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Physico-chemical Investigation of Th(IV) and UO2(VI) Complexes of Schiff Bases
Corresponding Author(s) : Kishor Arora
Asian Journal of Chemistry,
Vol. 25 No. 8 (2013): Vol 25 Issue 8
Abstract
Schiff bases were obtained using p-methoxy benzaldehyde and p-chloro benzaldehyde and 2-amino pyridine to prepare new complexes of thorium(IV) and dioxouranium(VI) metals by various anions. The synthesized ligands and complexes were analytically studied through spectral studies, elemental analysis conductance measurements along with semi empirical and thermogravimetric methods. The complexes were assigned various coordination numbers ranging from 6-10 on the basis of these studies.
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- D.P. Joshi and Keemtilal, J. Indian Chem. Soc., 46, 477 (1969).
- R.K. Agarwal, K. Arora, Priyanka and I. Chakraborti, Polish J. Chem., 67, 1913 (1993).
- R.M. Silverstein, F.X. Webster and D.Kiemle, Spectrometric Identification of Organic Compounds, Wiley & Sons, edn. 6 (1998).
- MOPAC 93 @ Fujitsu Inc.
- N.L. Allinger, J. Am. Chem. Soc., 113, 1907 (1977).
- K. Arora,A. Gupta and D.D. Agrawal, Asian J. Chem., 14, 1611 (2002).
- E.S. Freeman and B. Caroll, J. Phys. Chem., 62, 394 (1958).
- A.W. Coats and J.P. Redfern, Nature, 210, 68 (1964).
- H.H. Horowitz and G. Metzer, Anal. Chem., 35, 1464 (1958).
- S. Agnihotri, B. Singh, K. Burman and K. Arora, Asian J. Chem., 23, 2086 (2011)
References
D.P. Joshi and Keemtilal, J. Indian Chem. Soc., 46, 477 (1969).
R.K. Agarwal, K. Arora, Priyanka and I. Chakraborti, Polish J. Chem., 67, 1913 (1993).
R.M. Silverstein, F.X. Webster and D.Kiemle, Spectrometric Identification of Organic Compounds, Wiley & Sons, edn. 6 (1998).
MOPAC 93 @ Fujitsu Inc.
N.L. Allinger, J. Am. Chem. Soc., 113, 1907 (1977).
K. Arora,A. Gupta and D.D. Agrawal, Asian J. Chem., 14, 1611 (2002).
E.S. Freeman and B. Caroll, J. Phys. Chem., 62, 394 (1958).
A.W. Coats and J.P. Redfern, Nature, 210, 68 (1964).
H.H. Horowitz and G. Metzer, Anal. Chem., 35, 1464 (1958).
S. Agnihotri, B. Singh, K. Burman and K. Arora, Asian J. Chem., 23, 2086 (2011)