organic medium, was performed. Influence of reaction parameters such as biocatalyst amount, temperature, lipase preparations, organic solvents and the use of different fatty as acyl donor was studied. Critical micellar concentration and surface tension value of these amphiphilic compounds have been determined.
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- S. Piccicuto, C. Blecker, J.-C. Brohée, A. Mbampara, G. Lognay, C. Deranne, M. Paquot and M. Marlier, Biotechnol. Agronom. Soc. Environ., 5, 209 (2001).
- T. Polat and R.J. Linhardt, J. Surface Deterg., 4, 415 (2001).
- P. Villeneuve, Biotechnol. Adv., 25, 515 (2007).
- T. Kobayashi, Biotechnol. Lett., 33, 1911 (2011).
- D. Coulon,A. Ismail, M. Girardin, B. Rovel and M. Ghoul, J. Biotechnol., 51, 115 (1996).
- I.J.A. Baker, B. Matthews, H. Suares, I. Krodkiewska, D.N. Furlong, F. Grieser and C.J. Drummond, J. Surface Deterg., 3, 1 (2000).
- E. Abdulmalek, H.S.M. Saupi, B.A. Tejo, M. Basri, A.B. Salleh, R.N. Zaliha and M.B. Abdul Rahman, J. Mol. Catal. B, 76, 37 (2012).
- R. BenSalah, H. Ghamghui, N. Miled, H. Mejdoub and Y. Gargouri, J. Biosci. Bioeng., 103, 368 (2007).
- S. Ho Ha, N.M. Hiep, S.H. Lee and Y.M. Koo, Bioproc. Biosyst. Eng., 33, 63 (2010).
- Y. Yan, U.T. Bornscheuer, L. Cao and R.D. Schmid, Enzym. Microbial Technol., 25, 725 (1999).
- M. Leitgeb and Z. Knez, J. Am. Oil Chemist's Soc., 67, 775 (1990).
- F. Chamouleau, D. Coulon, M. Girardin and M. Ghoul, J. Molecul. Catal. B: Enzymatic, 11, 949 (2001).
- S. Tarahomjoo and I. Alemzadeh, Enzyme Microbiol. Technol., 33, 33 (2003).
- D. Coulon, M. Girardin, J.-M. Engasser and M. Ghoul, Ind. Crops Prod., 6, 375 (1997).
- L. Cao, U.T. Bornscheuer and R.D. Schmidt, Biocatal. Biotransform., 14, 269 (1997).
- T. Serradj and C. Bidjou-Haiour, Alg. J. Adv. Mater., 5, 297 (2008).
- N.A.S. Neta, J.C.S. dos Santos, S.O. Sancho, S. Rodrigues, L.R.B. Gonçalves, L.R. Rodrigues and J.A. Teixeira, Food Hydrocolloids, 27, 324 (2012).
- M.R. Infante, L. Perez, A. Pinazo, P. Clapés, M.C. Moràn, M. Angelet, M.T. Garcià and M.P. Vinardell, C.R. Chimie, 7, 583 (2004).
- J.W. Gibbs, The Collected Works of J. W. Gibbs, Yale Univesity Press, Vol. 1, p. 219 (1948); b) M.J. Rosen, Surfactants and Interfacial Phenomena, Wiley & Sons, New York, (1981).
- G. Garfalkis, B.S. Murray and D.B. Sarney, J. Colloid Interf. Sci., 9, 391 (2000).
References
S. Piccicuto, C. Blecker, J.-C. Brohée, A. Mbampara, G. Lognay, C. Deranne, M. Paquot and M. Marlier, Biotechnol. Agronom. Soc. Environ., 5, 209 (2001).
T. Polat and R.J. Linhardt, J. Surface Deterg., 4, 415 (2001).
P. Villeneuve, Biotechnol. Adv., 25, 515 (2007).
T. Kobayashi, Biotechnol. Lett., 33, 1911 (2011).
D. Coulon,A. Ismail, M. Girardin, B. Rovel and M. Ghoul, J. Biotechnol., 51, 115 (1996).
I.J.A. Baker, B. Matthews, H. Suares, I. Krodkiewska, D.N. Furlong, F. Grieser and C.J. Drummond, J. Surface Deterg., 3, 1 (2000).
E. Abdulmalek, H.S.M. Saupi, B.A. Tejo, M. Basri, A.B. Salleh, R.N. Zaliha and M.B. Abdul Rahman, J. Mol. Catal. B, 76, 37 (2012).
R. BenSalah, H. Ghamghui, N. Miled, H. Mejdoub and Y. Gargouri, J. Biosci. Bioeng., 103, 368 (2007).
S. Ho Ha, N.M. Hiep, S.H. Lee and Y.M. Koo, Bioproc. Biosyst. Eng., 33, 63 (2010).
Y. Yan, U.T. Bornscheuer, L. Cao and R.D. Schmid, Enzym. Microbial Technol., 25, 725 (1999).
M. Leitgeb and Z. Knez, J. Am. Oil Chemist's Soc., 67, 775 (1990).
F. Chamouleau, D. Coulon, M. Girardin and M. Ghoul, J. Molecul. Catal. B: Enzymatic, 11, 949 (2001).
S. Tarahomjoo and I. Alemzadeh, Enzyme Microbiol. Technol., 33, 33 (2003).
D. Coulon, M. Girardin, J.-M. Engasser and M. Ghoul, Ind. Crops Prod., 6, 375 (1997).
L. Cao, U.T. Bornscheuer and R.D. Schmidt, Biocatal. Biotransform., 14, 269 (1997).
T. Serradj and C. Bidjou-Haiour, Alg. J. Adv. Mater., 5, 297 (2008).
N.A.S. Neta, J.C.S. dos Santos, S.O. Sancho, S. Rodrigues, L.R.B. Gonçalves, L.R. Rodrigues and J.A. Teixeira, Food Hydrocolloids, 27, 324 (2012).
M.R. Infante, L. Perez, A. Pinazo, P. Clapés, M.C. Moràn, M. Angelet, M.T. Garcià and M.P. Vinardell, C.R. Chimie, 7, 583 (2004).
J.W. Gibbs, The Collected Works of J. W. Gibbs, Yale Univesity Press, Vol. 1, p. 219 (1948); b) M.J. Rosen, Surfactants and Interfacial Phenomena, Wiley & Sons, New York, (1981).
G. Garfalkis, B.S. Murray and D.B. Sarney, J. Colloid Interf. Sci., 9, 391 (2000).